Related papers: Solvo-osmotic flow in electrolytic mixtures
The distribution of ions at the air/water interface plays a decisive role in many natural processes. It is generally understood that polarizable ions with low charge density are surface-active, implying they sit on top of the water surface.…
Traditional models of electrokinetic transport in porous media are based on homogenized material properties, which neglect any macroscopic effects of microscopic fluctuations. This perspective is taken not only for convenience, but also…
Electroosmotic pumping of fluid through a nanopore that traverses an insulating membrane is considered. The density of surface charge on the membrane is assumed uniform, and sufficiently low for the Poisson-Boltzmann equation to be…
We study here the curious particle dynamics resulting from electro-osmotic flow around a microchannel junction corner whose dielectric walls are weakly polarizable. The hydrodynamic velocity field is obtained via superposition of a linear…
We study the role of ionic correlations on the electroosmotic flow in planar double-slit channels, without salt. We propose an analytical theory, based on recent advances in the understanding of correlated systems. We compare the theory…
In computational models of microchannel flows, the Helmholtz-Smoluchowski slip velocity boundary condition is often used because it approximates the motion of the electric double layer without resolving the charge density profiles close to…
When two reservoirs of a distinct salinity are connected by channels or pores, a fluid flow termed diffusio-osmotic is generated. This article investigates the flow emerging in an uniformly charged long slit whose thickness exceeds the…
We characterize the electro-phoretic motion of charged sphere suspensions in the presence of substantial electro-osmotic flow using a recently introduced small angle super-heterodyne dynamic light scattering instrument (ISASH-LDV).…
The generally accepted view of osmotic pressure is that it is a colligative property, along with freezing point depression, boiling point elevation and vapour pressure lowering. These properties ideally depend on the concentration of…
We consider two charged semipermeable membranes, which bound bulk electrolyte solutions and are separated by a thin film of salt-free liquid. Small counter-ions permeate into the gap, which leads to a steric charge separation in the system.…
Numerical analyses of transient electro-osmosis of a typical non-Newtonian liquid induced by DC and AC electric fields in a rectangular microchannel are conducted in the framework of continuum fluid mechanics. The famous power-law…
The movement of ionic solutions is an essential part of biology and technology. Fluidics, from nano- to micro- to microfluidics, is a burgeoning area of technology which is all about the movement of ionic solutions, on various scales. Many…
Thermo-osmotic flow around a microparticle in a liquid is characterized by observing and analyzing the distribution of tiny particles, i.e., tracers, near the microparticle's surface. First, an optical trapping laser is used to localize the…
We theoretically study the electrokinetic problem of a pressure-induced liquid flow through a narrow long channel with charged walls, going beyond the classical Helmholtz-Schmolukowski picture by considering the surprisingly strong combined…
We introduce a model for ionic electrodiffusion and osmotic water flow through cells and tissues. The model consists of a system of partial differential equations for ionic concentration and fluid flow with interface conditions at deforming…
It has been suggested that superhydrophobic surfaces, due to the presence of a no-shear zone, can greatly enhance transport of surface charges, leading to a considerable increase in the streaming potential. This could find potential use in…
We describe theoretically ``electrolubrication'' in liquid mixtures, the phenomenon where an electric field applied transverse to the confining surfaces leads to concentration gradients that alter the flow profile significantly. When the…
We study flows generated within a two-dimensional corner by the chemical activity of the confining boundaries. Catalytic reactions at the surfaces induce diffusioosmotic motion of the viscous fluid throughout the domain. The presence of…
The ion distribution of electrolytes near interfaces with dielectric contrast has important consequences for electrochemical processes and many other applications. To date, most studies of such systems have focused on geometrically simple…
Solute gradients next to an interface drive a diffusioosmotic flow, the origin of which lies in the intermolecular interactions between the solute and the interface. These flows on the surface of colloids introduce an effective slip…