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We report superconductivity in the novel 112-type iron-based compound Ca1-xLaxFeAs2. Single-crystal X-ray diffraction analysis revealed that the compound crystallizes in a monoclinic structure (space group P21), in which Fe2As2 layers…

Synthesis of a series of layered iron arsenides Ca1-xRExFeAs2 (112) was attempted by heating at 1000 C under a high-pressure of 2 GPa. The 112 phase successfully forms with RE = La, Ce, Nd, Sm, Eu and Gd, while Tb, Dy and Ho substituted and…

Single crystal X-ray diffraction studies were performed for the Sb-doped 112-type iron-based superconductor Ca1-xLaxFeAs2 with the superconducting transition temperature Tc of 47 K. Doped Sb preferably substituted not for As(1) in the FeAs…

A new iron arsenide superconducting system LiFeAs was found that crystallizes into a tetragonal structure with space group P4/nmm. The superconductivity with Tc up to 18 K was observed in the compounds. This simple 111 type layered iron…

Superconductivity · Physics 2009-11-13 X. C. Wang , Q. Q. Liu , Y. X. Lv , W. B. Gao , L. X. Yang , R. C. Yu , F. Y. Li , C. Q. Jin

The 1111-type iron arsenide hydride CaFe1-xCoxAsH was synthesized by high-pressure solid-state reaction, and its electronic structure and superconducting properties were investigated. Bulk superconductivity was observed at x = 0.07-0.26. A…

Superconductivity · Physics 2014-03-05 Yoshinori Muraba , Satoru Matsuishi , Hideo Hosono

The recently discovered high-T$_c$ superconductor Ca$_{1-x}$La$_{x}$FeAs$_{2}$ is a unique compound not only because of its low symmetry crystal structure, but also because of its electronic structure which hosts Dirac-like metallic bands…

Strongly Correlated Electrons · Physics 2017-01-25 Chang-Jong Kang , Turan Birol , Gabriel Kotliar

CaFeAs2 is a parent compound of recently discovered 112-type iron-based superconductors. It is predicted to be a staggered intercalation compound that naturally integrates both quantum spin Hall insulating and superconducting layers and an…

Superconductivity · Physics 2016-08-02 Z. T. Liu , X. Z. Xing , M. Y. Li , W. Zhou , Y. Sun , C. C. Fan , H. F. Yang , J. S. Liu , Q. Yao , W. Li , Z. X. Shi , D. W. Shen , Z. Wang

The newly discovered 112-type ferropnictide superconductors contain chains of As atoms that break the tetragonal symmetry between the $a$ and $b$ axes. This feature eliminates the need for uniaxial strain that is usually required to…

Strongly Correlated Electrons · Physics 2016-03-23 J. W. Harter , H. Chu , S. Jiang , N. Ni , D. Hsieh

We have synthesized 10 new iron oxyarsenides, K$Ln_2$Fe$_4$As$_4$O$_2$ ($Ln$ = Gd, Tb, Dy, and Ho) and Cs$Ln_2$Fe$_4$As$_4$O$_2$ ($Ln$ = Nd, Sm, Gd, Tb, Dy, and Ho), with the aid of lattice-match [between $A$Fe$_2$As$_2$ ($A$ = K and Cs)…

Superconductivity · Physics 2017-09-13 Si-Qi Wu , Zhi-Cheng Wang , Chao-Yang He , Zhang-Tu Tang , Yi Liu , Guang-Han Cao

We report a systematic polarization-dependent angle-resolved photoemission spectroscopy study of the three-dimensional electronic structure of the recently discovered 112-type iron-based superconductor Ca1-xLaxFeAs2 (x = 0.1). Besides the…

Superconductivity · Physics 2015-01-14 M. Y. Li , Z. T. Liu , W. Zhou , H. F. Yang , D. W. Shen , W. Li , J. Jiang , X. H. Niu , B. P. Xie , Y. Sun , C. C. Fan , Q. Yao , J. S. Liu , Z. X. Shi , X. M. Xie

We report a systematic crystal growth and characterization of Ca$_{1-y}$La$_{y}$Fe$_{1-x}$Ni$_{x}$As$_{2}$, the newly discovered 112-type iron-based superconductor. After substituting Fe by a small amount of Ni, bulk superconductivity is…

Fluctuation magnetoconductivity and magnetization above the superconducting transition temperature (Tc) are measured on the recently discovered 112 family of iron-based superconductors (IBS), Ca$_{1-x}$La$_x$Fe$_{1-y}$Ni$_y$As$_2$, which…

Superconductivity · Physics 2017-08-01 D. Sóñora , C. Carballeira , J. J. Ponte , Tao Xie , Huiqian Luo , Shiliang Li , J. Mosqueira

Superconductivity was achieved in Ti-doped iron-arsenide compound Sr4Cr0.8Ti1.2O6Fe2As2 (abbreviated as Cr-FeAs-42622). The x-ray diffraction measurement shows that this material has a layered structure with the space group of…

Superconductivity · Physics 2015-05-13 Xiyu Zhu , Fei Han , Gang Mu , Peng Cheng , Bing Shen , Bin Zeng , Hai-Hu Wen

A new layered iron arsenide oxide (Fe2As2)(Ca4(Mg,Ti)3Oy) was discovered. Its crystal structure is tetragonal with a space group of I4/mmm consisted of the anti-fluorite type FeAs layer and blocking layer of triple perovskite cells and is…

We report time-of-flight inelastic neutron scattering (INS) investigations on the spin fluctuation spectrum in the 112-type iron-based superconductor (FeSC) Ca$_{0.82}$La$_{0.18}$Fe$_{0.96}$Ni$_{0.04}$As$_{2}$ (CaLa-112). In comparison to…

Superconductivity · Physics 2022-10-12 Tao Xie , Chang Liu , Ryoichi Kajimoto , Kazuhiko Ikeuchi , Shiliang Li , Huiqian Luo

A new iron-based superconductor (Ca,Pr)FeAs2 was discovered. Plate-like crystals of the new phase were obtained and crystal structure was investigated by single-crystal X-ray diffraction analysis. The structure was identified as the…

We have discovered new layered oxyarsenides (Fe2As2)(Sr4M2O6) (M = Sc, Cr: M-22426). These materials are isostructural with (Fe2P2)(Sr4Sc2O6), which was found in our previous study. The new compounds are tetragonal with a space group of…

Superconductivity · Physics 2009-06-24 Hiraku Ogino , Yukari Katsura , Shigeru Horii , Kohji Kishio , Jun-ichi Shimoyama

We report the discovery and characterization of a novel 112-type iron pnictide EuFeAs2, with La-doping induced superconductivity in a series of Eu1-xLaxFeAs2. The polycrystalline samples were synthesized through solid state reaction method…

Superconductivity · Physics 2017-02-14 Jia Yu , Tong Liu , Bo-Jin Pan , Bin-Bin Ruan , Xiao-Chuan Wang , Qing-Ge Mu , Kang Zhao , Gen-Fu Chen , Zhi-An Ren

Based on first-principles FLAPW-GGA calculation, we have investigated electronic structure of newly discovered oxygen-free 38K superconductor Ba1-xKxFe2As2 in comparison with parent phase - tetragonal ternary iron arsenide BaFe2As2. The…

Superconductivity · Physics 2009-11-13 I. R. Shein , A. L. Ivanovskii

The ternary iron arsenide BaFe2As2 becomes superconducting by hole doping, which was achieved by partial substitution of the barium site with potassium. We have discovered bulk superconductivity up to Tc = 38 K in (Ba1-xKx)Fe2As2 with x =…

Superconductivity · Physics 2008-09-06 Marianne Rotter , Marcus Tegel , Dirk Johrendt
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