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The crystal structure of potassium doped picene with an exact stoichiometry (K3C22H14, K3picene from here onwards) has been theoretically determined within Density Functional Theory allowing complete variational freedom of the crystal…

Materials Science · Physics 2011-10-10 P. L. de Andres , A. Guijarro , J. A. Verges

Alkali doped aromatic compounds have shown evidence of metallic and superconducting phases whose precise nature is still mysterious. In potassium and rubidium doped phenanthrene, superconducting temperatures around 5 K have been detected,…

Materials Science · Physics 2014-08-28 S. Shahab Naghavi , Erio Tosatti

We theoretically explore the crystal structures of K$_x$picene, for which a new aromatic superconductivity has recently been discovered for $x=3$, by systematically performing first-principles full structural optimization covering the…

Superconductivity · Physics 2015-05-30 Taichi Kosugi , Takashi Miyake , Shoji Ishibashi , Ryotaro Arita , Hideo Aoki

Potassium-doped terphenyl has recently attracted attention as a potential host for high-transition-temperature superconductivity. Here, we elucidate the many-body electronic structure of recently synthesized potassium-doped terphenyl…

Strongly Correlated Electrons · Physics 2022-05-03 John Sous , Natalia A. Gadjieva , Colin Nuckolls , David R. Reichman , Andrew J. Millis

The potassium-doped p-terphenyl compounds were synthesized in recent experiments and the superconductivity with high transition temperatures were reported, but the atomic structure of potassium-doped p-terphenyl is unclear. In this paper,…

Superconductivity · Physics 2018-11-27 Xun-Wang Yan , Zhongbing Huang , Miao Gao , Chunfang Zhang

By the first principles calculations and X-ray diffraction simulations, we perform a systematic study of multiple superconducting phases of potassium-doped picene [Nature {\bf464} 76, 2010]. The combination of optimized lattice parameters,…

Superconductivity · Physics 2014-07-04 Xun-Wang Yan , Zhongbing Huang , Hai-Qing Lin

Detailed electronic structure calculations of picene clusters doped by potassium modeling the crystalline K3picene structure show that while two electrons are completely transferred from potassium atoms to the LUMO of pristine picene, the…

Strongly Correlated Electrons · Physics 2015-06-18 G. Chiappe , E. Louis , A. Guijarro , E. San-Fabian , J. A. Verges

We have investigated the evolution of the temperature-dependent conductivity of electron-doped pentacene (PEN) thin films, in which the electron density is controlled by means of potassium (K) intercalation. We find that the conductivity is…

Strongly Correlated Electrons · Physics 2007-05-23 M. F. Craciun , S. Rogge , A. F. Morpurgo

The geometrical and electronic structure of tripotassium doped phenanthrene, \ce{K3C14H10}, have been studied by first-principles density functional theory. The main effect of potassium doping is to inject charge in the narrow phenanthrene…

Materials Science · Physics 2011-11-14 P. L. de Andres , A. Guijarro , J. A. Verges

To explore underlying mechanism for the superconducting phase in recent discovered aromatic hydrocarbons, we carry out the first-principles calculations on benzene, the basic and the simplest unit of the series and examine the structural…

Superconductivity · Physics 2015-01-05 Guohua Zhong , Xiao-Jia Chen , Hai-Qing Lin

Recently, there is a series of reports by Wang et al. on the superconductivity in K-doped p-terphenyl (KxC18H14) with the transition temperatures range from 7 to 123 Kelvin. Identifying the structural and bonding character is the key to…

Superconductivity · Physics 2018-05-24 Guo-Hua Zhong , Xiao-Hui Wang , Ren-Shu Wang , Jia-Xing Han , Chao Zhang , Xiao-Jia Chen , Hai-Qing Lin

A systemically theoretical study has been presented to explored the crystal structures and electronic characteristics of polycyclic aromatic hydrocarbons (PAHs), such as solid phenanthrene, picene, 1,2;8,9-dibenzopentacene, and…

Materials Science · Physics 2015-12-10 Guohua Zhong , Zhongbing Huang , Chao Zhang , Xunwang Yan , Xiaojia Chen , Haiqing Lin

To explore the electronic structure of the first aromatic superconductor, potassium-doped solid picene which has been recently discovered by Mitsuhashi et al with the transition temperatures $T_c=7 - 20$ K, we have obtained a…

Superconductivity · Physics 2015-05-14 Taichi Kosugi , Takashi Miyake , Shoji Ishibashi , Ryotaro Arita , Hideo Aoki

We demonstrate the preparation of large, free standing iron pnictide single crystals with a size up to 20 x 10 x 1 mm3 using solvents in zirconia crucibles under argon atmosphere. Transport and magnetic properties are investigated to study…

Superconductivity · Physics 2011-08-11 G. L. Sun , D. L. Sun , M. Konuma , P. Popovich , A. Boris , J. B. Peng , K. -Y. Choi , P. Lemmens , C. T. Lin

We report a combined theoretical and experimental search for thermoelectric materials based on semiconducting zinc antimony. Influence of three new doping elements (sodium, potassium and boron) on the electronic properties is investigated…

Materials Science · Physics 2014-08-27 K Niedziolka , R Pothin , F Rouessac , R M Ayral , P Jund

We have obtained the first-principles electronic structure of solid coronene, which has been recently discovered to exhibit superconductivity with potassium doping. Since coronene, along with picene, the first aromatic superconductor, now…

Superconductivity · Physics 2015-05-28 Taichi Kosugi , Takashi Miyake , Shoji Ishibashi , Ryotaro Arita , Hideo Aoki

We report electronic structure and physical properties of metal doped picene as well as selective synthesis of the phase exhibiting 18 K superconducting transition. First, Raman scattering is used to characterize the number of electrons…

We investigate electronic transport through pentacene thin-films intercalated with potassium. From temperature-dependent conductivity measurements we find that potassium-intercalated pentacene shows metallic behavior in a broad range of…

Strongly Correlated Electrons · Physics 2009-03-31 M. F. Craciun , G. Giovannetti , S. Rogge , G. Brocks , A. F. Morpurgo , J. van den Brink

The morphology and electronic structure of pentacene (Pn) deposited on Cu(111) was studied using scanning tunneling microscopy (STM) and spectroscopy (STS). Deposition of a multilayer followed by annealing to reduce coverage to a monolayer…

Mesoscale and Nanoscale Physics · Physics 2011-10-24 Joseph Smerdon , Matthias Bode , Nathan Guisinger , Jeffrey Guest

The electronic excitations of manganese phthalocyanine (MnPc) films were studied as a function of potassium doping using electron energy-loss spectroscopy in transmission. Our data reveal doping induced changes in the excitation spectrum,…

Materials Science · Physics 2011-05-20 Benjamin Mahns , Friedrich Roth , Mandy Grobosch , Dietrich R. T. Zahn , Martin Knupfer
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