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Ferromagnetic shape memory alloys Ni$_{2+x}$Mn$_{1-x}$Ga were studied in the range of compositions $0.16 \le x \le 0.36$. Experimental phase diagram, constructed from differential scanning calorimetry, transport and magnetic measurements,…

Using first-principles calculations based on density functional theory, we have studied the mechanical, electronic, and magnetic properties of Heusler alloys, namely, Ni$_{2}BC$ and Co$_{2}BC$ ($B$ = Sc, Ti, V, Cr and Mn as well as Y, Zr,…

Materials Science · Physics 2016-05-18 Tufan Roy , Dhanshree Pandey , Aparna Chakrabarti

Ni-Mn-based Heusler alloys, in particular all-d-metal Ni(-Co)-Mn-Ti, are highly promising materials for energy-efficient solid-state refrigeration as large multicaloric effects can be achieved across their magnetostructural martensitic…

The effect of Co on the structural, magnetic and magnetocaloric effect (MCE) of Ni50-xCoxMn38Sb12 (x=0,2,3,4,5) Heusler alloys was studied. Using x-ray diffraction, we show the evolution of the martensitic phase from the austenite phase.…

Strongly Correlated Electrons · Physics 2010-06-02 Ajaya K Nayak , K G Suresh , A K Nigam

Besides permitting an accurate determination of the ferromagnetic-to-paramagnetic phase transition temperature and the characteristic temperatures for the beginning and end of the growth of martensite (austenite) phase at the expense of…

Materials Science · Physics 2009-11-13 P. K. Mukhopadhyay , S. N. Kaul

The structural transitions, magnetic properties, and electronic structures of Co(Fe)-doped MnNiSi compounds are investigated by x-ray powder diffraction (XRD), differential scanning calorimetry (DSC), magnetic measurements, and…

Materials Science · Physics 2015-04-17 Y. Li , Z. Y. Wei , E. K. Liu , G. D. Liu , S. G. Wang , W. H. Wang , G. H. Wu

Martensitic transition temperature steadily decreases in Ni$_{2-x}$Fe$_{x}$Mn$_{1.5}$In$_{0.5}$ and is completely suppressed at $x$ = 0.2. Despite suppression of martensitic transition, Ni$_{1.8}$Fe$_{0.2}$Mn$_{1.5}$In$_{0.5}$ does not…

Materials Science · Physics 2020-04-02 R. Nevgi , Gangadhar Das , M. Acet , K. R. Priolkar

7M orthorhombic modulated structure in the martensite phase of Ni1.8Pt0.2MnGa is reported by powder neutron diffraction study, which indicates that it is likely to exhibit magnetic field induced strain. The change in the unit cell volume is…

Materials Science · Physics 2012-11-02 Sanjay Singh , K. R. A. Ziebeck , E. Suard , P. Rajput , S. Bhardwaj , A. M. Awasthi , S. R. Barman

We study the thermal properties of a bulk Ni55Fe19Ga26 Heusler alloy in a conduction calorimeter. At slow heating and cooling rates (1K/h), we compare as-cast and annealed samples. We report a smaller thermal hysteresis after the thermal…

Neutron diffraction measurements, performed in presence of an external magnetic field, have been used to show structural evidence for the kinetic arrest of the first-order phase transition from (i) the high temperature austenite phase to…

Materials Science · Physics 2013-11-14 V. Siruguri , P. D. Babu , S. D. Kaushik , Aniruddha Biswas , S. K. Sarkar , K. Madangopal , P. Chaddah

Magnetocaloric effect (MCE), magnetization, specific heat, and magnetostriction measurements were performed in both pulsed and steady high magnetic fields to investigate the magnetocaloric properties of Heusler alloys Ni50-xCoxMn31.5Ga18.5…

Materials Science · Physics 2021-03-24 T. Kihara , T. Roy , X. Xu , A. Miyake , M. Tsujikawa , H. Mitamura , M. Tokunaga , Y. Adachi , T. Eto , T. Kanomata

The irreversibility of the martensite transition in magnetic shape memory alloys (MSMAs) with respect to external magnetic field is one of the biggest challenges that limits their application as giant caloric materials. This transition is a…

We report a systematic study on the magneto-structural transition in Mn-rich Fe-doped Mn-Fe-Ni-Sn(Sb/In) Heusler alloys by keeping the total valence electron concentration (e/a ratio) fixed. The martensitic transition (MT) temperature is…

Materials Science · Physics 2019-01-30 Arup Ghosh , Rajeev Rawat , Arpan Bhattacharyya , Guruprasad Mandal , A. K. Nigam , Sunil Nair

We have synthesized a nominal composition of Ni50Mn30Sn20 alloy using arc melting technique. Rietveld refinement confirms the austenite L21 structure in Fm-3m space group. Electrical resistivity has been found to clearly exhibiting two…

Strongly Correlated Electrons · Physics 2015-11-06 Ramesh Chandra Bhatt , R. S. Meena , H. Kishan , V. P. S. Awana , S. K. Agarwal

Magnetic, transport, and x-ray diffraction measurements of ferromagnetic shape memory alloy Ni$_{2.16}$Mn$_{0.84}$Ga revealed that this alloy undergoes an intermartensitic transition upon cooling, whereas no such a transition is observed…

Materials Science · Physics 2009-11-10 V. V. Khovailo , K. Oikawa , C. Wedel , T. Takagi , T. Abe , K. Sugiyama

Present work reports on the observation of multiple magnetic transitions in a Ni-excess ferromagnetic shape memory alloy with nominal composition Ni$_{2.048}$Mn$_{1.312}$In$_{0.64}$. The magnetization data reveal two distinct thermal…

Materials Science · Physics 2016-02-17 S. Pramanick , P. Dutta , S. Chatterjee , S. Giri , S. Majumdar

The crystal structures, martensitic structural transitions and magnetic properties of MnCo1-xFexSi (0 <= x <= 0.50) alloys were studied by differential scanning calorimetry (DSC), x-ray powder diffraction (XRD) and magnetic measurements. In…

Materials Science · Physics 2015-04-17 J. H. Chen , Z. Y. Wei , E. K. Liu , X. Qi , W. H. Wang , G. H. Wu

The large magnetocaloric effect (MCE) observed in Ni-Mn based shape-memory Heusler alloys put them forward to use in magnetic refrigeration technology. It is associated with a first-order magnetostructural (martensitic) phase transition. We…

Materials Science · Physics 2020-04-03 P. Devi , M. Ghorbani Zavareh , C. Salazar Mejia , K. Hofmann , B. Albert , C. Felser , M. Nicklas , Sanjay Singh

Shape memory alloys inherit their macroscopic properties from their mesoscale microstructure originated from the martensitic phase transformation. In a cubic to orthorhombic transition, a single variant of marten- site can have a compatible…

Materials Science · Physics 2020-09-23 Oguz Umut Salman , Alphonse Finel , Remi Delville , Dominique Schryvers

The reverse martensitic ("austenitic") transformation upon heating of equiatomic nickel-titanium nanoparticles with diameters between 4 and 17 nm is analyzed by means of molecular-dynamics simulations with a semi-empirical model potential.…

Materials Science · Physics 2022-01-04 Daniel Mutter , Peter Nielaba