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We study surface charge transfer doping of exfoliated black phosphorus (bP) flakes by copper using scanning tunneling microscopy (STM) and spectroscopy (STS) at room temperature. The tunneling spectra reveal a gap in correspondence of Cu…

Using the Tight Binding (TB) parameters extracted from Density Functional Theory (DFT) and Recursive Green's Function method, it is shown that skewed-zigzag black phosphorous (phosphorene) nanoribbons obtain large and tuneable bandgap in…

Mesoscale and Nanoscale Physics · Physics 2019-01-16 Sima Shekarforoush , Farhad Khoeini , Daryoush Shiri

Coulomb interaction and its screening play an important role in many physical phenomena of materials ranging from optical properties to many-body effects including superconductivity. Here, we report on a systematic study of dielectric…

Materials Science · Physics 2017-04-05 D. A. Prishchenko , V. G. Mazurenko , M. I. Katsnelson , A. N. Rudenko

The latest achievements in the fabrication of black phosphorus thin layers, towards the technological breakthrough of a phosphorene atomically thin layer, are paving the way for a their employment in electronics, optics, and…

Optics · Physics 2016-12-21 I. Kriegel , S. Toffanin , F. Scotognella

Unencapsulated, exfoliated black phosphorus (BP) flakes are found to chemically degrade upon exposure to ambient conditions. Atomic force microscopy, electrostatic force microscopy, transmission electron microscopy, X-ray photoelectron…

Optical selection rules endorsed by symmetry are crucial for understanding the optical properties of quantum materials and the associated ultrafast spectral phenomena. Here, we introduce momentum-resolved Floquet optical selection rules…

Materials Science · Physics 2025-08-29 Benshu Fan , Umberto De Giovannini , Hannes Hübener , Shuyun Zhou , Wenhui Duan , Angel Rubio , Peizhe Tang

We report on the mechanical properties of few-layer black phosphorus (BP) nanosheets, in high vacuum and as a function of time of exposure to atmospheric conditions [1]. BP flakes with thicknesses ranging from 4 to 30 nm suspended over…

Within the past few years, atomically thin black phosphorus (BP) has been demonstrated as a fascinating new 2D material that is promising for novel nanoelectronics and nanophotonics applications, due to its many unique properties such as…

Applied Physics · Physics 2019-08-06 Zi-Yu Chen , Rui Qin

Black phosphorus (BP), a layered van der Waals (vdW) crystal, has unique in-plane band anisotropy and many resulting anisotropy properties such as the effective mass, electron mobility, optical absorption, thermal conductivity and plasmonic…

Materials Science · Physics 2020-08-14 Zhimin Liu , Ye Yang , Yueshao Zheng , Qinjun Chen , Yexin Feng

Black phosphorus (P) has emerged as a layered semiconductor with a unique crystal structure featuring corrugated atomic layers and strong in-plane anisotropy in its physical properties. Here, we demonstrate that the crystal orientation and…

Mesoscale and Nanoscale Physics · Physics 2016-09-27 Zenghui Wang , Hao Jia , Xu-Qian Zheng , Rui Yang , G. J. Ye , X. H. Chen , Philip X. -L. Feng

The impact of vacancies on spin-resolved electronic properties of quantum dots (QDs) in phosphorene-based junctions, are investigated numerically. Regardless of the crystal orientation, a phosphorene nanoribbon (PNR) containing a…

Mesoscale and Nanoscale Physics · Physics 2024-11-05 Maryam Mahdavifar , Farhad Khoeini , Francois M. Peeters

Quantum dot sensitized solar cells are among the new generations of solar cells that have attracted much attention. Theoretical and simulation studies have predicted high efficiency for these cells so that in the future, these cells could…

Applied Physics · Physics 2020-07-17 Hossein Vahid Dastjerdi , Hamidreza Fallah , Morteza Hajimahmoodzadeh

We report about the energy and momentum resolved optical response of black phosphorus (BP) in its bulk form. Along the armchair direction of the puckered layers we find a highly dispersive mode that is trongly suppressed in the…

Mesoscale and Nanoscale Physics · Physics 2015-03-10 R. Schuster , J. Trinckauf , M. Knupfer , B. Büchner

With a semiconducting band gap and high charge carrier mobility, two-dimensional (2D) black phosphorus (BP), often referred to as phosphorene, holds significant promise for next generation electronics and optoelectronics. However, as a 2D…

Materials Science · Physics 2015-02-10 Xiaolong Liu , Joshua D. Wood , Kan-Sheng Chen , EunKyung Cho , Mark C. Hersam

Tunability of the photoabsorption and directional charge injection characteristics of Bodipy-based dye molecules with different carbonyl groups make them promising candidates for photovoltaic applications. In order to study the effect of…

Chemical Physics · Physics 2014-04-01 Hatice Unal , Deniz Gunceler , Ersen Mete

Black phosphorus (BP), a relative new plasmonic two-dimensional (2D) material, offers unique photonic and electronic properties. In this work, we propose a new tunable and broadband ultrathin coherent perfect absorber (CPA) device operating…

Optics · Physics 2020-08-10 Tianjing Guo , Christos Argyropoulos

We report a straightforward chemical methodology for controlling the thickness of black phosphorus flakes down to the monolayer limit by layer-by-layer oxidation and thinning, using water as solubilizing agent. Moreover, the oxidation…

Black Phosphorus (BP) is an excellent material for post graphene era due to its layer dependent band gap, high mobility and high Ion/Ioff. However, its poor stability in ambient poses a great challenge in its practical and long-term usage.…

Black Phosphorus (BP) is unique among layered materials owing to its homonuclear lattice and strong structural anisotropy. While recent investigations on few layers BP have extensively explored the in-plane (a,c) anisotropy, much less…

Density functional theory (DFT) can be quite advantageous in advancing the field of catalysis because of the microscopic insights it provides, and thus can guide experimental searches of novel catalysts. Several recent works have…

Materials Science · Physics 2022-03-24 Vaishali Sharma , Basant Roondhe , Sumit Saxena , Alok Shukla