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In this paper, we investigate the energy minimization model of the ensemble Kohn-Sham density functional theory for metallic systems, in which a pseudo-eigenvalue matrix and a general smearing approach are involved. We study the invariance…

Numerical Analysis · Mathematics 2022-01-19 Xiaoying Dai , Stefano de Gironcoli , Bin Yang , Aihui Zhou

The success of density functional theory for the description of the adsorption of atoms on surfaces is well established, and based on recent calculations using gradient corrections, it has been shown that it also describes well the…

mtrl-th · Physics 2008-02-03 Catherine Stampfl

The free-free opacity in dense systems is a property that both tests our fundamental understanding of correlated many-body systems, and is needed to understand the radiative properties of high energy-density plasmas. Despite its importance,…

We present calculations of the free-free XUV opacity of warm, solid-density aluminum at photon energies between the plasma frequency at 15 eV and the L-edge at 73 eV, using both density functional theory combined with molecular dynamics and…

Plasma Physics · Physics 2009-04-02 S. M. Vinko , G. Gregori , B. Nagler , T. J. Whitcher , M. P. Desjarlais , R. W. Lee , P. Audebert , J. S. Wark

We discuss a $\beta$-dependent family of electronic density scalings of the form $n_\lambda(\R)=\lambda^{3\beta+1}\; n(\lambda^\beta \R)$ in the context of density functional theory. In particular, we consider the following special cases:…

Materials Science · Physics 2013-01-31 Eduardo Fabiano , Lucian A. Constantin

Reactivity of Aluminum Clusters has been found to exhibit size sensitive variations. This work is motivated by a recent report1 predicting higher reactivity of melted Aluminum clusters towards the N2 molecule as compared to the non-melted…

Materials Science · Physics 2010-06-02 Bhakti S. Kulkarni , Sailaja Krishnamurty , Sourav Pal

The average-atom model is applied to study Thomson scattering of x-rays from warm-dense matter with emphasis on scattering by bound electrons. Parameters needed to evaluate the dynamic structure function (chemical potential, average ionic…

Plasma Physics · Physics 2015-06-05 W. R. Johnson , J. Nilsen , K. T. Cheng

We present an analytical study of the spatial decay rate $\gamma$ of the one-particle density matrix $\rho(\vec r,\vec r')\sim\exp(-\gamma|\vec r-\vec r'|)$ for systems described by single particle orbitals in periodic potentials in…

Materials Science · Physics 2007-05-23 Sohrab Ismail-Beigi , Tomas Arias

We develop a microscopic theory to analyze the phase behaviour and compute correlation functions of dense assemblies of soft repulsive particles both at finite temperature, as in colloidal materials, and at vanishing temperature, a…

Disordered Systems and Neural Networks · Physics 2011-11-09 Ludovic Berthier , Hugo Jacquin , Francesco Zamponi

Orbital-free density functional theory (OF-DFT) constitutes a computationally highly effective tool for modeling electronic structures of systems ranging from room-temperature materials to warm dense matter. Its accuracy critically depends…

Density functional methods were developed, in which the Coulomb electron-electron interaction is split into a long- and a short-range part. In such methods, one term is calculated using traditional density functional approximations, like…

Chemical Physics · Physics 2007-05-23 Julien Toulouse , Andreas Savin

We apply density functional theory to study the freezing of superfluid {$^{4}\rm{He}$}, charged bosons and charged fermions at zero temperature. We employ accurate Quantum Monte Carlo data for the linear response function in the uniform…

Condensed Matter · Physics 2009-10-28 C. N. Likos , Saverio Moroni , Gaetano Senatore

The technological performances of metallic compounds are largely influenced by atomic ordering. Although there is a general consensus that successful theories of metallic systems should account for the quantum nature of the electronic glue,…

Materials Science · Physics 2015-05-13 Ezio Bruno , Francesco Mammano , Beniamino Ginatempo

Methods exhibiting linear scaling with respect to the size of the system, so called O(N) methods, are an essential tool for the calculation of the electronic structure of large systems containing many atoms. They are based on algorithms…

Condensed Matter · Physics 2007-05-23 Stefan Goedecker

Accurate prediction of the thermal and electrical conductivities of materials under extremely high temperatures is essential in high-energy-density physics. These properties govern processes such as stellar core dynamics, planetary magnetic…

Plasma Physics · Physics 2025-10-14 Qianrui Liu , Xiantu He , Mohan Chen

We derive an exact representation of the exchange-correlation energy within density functional theory (DFT) which spawns a class of approximations leading to correct long-range asymptotic behavior. In what amounts to be the simplest…

Materials Science · Physics 2009-11-10 Roi Baer , Daniel Neuhauser

Atom density profile arising in the atomic beam after passing through the one or two microfabricated structures (MS) is considered. Two limiting cases the beam with large and small angular divergence are considered. An equivalence of the…

Atomic Physics · Physics 2007-05-23 B. Dubetsky , P. R. Berman

Accurate predictions of the abundance and clustering of dark matter haloes play a key role in testing the standard cosmological model. Here, we investigate the accuracy of one of the leading methods of connecting the simulated dark matter…

Cosmology and Nongalactic Astrophysics · Physics 2013-10-15 Anatoly Klypin , Francisco Prada , Gustavo Yepes , Steffen Hess , Stefan Gottlober

In a recent Letter, Baer et al. present a stochastic method for Kohn-Sham density functional theory calculations. Their convergence criterion is the self-averaging total energy per electron, which requires a number of statistical samples…

Materials Science · Physics 2014-04-15 Jonathan E. Moussa , Andrew D. Baczewski

The effect of the nitrided layer introduced by NO annealing on the electronic structure and carrier scattering property of the 4H-SiC(0001)/SiO$_2$ interface is investigated by the density functional theory calculation using the interface…

Materials Science · Physics 2025-07-08 Nahoto Funaki , Kosei Sugiyama , Mitsuharu Uemoto , Tomoya Ono
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