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Grain boundary (GB) enthalpies in nanocrystalline (NC) $\mathrm {Pd_{90}Au_{10}}$ are studied after preparation, thermal relaxation and plastic deformation. By comparing results from atomistic computer simulations and calorimetry, we show…

Materials Science · Physics 2014-12-10 Michael Johannes Deckarm , Jonathan Schäfer , Karsten Albe , Rainer Birringer

Local chemical ordering strongly influences the behavior of complex concentrated alloys, yet its characterization remains challenging due to the nanoscale dimensions and scattered spatial distribution of the ordered domains. Here, we study…

Materials Science · Physics 2026-02-10 Ian Geiger , Yuan Tian , Ying Han , Yutong Bi , Xiaoqing Pan , Penghui Cao , Timothy J. Rupert

Intergranular attack of alloys under hydrothermal conditions is a complex problem that depends on metal and oxygen transport kinetics via solid-state and channel-like pathways to an advancing oxidation front. Experiments reveal very…

Chemical Physics · Physics 2018-09-03 Zhijie Xu , Dongsheng Li , Daniel K. Schreiber , Kevin M. Rosso , Stephen M. Bruemmer

For its potential as a catalyst, nanoporous gold (NPG) prepared through dealloying of bulk Ag-Au alloys has been extensively investigated. NPG thin films can offer ease of handling, better tunability of the chemistry and microstructure of…

Solute segregation in materials with grain boundaries (GBs) has emerged as a popular method to thermodynamically stabilize nanocrystalline structures. However, the impact of varied GB crystallographic character on solute segregation has…

Materials Science · Physics 2025-03-10 Lydia Harris Serafin , Ethan R. Cluff , Gus L. W. Hart , Eric R. Homer

The effect of slip transfer on the deformation mechanisms of Al bicrystals was explored using a rate-dependent dislocation-based crystal plasticity model. Three different types of grain boundaries (GBs) were included in the model by…

Materials Science · Physics 2020-01-27 S. Haouala , R. Alizadeh , T. R. Bieler , J. Segurado , J. LLorca

Grain boundaries have been shown to dramatically influence the behavior of relatively simple materials such as monatomic metals and binary alloys. The increased chemical complexity associated with multi-principal element alloys is…

To investigate the barrier effect of grain boundaries on the propagation of avalanche-like plasticity at the atomic-scale, we perform three-dimensional molecular dynamics simulations by using simplified polycrystal models including…

Materials Science · Physics 2017-01-19 Tomoaki Niiyama , Tomotsugu Shimokawa

Practical high temperature superconductors must be textured to minimize the reduction of the critical current density $J_{gb}$ at misoriented grain boundaries. Partial substitution of Ca for Y in $YBa_2Cu_3O_{7-\delta}$ has shown…

Materials Science · Physics 2007-05-23 Xueyan Song , George Daniels , D. Matt Feldmann , Alex Gurevich , David Larbalestier

Chromium depletion at grain boundaries (GBs) due to selective attack is a critical issue in the molten salt corrosion of NiCr alloys. Despite the importance of GBs in this process from numerous experimental studies, most theoretical work…

Materials Science · Physics 2025-04-29 Hamdy Arkoub , Miaomiao Jin

We present calculations of diffusion coefficients in grain boundaries in Yukawa crystals for astrophysics. Our methods follow from our recent work calculating diffusion coefficients in perfect body-centered cubic crystals. These diffusion…

A FePd alloy was nanostructured by severe plastic deformation following two different routes: ordered and disordered states were processed by high pressure torsion (HPT). A grain size in a range of 50 to 150 nm is obtained in both cases.…

High entropy alloys (HEAs) have emerged as a new class of multicomponent materials, which have potential for high temperature applications. Phase stability and creep deformation, two key selection criteria for high temperature materials,…

Materials Science · Physics 2017-07-14 M. Vaidya , K. G. Pradeep , B. S. Murty , G. Wilde , S. V. Divinski

The mobility of lighter species on the surface of interstellar dust grains plays a crucial role in forming simple through complex molecules. Carbon monoxide is one of the most abundant molecules, its surface diffusion on the grain surface…

Astrophysics of Galaxies · Physics 2022-03-30 Kinsuk Acharyya

Grain Boundary (GB) deformation mechanisms such as Sliding (GBS) and Opening (GBO) are prevalent in alloys at high homologous temperatures but are hard to capture quantitatively. We propose an automated procedure to quantify 3D GB…

Materials Science · Physics 2025-07-24 C. J. A. Mornout , G. Slokker , T. Vermeij , D. König , J. P. M. Hoefnagels

The processing of binary alloys consisting of ferromagnetic Fe and antiferromagnetic Cr by severe plastic deformation (SPD) with different chemical compositions has been investigated. Although the phase diagram exhibits a large gap in the…

Materials Science · Physics 2021-01-12 Lukas Weissitsch , Martin Stückler , Stefan Wurster , Reinhard Pippan , Andrea Bachmaier

Grain boundaries (GBs) in oxide perovskites significantly influence their functional properties. This study examines the atomic-scale structure and composition of a faceted asymmetric grain boundary in strontium titanate (SrTiO$_3$) using…

Abbreviation. Thermal diffusion is one of the basic processes for the mobility and formation of species on cosmic dust grains. Recent laboratory measurements have found that the diffusion pre-exponential factor can differ from that for…

Astrophysics of Galaxies · Physics 2024-05-09 Long-Fei Chen , Donghui Quan , Jiao He , Yao Wang , Di Li , Thomas Henning

The slip behavior of dislocations and grain boundaries critically governs recrystallization and plastic deformation in Mg alloys and can be strongly influenced by solutes. However, the quantitative effects of solute distribution on defect…

Nanocrystalline silicon and silicon-germanium alloys are promising thermoelectric materials that have achieved substantially improved figure of merits compared to their bulk counterparts. This enhancement is typically attributed to a…

Mesoscale and Nanoscale Physics · Physics 2015-06-19 Chengyun Hua , Austin J. Minnich