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Hydrogen has been the essential element in the development of atomic and molecular physics1). Moving to the properties of dense hydrogen has appeared a good deal more complex than originally thought by Wigner and Hungtinton in their seminal…

Materials Science · Physics 2019-06-14 Paul Loubeyre , Florent Occelli , Paul Dumas

The possibility of metallic hydrogen was first mooted by Wigner and Huntington in 1935. Here it is show that the calculations from that paper are in remarkably good agreement with modern density functional theory results. The possibility…

Materials Science · Physics 2017-09-18 Graeme J Ackland

A recent paper by Zaghoo et al. presents optical data at high-pressure and high-temperature and interprets the data as evidence for a first-order phase transition to metallic hydrogen during heating. Here we argue that the presented data…

Materials Science · Physics 2017-10-25 Alexander F. Goncharov , Zachary M. Geballe

The insulator to metal transition in solid hydrogen was predicted over 70 years ago but the demonstration of this transition remains a scientific challenge. In this regard, a peak in the temperature vs. pressure melting line of hydrogen may…

Materials Science · Physics 2009-11-13 Shanti Deemyad , Isaac F. Silvera

Characterization of the first ever laboratory produced metallic hydrogen sample relies on measurements of optical spectra. Here we present first-principles calculations of the reflectivity of hydrogen between 400 and 600 GPa in the…

Superconductivity · Physics 2018-02-07 Miguel Borinaga , Julen Ibañez-Azpiroz , Aitor Bergara , Ion Errea

The primary purpose of this paper is to stimulate theoretical predictions of how to retain metastably hydrogenous materials made at high pressure P on release to ambient. Ultracondensed metallic hydrogen has been made at 140 GPa at finite…

Materials Science · Physics 2017-12-06 W. J. Nellis

Optical properties of compressed fluid hydrogen in the region where dissociation and metallization is observed are computed by ab-initio methods and compared to recent experimental results. We confirm that above 3000 K both processes are…

Materials Science · Physics 2019-09-04 Giovanni Rillo , Miguel A. Morales , David M. Ceperley , Carlo Pierleoni

Liquid-liquid phase transition of hydrogen is at the center of hydrogen phase diagram as a promising route towards emergent properties such as the Wigner-Huntington metallization, superconductivity, and superfluidity. Here we report a study…

Materials Science · Physics 2022-06-27 Jianqing Guo , Bingqing Cheng , Limei Xu , Enge Wang , Ji Chen

In Nat Commun 13, 3194 (2022) [1], Minkov et al. reported magnetization measurements on hydrides under pressure that claimed to find a diamagnetic signal below a critical temperature demonstrating the existence of superconductivity. Here we…

Superconductivity · Physics 2023-10-06 J. E. Hirsch , F. Marsiglio

Dissipationless quantum states, such as superconductivity and superfluidity, have attracted interest for almost a century. A variety of systems exhibit these macroscopic quantum phenomena, ranging from superconducting electrons in metals to…

Superconductivity · Physics 2007-05-23 Egor Babaev , Asle Sudbo , N. W. Ashcroft

The optical spectra of hydrogen at $\sim$500 GPa were studied theoretically using a combination of \emph{ab initio} methods. Among the four most competitive structures, i.e. C2/c-24, Cmca-12, Cmca-4, and I41/amd, only the atomic phase…

Materials Science · Physics 2018-10-24 Xiaowei Zhang , En-Ge Wang , Xin-Zheng Li

The phase diagram of hydrogen is one of the most important challenges in high-pressure physics and astrophysics. Especially, the melting of dense hydrogen is complicated by dimer dissociation, metallization and nuclear quantum effect of…

Materials Science · Physics 2023-04-25 Hua Y. Geng , Q. Wu

In previous work,1 we showed that hydrogen metallizes in phase III at temperatures below ~200 K and at pressures near ~350 GPa. Here, we perform a detailed study of electrical conductivity R(T) in phase III over a pressure range of 200-400…

Materials Science · Physics 2021-09-24 M. I. Eremets , P. P. Kong , A. P. Drozdov

In recent years, metal hydride research has become one of the driving forces of the high-pressure community, as it is believed to hold the key to superconductivity close to ambient temperature. While numerous novel metal hydride compounds…

The article in \cite{HolmlidAIPA2016} has recently come to our attention. It makes a number of extraordinary claims that each contradict well established facts in several fields, ranging from atomic and molecular physics to…

Atomic and Molecular Clusters · Physics 2022-07-19 Klavs Hansen , Jos Engelen

Metallic hydrogen, existing in remarkably extreme environments, was predicted to exhibit long-sought room-temperature superconductivity. Although the superconductivity of metallic hydrogen has not been confirmed experimentally,…

Superconductivity · Physics 2024-06-12 Zihan Zhang , Wendi Zhao , Defang Duan , Tian Cui

It is generally assumed that solid hydrogen will transform into a metallic alkali-like crystal at sufficiently high pressure. However, some theoretical models have also suggested that compressed hydrogen may form an unusual two-component…

Materials Science · Physics 2009-11-10 Stanimir A. Bonev , Eric Schwegler , Tadashi Ogitsu , Giulia Galli

In the quest to make metallic hydrogen at low temperatures a rich number of new phases have been found and the highest pressure ones have somewhat flat phase lines, around room temperature. We have studied hydrogen to static pressures of…

Other Condensed Matter · Physics 2016-05-30 Ranga Dias , Ori Noked , Isaac F. Silvera

A possibility of high, room-temperature superconductivity was predicted for metallic hydrogen in the 1960s. However, metallization and superconductivity of hydrogen are yet to be unambiguously demonstrated in the laboratory and may require…

Atomic metallic hydrogen has been produced in the laboratory at high pressure and low temperature, prompting further investigations of its different properties. However, purely experimental approaches are infeasible because of the extreme…

Materials Science · Physics 2018-05-29 Bo Peng , Ke Xu , Hao Zhang , Hezhu Shao , Gang Ni , Jing Li , Liangcai Wu , Hongliang Lu , Qingyuan Jin , Heyuan Zhu