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The linear combination of atomic orbitals (LCAO) is a standard method for studying solids and molecules, it is also known as the tight$-$binding (TB) method. In most of the implementations only the basis set and the coupling constants are…

Materials Science · Physics 2024-01-18 Graziâni Candiotto

We present a simple density functional theory for the solid phases of systems of particles interacting via soft-core potentials. In particular, we apply the theory to particles interacting via repulsive point Yukawa and Gaussian pair…

Soft Condensed Matter · Physics 2007-05-23 A. J. Archer

We present an ab-initio study of the electronic response function of sodium in its 5 known metallic phases from 0 to 180 GPa at room temperature. The considered formalism is based on a interpolation scheme within time-dependent density…

Materials Science · Physics 2014-02-07 J. Ibañez-Azpiroz , B. Rousseau , A. Eiguren , A. Bergara

Using density functional theory calculations, many researchers have predicted that various tungsten-nitride compounds WN$_x$ ($x$ > 1) will be "ultra-compressible" or "superhard", $i.e.$ as hard as or harder than diamond. These compounds…

Materials Science · Physics 2015-06-11 Michael J. Mehl , Daniel Finkenstadt , Christian Dane , Gus L. W. Hart , Stefano Curtarolo

We proposed a formally exact, probabilistic method to assess the validity of the Thomas-Fermi potential for three-dimensional condensed matter systems where electron dynamics is constrained to the Fermi surface. Our method, which relies on…

Materials Science · Physics 2024-06-25 Gionni Marchetti

{\em Ab initio} techniques based on density functional theory in the projector-augmented-wave implementation are used to calculate the free energy and a range of other thermodynamic properties of liquid iron at high pressures and…

Materials Science · Physics 2009-11-07 D. Alfe` , G. D. Price , M. J. Gillan

Disordered and hyperuniform structures of densely packed spheres near and at jamming are characterized by vanishing of long-wavelength density fluctuations, or equivalently by long-range power-law decay of the direct correlation function…

Statistical Mechanics · Physics 2021-10-04 Hiroshi Frusawa

In this work we present a new method for the calculation of the electrostrictive properties of materials using density functional theory. The method relies on the thermodynamical equivalence, in a dielectric, of the quadratic mechanical…

Materials Science · Physics 2022-08-15 Daniel S. P. Tanner , Eric Bousquet , Pierre-Eymeric Janolin

Ground-state Kohn-Sham density functional theory provides, in principle, the exact ground-state energy and electronic spin-densities of real interacting electrons in a static external potential. In practice, the exact density functional for…

Chemical Physics · Physics 2022-07-11 Aaron D. Kaplan , Mel Levy , John P. Perdew

The influence of pressure on the structural and elastic properties of ScM (M = Rh, Cu, Ag, Hg) compounds has been performed by using ab initio approach pseudopotential plane- wave method based on the density functional theory within the…

Materials Science · Physics 2016-05-18 Md. Lokman Ali , Md. Zahidur Rahaman , Md. Atikur Rahman

A geometry-based density functional theory is presented for mixtures of hard spheres, hard needles and hard platelets; both the needles and the platelets are taken to be of vanishing thickness. Geometrical weight functions that are…

Soft Condensed Matter · Physics 2009-11-11 Ansgar Esztermann , Hendrik Reich , Matthias Schmidt

Accurate knowledge of the properties of hydrogen at high compression is crucial for astrophysics (e.g. planetary and stellar interiors, brown dwarfs, atmosphere of compact stars) and laboratory experiments, including inertial confinement…

In a spatially periodic temperature profile, directed transport of an overdamped Brownian particle can be induced along a periodic potential. With a load force applied to the particle, this setup can perform as a heat engine. For a given…

Statistical Mechanics · Physics 2009-04-02 Florian Berger , Tim Schmiedl , Udo Seifert

In this progress report we present a new approach to the ab-initio guided bottom up design of beta-Ti alloys for biomedical applications using a quantum mechanical simulation method in conjunction with experiments. Parameter-free density…

Materials Science · Physics 2008-11-04 D. Raabe , B. Sander , M. Friak , D. Ma , J. Neugebauer

Austenitic stainless steels with low carbon have exceptional mechanical properties and are capable to reduce embrittlement, due to high chromium and nickel alloying, thus they are very attractive for efficient energy production in extreme…

As part of a project to obtain better optical response functions for nano materials and other systems with strong excitonic effects we here calculate the exchange-correlation (XC) potential of density-functional theory (DFT) at a level of…

Other Condensed Matter · Physics 2009-11-13 M. Hellgren , U. von Barth

We use atomistic simulations to investigate grain boundary (GB) phase transitions in el- emental body-centered cubic (bcc) metal tungsten. Motivated by recent modeling study of grain boundary phase transitions in [100] symmetric tilt…

Materials Science · Physics 2018-04-17 Timofey Frolov , Qiang Zhu , Tomas Oppelstrup , Jaime Marian , Robert E. Rudd

It is a long-time pursuit of computations with \emph{ab initio} precision of thermal contributions to phase behaviors of condensed matters under extreme conditions. In this work, the pressure induced structural phase transitions of…

Materials Science · Physics 2022-12-13 Bo-Yuan Ning , Li-Yuan Zhang

Predicting the dramatic changes in material properties caused by irradiation damage is key for the design of future nuclear fission and fusion reactors. Self-ion implantation is an attractive tool for mimicking the effects of neutron…

Computational Physics · Physics 2020-08-26 Suchandrima Das , Hongbing Yu , Kenichiro Mizohata , Edmund Tarleton , Felix Hofmann