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Related papers: Singlet Fission in Chiral Carbon Nanotubes: Densit…

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We use Boltzmann transport equation (BE) to study time evolution of a photo-excited state in a nanoparticle including phonon-mediated exciton relaxation and the multiple exciton generation (MEG) processes, such as exciton-to-biexciton…

Mesoscale and Nanoscale Physics · Physics 2017-11-22 Andrei Kryjevski , Deyan Mihaylov , Svetlana Kilina , Dmitri Kilin

Singlet fission, a spin-allowed energy transfer process generating two triplet excitons from one singlet exciton, has the potential to dramatically increase the efficiency of organic solar cells. However, the dynamical mechanism of this…

Materials Science · Physics 2015-06-12 Timothy C. Berkelbach , Mark S. Hybertsen , David R. Reichman

We studied the nonlinear time-resolved luminescence signals due to multiexciton recombination processes in single-walled carbon nanotubes (SWNTs) using femtosecond excitation correlation (FEC) spectroscopy. From theoretical analysis of the…

Materials Science · Physics 2015-05-13 Yuhei Miyauchi , Kazunari Matsuda , Yoshihiko Kanemitsu

We develop a method for computing self-energy of a biexciton state in a semiconductor nanostructure using many-body perturbation theory (MBPT) based on the density functional theory (DFT) simulation. We compute energies of low-energy…

Mesoscale and Nanoscale Physics · Physics 2020-03-19 Deyan Mihaylov , Andrei Kryjevski

Singlet fission is a form of multiple exciton generation which occurs in organic chromophores when a high energy singlet exciton separates into two lower energy triplet excitons, each with approximately half the singlet energy. Since this…

Photophysics of single-wall carbon nanotubes (SWCNTs) is intensively studied due to their potential application in light harvesting and optoelectronics. Excited states of SWCNTs form strongly bound electron-hole pairs, excitons, of which…

Mesoscale and Nanoscale Physics · Physics 2021-01-28 J. Palotas , M. Negyedi , S. Kollarics , A. Bojtor , P. Rohringer , Th. Pichler , F. Simon

Singlet fission (SF), the spontaneous down-conversion of a singlet exciton into two triplet excitons residing on neighboring molecules, is a promising route to improving organic photovoltaic (OPV) device efficiencies by harvesting two…

Materials Science · Physics 2018-05-23 Xiaopeng Wang , Xingyu Liu , Cameron Cook , Bohdan Schatschneider , Noa Marom

Singlet fission (SF) is a multi-exciton generation process that could be harnessed to improve the efficiency of photovoltaic devices. Experimentally, systems derived from the pentacene molecule have been shown to exhibit ultrafast SF with…

Chemical Physics · Physics 2020-06-23 David H. P. Turban , Gilberto Teobaldi , David D. O'Regan , Nicholas D. M. Hine

We develop a powerful tree tensor network states method that is capable of simulating exciton-phonon quantum dynamics of larger molecular complexes and open quantum systems with multiple bosonic environments. We interface this method with…

Multiple exciton generation (MEG) in nanometer-sized hydrogen-passivated silicon nanowires (NWs), and quasi two-dimensional nanofilms strongly depends on the degree of the core structural disorder as shown by the many-body perturbation…

Mesoscale and Nanoscale Physics · Physics 2014-11-25 Andrei Kryjevski , Dmitri Kilin

Single-walled carbon nanotubes (SWNTs) are potential materials for future nanoelectronics. Since the electronic and optical properties of SWNTs strongly depend on tube diameter and chirality, obtaining SWNTs with narrow (n,m) chirality…

Materials Science · Physics 2007-11-28 Xiaolin Li , Xiaomin Tu , Sasa Zaric , Kevin Welsher , Won Seok Seo , Wei Zhao , Hongjie Dai

The complete energy expression of a deformed single-walled carbon nanotube (SWNT) is derived in the continuum limit from the local density approximation model proposed by Lenosky {\it et al.} \lbrack Nature (London) {\bf 355}, 333…

Materials Science · Physics 2007-05-23 Zhan-chun Tu , Zhong-can Ou-Yang

The recent development of efficient chirality sorting techniques has opened the way to the use of single-walled carbon nanotubes (SWCNTs) in a plethora of nanoelectronic, photovoltaic, and optoelectronic applications. However, to understand…

Mesoscale and Nanoscale Physics · Physics 2019-12-25 María Rosa Preciado-Rivas , Victor Alexander Torres-Sánchez , Duncan J. Mowbray

Singlet fission (SF) can potentially break the Shockley-Queisser efficiency limit in single-junction solar cells by splitting one photo-excited singlet exciton (S1) into two triplets (2T1) in organic semiconductors. A dark multi-exciton…

Chemical Physics · Physics 2015-12-08 Rui Wang , Chunfeng Zhang , Bo Zhang , Yunlong Liu , Xiaoyong Wang , Min Xiao

Environmental dielectric screening effects on exciton transition energies in single-walled carbon nanotubes (SWNTs) have been studied quantitatively in the range of dielectric constants from 1.0 to 37 by immersing SWNTs bridged over…

Singlet fission (SF) is an electronic transition that in the last decade has been under the spotlight for its applications in optoelectronics, from photovoltaics to spintronics. Despite considerable experimental and theoretical…

Quantum Physics · Physics 2024-11-12 Francesco Campaioli , Alice Pagano , Daniel Jaschke , Simone Montangero

The electronic and structural properties of zigzag and armchair single-wall carbon nanotubes (SWCNT) with a single vacancy or two vacancies located at various distances have been obtained within the frame of the Density Function Theory…

Atomic and Molecular Clusters · Physics 2008-07-15 A. Proykova , H. Iliev , Feng Yin Li

Singlet fission, in which the optical spin-singlet exciton dissociates into two low energy triplet excitons, has been proposed as a viable approach to enhance the quantum efficiency of organic solar cells. We show that even when singlet…

Strongly Correlated Electrons · Physics 2013-03-15 K. Aryanpour , J. A. Muñoz , S. Mazumdar

A 1 $\mu$m long, field emitting, (5,5) single-walled, carbon nanotube (SWCNT) closed with a fullerene cap, and a similar open nanotube with hydrogen-atom termination, have been simulated using the MNDO (Modified Neglect of Diatomic Overlap)…

Singlet fission may boost photovoltaic efficiency [by transforming a singlet exciton into two triplet excitons and thereby doubling the number of excited charge carriers. The primary step of singlet fission is the ultrafast creation of the…

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