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The performance of density functional theory (DFT) approximations for predicting materials thermodynamics is typically assessed by comparing calculated and experimentally determined enthalpies of formation from elemental phases, {\Delta}Hf.…

Materials Science · Physics 2019-01-08 Christopher J. Bartel , Alan W. Weimer , Stephan Lany , Charles B. Musgrave , Aaron M. Holder

We show that for any liquid or solid with strong correlation between its $NVT$ virial and potential-energy equilibrium fluctuations, the temperature is a product of a function of excess entropy per particle and a function of density,…

Soft Condensed Matter · Physics 2012-03-13 Trond S. Ingebrigtsen , Lasse Bøhling , Thomas B. Schrøder , Jeppe C. Dyre

Transforming CO$_2$ into methanol represents a crucial step towards closing the carbon cycle, with thermoreduction technology nearing industrial application. However, obtaining high methanol yields and ensuring the stability of…

Chemical Physics · Physics 2025-07-08 Prajwal Pisal , Ondrej Krejci , Patrick Rinke

Predicting the melting temperature (Tm) of multi-component and high-entropy alloys (HEAs) is critical for high-temperature applications but computationally expensive using traditional CALPHAD or DFT methods. In this work, we develop a…

Materials Science · Physics 2026-01-08 Mohd Hasnain

The experimental calorimetric two-state criterion requires the van't Hoff enthalpy $\Delta H_{\rm vH}$ around the folding/unfolding transition midpoint to be equal or very close to the calorimetric enthalpy $\Delta H_{\rm cal}$ of the…

Statistical Mechanics · Physics 2009-09-25 Huseyin Kaya , Hue Sun Chan

An inverse problem for a stationary heat transfer process is studied for a totally isolated bar on its lateral surface, made up of two consecutive sections of different, isotropic and homogeneous materials, perfectly assembly, where one of…

Analysis of PDEs · Mathematics 2021-05-28 Guillermo Federico Umbricht , Diana Rubio , Domingo Alberto Tarzia

We propose a new method to compute the free energy or enthalpy of fluids or disordered solids by computer simulation . The main idea is to construct a reference system by freezing one representative configuration, and then carry out a…

Computational Physics · Physics 2011-03-16 Friederike Schmid , Tanja Schilling

High entropy alloys (HEAs) are promising magnetocaloric materials with tunable operating temperature conditions using compositional modifications. Here, we combine experiments and first principles based spin modelling to engineer…

Advances in next-generation hypersonic hot structures, high heat-flux fusion or fission components, and laser based additive manufacturing depend on reliable solid state thermal conductivity data at high and ultrahigh temperatures, where…

Lattice parameter, electronic structure, mechanical and thermodynamic properties of ThN are systematically studied using the projector-augmented-wave method and the generalized gradient approximation based on the density functional theory.…

Materials Science · Physics 2015-05-20 Yong Lu , Dafang Li , Bao-Tian Wang , Rong-Wu Li , Ping Zhang

Despite vibrational properties being critical for the ab initio prediction of the finite temperature stability and transport properties of solids, their inclusion in ab initio materials repositories has been hindered by expensive…

Transition state calculation is a critical technique to understand and predict versatile dynamical phenomena in solids. However, the transition state results obtained at zero Kelvin are often utilized for prediction or interpretation of…

Materials Science · Physics 2023-11-03 Chengxuan Ke , Chenxi Nie , Guangfu Luo

Conventional barocaloric materials typically exhibit limited operating temperature ranges. In contrast, KPF$_6$ has recently been reported to achieve an exceptional all-temperature barocaloric effect (BCE) via pressure-driven phase…

Materials Science · Physics 2025-11-26 Jiantao Wang , Yi-Chi Zhang , Yan Liu , Hongkun Deng , Mingfeng Liu , Yan Sun , Bing Li , Xing-Qiu Chen , Peitao Liu

Fe II emission lines are observed from nearly all classes of astronomical objects over a wide spectral range from the infrared to the ultraviolet. To meaningfully interpret these lines, reliable atomic data are necessary. In work presented…

Atomic Physics · Physics 2019-03-12 Yier Wan , C. Favreau , S. D. Loch , B. M. McLaughlin , Yueying Qi , P. C. Stancil

Using Ba(Fe$_{0.975}$Co$_{0.025}$)$_2$As$_{2}$ as an exemplar material exhibiting second order electronic-nematic and antiferromagnetic transitions, we present measurements that reveal anomalies in the elastoresistance $\left(\frac{\partial…

Strongly Correlated Electrons · Physics 2019-03-27 Alexander T. Hristov , Matthias S. Ikeda , Johanna C. Palmstrom , Philip Walmsley , Ian R. Fisher

We describe a theoretical and computational approach to calculate the vibrational, elastic, and thermal properties of materials from the low-temperature quantum regime to the high-temperature anharmonic regime. This approach is based on…

Materials Science · Physics 2024-09-20 Dylan A. Folkner , Zekun Chen , Giuseppe Barbalinardo , Florian Knoop , Davide Donadio

Currently existing energy-stable parametric finite element methods for surface diffusion flow and other flows are usually limited to first-order accuracy in time. Designing a high-order algorithm for geometric flows that can also be…

Numerical Analysis · Mathematics 2024-07-15 Meng Li , Yihang Guo , Jingjiang Bi

Phase diagrams are an invaluable tool for material synthesis and provide information on the phases of the material at any given thermodynamic condition. Conventional phase diagram generation involves experimentation to provide an initial…

Coarse-grain Lagrangian methods, such as Dissipative Particle Dynamics ( Hoogerbrugge et al., EPL, 1992), are suitable for describing mesoscopic fluid systems that include thermal fluctuations. However, the realistic simulation of liquids…

Soft Condensed Matter · Physics 2026-03-13 Giuseppe Colella , Allan D. Mackie , James P. Larentzos , Fernando Bresme , Josep Bonet Avalos

Since the internal temperature is less accessible than surface temperature, there is an urgent need to develop accurate and real-time estimation algorithms for better thermal management and safety. This work presents a novel framework for…

Systems and Control · Electrical Eng. & Systems 2025-09-15 Yusheng Zheng , Wenxue Liu , Yunhong Che , Ferdinand Grimm , Jingyuan Zhao , Xiaosong Hu , Simona Onori , Remus Teodorescu , Gregory J. Offer
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