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The issue of the stability of Pickering emulsions is tackled at a mesoscopic level using dissipative particle dynamics simulations within the Adiabatic Biased Molecular Dynamics framework. We consider the early stage of the coalescence…

Soft Condensed Matter · Physics 2017-02-08 François Sicard , Alberto Striolo

We introduce a new experimental approach to study the structural transitions of large numbers of nanoparticle-coated droplets as their volume is reduced. We use an emulsion system where the dispersed phase is slightly soluble in the…

Soft Condensed Matter · Physics 2012-09-28 Sujit S. Datta , Ho Cheung Shum , David A. Weitz

Droplet-based microfluidics has emerged as a powerful technology for the miniaturization and automation of biochemical assays. The replacement of surfactants by nanoparticles as interfacial stabilizers has gained increasing interest.…

Soft Condensed Matter · Physics 2019-06-21 Laura Andreina Chacon Orellana , Jean-Christophe Baret

We propose diagrams representing the equilibrium morphologies of two immiscible liquid droplets brought into contact. We study the dependence of the shape of the droplets on the surface tensions and ratio of volumes. We study theoretically…

Soft Condensed Matter · Physics 2014-09-25 J. Guzowski , P. Garstecki , P. Korczyk

The transport and deformation of confined droplets and flexible capsules are central to diverse phenomena and applications, from biological flows in microcapillaries to industrial processes in porous media. Inspired by experiments, we…

Deformed droplets are ubiquitous in various industrial applications, such as inkjet printing, lab-on-a-chip devices, and spray cooling, and can fundamentally affect the involved applications both favorably and unfavorably. Here, we employ…

The stability of shapes formed by three viscoelastic droplets during their arrested coalescence has been investigated using micromanipulation experiments. Addition of a third droplet to arrested droplet doublets is shown to be controlled by…

Motivated by recent experiments, we consider theoretically the compression of droplets pinned at the bottom on a surface of finite area. We show that if the droplet is sufficiently compressed at the top by a surface, it will always develop…

Fluid Dynamics · Physics 2017-08-03 Gwynn J. Elfring , Eric Lauga

We use molecular dynamics simulations to study the dynamics of Janus particles, micro- or nanoparticles which are not spherically symmetric, in the uniform flow of a simple liquid. In particular we consider spheres with an asymmetry in the…

Fluid Dynamics · Physics 2016-06-10 Aurelien Y. M. Archereau , Shaun C. Hendy , Geoff. R. Willmott

Self-assembly of nanoparticles at fluid-fluid interfaces is a promising route to fabricate functional materials from the bottom-up. However, directing and controlling particles into highly tunable and predictable structures -- while…

Soft Condensed Matter · Physics 2019-09-25 Qingguang Xie , Gary B. Davies , Jens Harting

In recent decades novel solid substrates have been designed which change their wettability in response to light or an electrostatic field. Here, we investigate a droplet on substrates with oscillating uniform wettability by varying minimium…

Fluid Dynamics · Physics 2021-10-28 Josua Grawitter , Holger Stark

Cooled oil emulsion droplets in aqueous surfactant solution have been observed to flatten into a remarkable host of polygonal shapes with straight edges and sharp corners, but different driving mechanisms - (i) a partial phase transition of…

Soft Condensed Matter · Physics 2019-09-25 Pierre A. Haas , Diana Cholakova , Nikolai Denkov , Raymond E. Goldstein , Stoyan K. Smoukov

The atomisation of suspension containing liquid and dispersed particles is prevalent in many applications. Previous studies of droplet breakup mainly focused on homogeneous fluids, and the heterogeneous effect of particles on the breakup…

Fluid Dynamics · Physics 2024-03-19 Zhikun Xu , Tianyou Wang , Zhizhao Che

Controlling the shape and position of moving and pinned droplets on a solid surface is an important feature often found in microfluidic applications. However, automating them, e.g., for high-throughput applications, does rarely involve…

Fluid Dynamics · Physics 2020-07-09 Henning Bonart , Christian Kahle , Jens-Uwe Repke

Curved fluid interfaces are investigated on the nanometre length scale by molecular dynamics simulation. Thereby, droplets surrounded by a metastable vapour phase are stabilized in the canonical ensemble. Analogous simulations are conducted…

We show that energy dissipation partition between a liquid and a solid controls the shape and stability of droplets sliding on viscoelastic gels. When both phases dissipate energy equally, droplet dynamics is similar to that on rigid…

Soft Condensed Matter · Physics 2024-02-20 Mathieu Oléron , Laurent Limat , Julien Dervaux , Matthieu Roché

Droplet deposition onto a hydrophobic surface is studied experimentally and numerically. A wide range of droplet sizes can result from the same syringe, depending strongly on the needle retraction speed. Three regimes are identified…

Fluid Dynamics · Physics 2015-05-13 Bian Qian , Melissa Loureiro , David Gagnon , Anubhav Tripathi , Kenneth S. Breuer

Motivated by the buckling of glassy crusts formed on evaporating droplets of polymer and colloid solutions, we numerically model the deformation and buckling of spherical elastic caps controlled by varying the volume between the shell and…

Materials Science · Physics 2009-11-11 D. A. Head

Nanometer-sized clusters are often targeted due to their potential applications as nanoreactors or storage/delivery devices. One route to assemble and stabilize finite structures consists in imparting directional bonding patterns between…

Soft Condensed Matter · Physics 2024-06-13 Carlo Andrea De Filippo , Sara Del Galdo , Emanuela Bianchi , Cristiano De Michele , Barbara Capone

We investigate the mechanical behavior of particle-stabilized droplets using micropipette aspiration. We observe that droplets stabilized with amphiphilic dumbbell-shaped particles exhibit a two-stage response to increasing suction…

Soft Condensed Matter · Physics 2017-01-25 Niveditha Samudrala , Jin Nam , Raphael Sarfati , Robert W. Style , Eric R. Dufresne
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