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A glass surface may still flow below the bulk glass transition temperature, where the underlying bulk is frozen. Assuming the existence at T=T* of a bulk thermodynamical glass transition, we show that the glass-vapor interface is generally…

Materials Science · Physics 2009-10-31 E. A. Jagla , E. Tosatti

Phase change under reduced environmental pressures is key to understanding liquid discharge and propulsion processes for aerospace applications. A representative case is the sessile water droplets exposed to high vacuum, which experience…

The origin of ice slipperiness has been a matter of great controversy for more than a century, but an atomistic understanding of ice friction is still lacking. Here, we perform computer simulations of an atomically smooth substrate sliding…

Applied Physics · Physics 2024-02-08 Lukasz Baran , Pablo Llombart , Wojciech Rzysko , Luis G. MacDowell

The properties of the interface between solid and melt are key to solidification and melting, as the interfacial free energy introduces a kinetic barrier to phase transitions. This makes solidification happen below the melting temperature,…

Statistical Mechanics · Physics 2015-12-02 Bingqing Cheng , Gareth A. Tribello , Michele Ceriotti

Manipulating surface topography is one of the most promising strategies for increasing the efficiency of numerous industrial processes involving droplet contact with superheated surfaces. In such scenarios, the droplets may immediately boil…

Fluid Dynamics · Physics 2022-03-31 Navid Saneie , Varun Kulkarni , Kamel Fezzaa , Neelesh Patankar , Sushant Anand

Nanofluidics is an emerging field offering innovative solutions for energy harvesting and desalination. The efficiency of these applications depends strongly on liquid-solid slip, arising from a favorable ratio between viscosity and…

Soft Condensed Matter · Physics 2022-08-16 Cecilia Herrero , Gabriele Tocci , Samy Merabia , Laurent Joly

We apply a phenomenological theory of polar liquids to calculate the interaction energy between two plane surfaces at nm-distances. We show that depending on the properties of the surface-liquid interfaces, the interacting surfaces induce…

Soft Condensed Matter · Physics 2013-04-24 P. O. Fedichev , L. I. Menshikov

Surface effect of low-surface-tension contaminants accumulating at the evaporation surface can easily induce membrane wetting in the application of membrane distillation, especially in hypersaline scenarios. In this work, we propose a novel…

Chemical Physics · Physics 2023-12-25 Yanni Ma , Zehua Yu , Xifan Fu , Zhi Huang , Tenghui Qiu , Na Zhao , Huidong Liu , Kang Liu

The splat formed after drop impact on supercooled solid surfaces sticks to it. On the contrary, a sublimating supercooled surface such as dry ice inhibits pinning and therefore efficiently rebounds drops made of a variety of liquids. While…

Freezing is a fundamental physical phenomenon that has been studied over many decades; yet the role played by surfaces in determining nucleation has remained elusive. Here we report direct computational evidence of surface induced…

Statistical Mechanics · Physics 2015-05-13 T. Li , D. Donadio , L. M. Ghiringhelli , G. Galli

Using molecular dynamics simulations and methods of importance sampling, we study the thermodynamics and dynamics of sodium chloride in the aqueous premelting layer formed spontaneously at the interface between ice and its vapor. We uncover…

Statistical Mechanics · Physics 2020-12-21 Samuel P. Niblett , David T. Limmer

Freezing of water droplets placed on the bare and superhydrophobic surfaces of polymer wedges are studied both experimentally and computationally. Two-dimensional numerical calculations of the transient temperature field in a chilled…

In this work, we perform a systematic computer simulation study of ice premelting, and explore the thickness and structure of quasi-liquid layers formed at the interface of ice with substrates of different hydrophilicity. Our study shows…

Soft Condensed Matter · Physics 2024-10-30 Łukasz Baran , Pablo Llombart , Luis G. MacDowell

The influence of temperature on interfacial fluid slip, as measured by molecular-dynamics simulations of a Couette flow comprising a Lennard-Jones fluid and rigid crystalline walls, is examined as a function of the fluid-solid interaction…

Fluid Dynamics · Physics 2021-06-30 Thiago F. Viscondi , Adriano Grigolo , Iberê L. Caldas , Julio R. Meneghini

Water condensation on superhydrophobic surfaces can generate spontaneous droplet jumping, enabling rapid condensate removal and improved thermal and mass transfer. Although this effect has been extensively demonstrated on densely packed…

Superhydrophobic surfaces can exhibit icephobicity in many ways due to their large contact angles and small rolling angles. The melting process of frozen droplets on superhydrophobic surfaces is still unclear, hindering the understanding of…

Fluid Dynamics · Physics 2023-10-09 Jiawang Cui , Tianyou Wang , Zhizhao Che

Freezing in the vicinity of water-vapor interfaces is of considerable interest to a wide range of disciplines, most notably the atmospheric sciences. In this work, we use molecular dynamics and two advanced sampling techniques, forward flux…

Statistical Mechanics · Physics 2014-11-04 Amir Haji-Akbari , Ryan S. DeFever , Sapna Sarupria , Pablo G. Debenedetti

A widely accepted phenomenological rule states that solids with free surfaces cannot be overheated. In this work we discuss this statement critically under the light of the statistical thermodynamics of interfacial roughening transitions.…

Soft Condensed Matter · Physics 2025-01-08 Lukasz Baran , Pablo Llombart , Eva G. Noya , L. G. MacDowell

The controlled handling of liquids and colloidal suspensions as they interact with surfaces, targeting a broad palette of related functionalities, is of great importance in science, technology, and nature. When small liquid volumes need to…

Modification of surfaces to enable dropwise condensation is a promising approach for achieving high condensation rates. In this work, we present an experimental study on condensation of water on copper surfaces coated with an ultrathin, 5…