Related papers: Resolving the debate about proposed expressions fo…
The possible distinction between inanimate and living matter has been of interest to humanity since thousands of years. Clearly, such a rich question can not be answered in a single manner, and a plethora of approaches naturally do exist.…
Several results of black holes thermodynamics can be considered as firmly founded and formulated in a very general manner. From this starting point we analyse in which way these results may give us the opportunity to gain a better…
Statistical entropies of a general relativistic ideal gas obeying Maxwell-Boltzmann, Bose-Einstein and Fermi-Dirac statistics are calculated in a general axisymmetry space-time of arbitrary dimension. This general formation can be used to…
In statistical mechanics entropy is a measure of disorder obeying Boltzmann's formula $S=\log{\cal N}$, where ${\cal N}$ is the accessible phase space volume. In black hole thermodynamics one associates to a black hole an entropy…
We report the statistical properties of classical particles in (2+1) gravity as resulting from numerical simulations. Only particle momenta have been taken into account. In the range of total momentum where thermal equilibrium is reached,…
A dynamical estimate is given for the Boltzmann entropy of the Universe, under the simplifying assumptions provided by Newtonian cosmology. We first model the cosmological fluid as the probability fluid of a quantum-mechanical system. Next,…
Conventional thermo-statistics address infinite homogeneous systems within the canonical ensemble. However, some 150 years ago the original motivation of thermodynamics was the description of steam engines, i.e. boiling water. Its essential…
We discuss the form of the entropy for classical hamiltonian systems with long-range interaction using the Vlasov equation which describes the dynamics of a $N$-particle in the limit $N\to\infty$. The stationary states of the hamiltonian…
The usual canonical Hamiltonian or Lagrangian formalism of classical mechanics applied to macroscopic systems describes energy conserving adiabatic motion. If irreversible diabatic processes are to be included, then the law of increasing…
In ordinary Boltzmann-Gibbs thermostatistics, the relative entropy expression plays the role of generalized free energy, providing the difference between the off-equilibrium and equilibrium free energy terms associated with Boltzmann-Gibbs…
In the last quarter of the nineteenth century, Ludwig Boltzmann explained how irreversible macroscopic laws, in particular the second law of thermodynamics, originate in the time-reversible laws of microscopic physics. Boltzmann's analysis,…
We employ classical thermodynamics to gain information about absolute entropy, without recourse to statistical methods, quantum mechanics or the Third Law of thermodynamics. The Gibbs-Duhem equation yields various simple methods to…
Statistical mechanics can only be ultimately justified in terms of microscopic dynamics (classical, quantum, relativistic, or any other). It is known that Boltzmann-Gibbs statistics is based on the hypothesis of exponential sensitivity to…
Gibbs and Boltzmann definitions of temperature agree only in the macroscopic limit. The ambiguity in identifying the equilibrium temperature of a finite sized `small' system exchanging energy with a bath is usually understood as a…
We show how the dependence of phase space volume $\Omega(N)$ of a classical system on its size $N$ uniquely determines its extensive entropy. We give a concise criterion when this entropy is not of Boltzmann-Gibbs type but has to assume a…
The fundamental assumption of statistical mechanics is that the system is equally likely in any of the accessible microstates. Based on this assumption, the Boltzmann distribution is derived and the full theory of statistical thermodynamics…
This short book is an elementary course on entropy, leading up to a calculation of the entropy of hydrogen gas at standard temperature and pressure. Topics covered include information, Shannon entropy and Gibbs entropy, the principle of…
The physical impossibility of heat transfer under isothermal conditions implies that the classical expression for the entropy of the ideal gas may not be compatible with the internal energy of the gas itself. A corrected expression of the…
Ergodicity, this is to say, dynamics whose time averages coincide with ensemble averages, naturally leads to Boltzmann-Gibbs (BG) statistical mechanics, hence to standard thermodynamics. This formalism has been at the basis of an enormous…
In a recent paper [Franzosi, Physica A {\bf 494}, 302 (2018)], we have suggested to use of the surface entropy, namely the logarithm of the area of a hypersurface of constant energy in the phase space, as an expression for the thermodynamic…