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To improve the efficiency of Gaussian integral evaluation on modern accelerated architectures FLOP-efficient Obara-Saika-based recursive evaluation schemes are optimized for the memory footprint. For the 3-center 2-particle integrals that…

Computational Physics · Physics 2024-07-30 Andrey Asadchev , Edward F. Valeev

By using Poisson's summation formula, we calculate periodic integrals over Gaussian basis functions by partitioning the lattice summations between the real and reciprocal space, where both sums converge exponentially fast with a large…

Strongly Correlated Electrons · Physics 2021-04-06 Sandeep Sharma , Gregory Beylkin

We present a high-performance evaluation method for 4-center 2-particle integrals over Gaussian atomic orbitals with high angular momenta ($l\geq4$) and arbitrary contraction degrees on graphical processing units (GPUs) and other…

Computational Physics · Physics 2023-12-20 Andrey Asadchev , Edward F. Valeev

Evaluating multi-center molecular integrals with Cartesian Gaussian-type basis sets has been a long-standing bottleneck in electronic structure theory calculation for solids and molecules. We have developed a vector-coupling and…

Quantum Physics · Physics 2024-05-17 Hang Hu , Gilles Peslherbe , Hsu Kiang Ooi , Anguang Hu

We extend the tight distance-dependent estimator proposed by Hollman et al. [J. Chem. Phys. 142, 154106 (2015)] for the three-center Coulomb integrals over Gaussian atomic orbitals to handle the two-center case. We also propose minor…

Chemical Physics · Physics 2024-07-30 Edward F. Valeev , Toru Shiozaki

In this paper, which constitutes the first part of the series, we consider calculation of two-centre Coulomb and hybrid integrals over Slater-type orbitals (STOs). General formulae for these integrals are derived with no restrictions on the…

Quantum Physics · Physics 2015-01-09 Michał Lesiuk , Robert Moszynski

We implement an efficient method of computation of two dimensional Fourier-type integrals based on approximation of the integrand by Gaussian radial basis functions, which constitute a standard tool in approximation theory. As a result, we…

Numerical Analysis · Mathematics 2022-02-07 A. Martinez-Finkelshtein , D. Ramos-Lopez , D. R. Iskander

We present a purely numerical approach in Cartesian grid, for efficient computation of Hartree-Fock (HF) exchange contribution in the HF and density functional theory models. This takes inspiration from a recently developed algorithm [Liu…

Chemical Physics · Physics 2019-04-05 Abhisek Ghosal , Tanmay Mandal , Amlan K. Roy

We have developed a McMurchie-Davidson-like recursion formula for efficient evaluation of the Coulomb attraction and interaction matrix elements between two-dimensional primitive Cartesian Gaussian type orbitals. We also present recurrence…

Computational Physics · Physics 2021-11-30 Øyvind Sigmundson Schøyen , Håkon Emil Kristiansen , Alfred Alocias Mariadason

We present an object-oriented programming (OOP) CUDA-based package for fast and accurate simulation of second-harmonic generation (SHG) efficiency using focused Gaussian beams. The model includes linear as well as two-photon absorption that…

Optics · Physics 2024-10-08 A. D. Sanchez , S. Chaitanya Kumar , M. Ebrahim-Zadeh

We develop efficient numerical integration methods for computing an integral whose integrand is a product of a smooth function and the Gaussian function with a small standard deviation. Traditional numerical integration methods applied to…

Numerical Analysis · Mathematics 2018-04-12 Yunyun Ma , Yuesheng Xu

When applying Hamiltonian operator splitting methods for the time integration of multi-species Vlasov-Maxwell-Landau systems, the reliable and efficient numerical approximation of the Landau equation represents a fundamental component of…

Numerical Analysis · Mathematics 2025-12-23 Jose Antonio Carrillo , Mechthild Thalhammer

A new estimator for three-center two-particle Coulomb integrals is presented. Our estimator is exact for some classes of integrals and is much more efficient than the standard Schwartz counterpart due to the proper account of distance…

Chemical Physics · Physics 2015-09-02 David S. Hollman , Henry F. Schaefer , Edward F. Valeev

A new method is introduced which uses higher-order Laplace approximation to evaluate functional integrals much faster than existing methods. An implementation in MATLAB is called SLAM-FIT (Sparse Laplace Approximation Method for Functional…

Computation · Statistics 2016-06-27 John Tillinghast

We present a numerical algorithm for evaluating the Boltzmann collision operator with $O(N^2)$ operations based on high order discontinuous Galerkin discretizations in the velocity variable. To formulate the approach, Galerkin projection of…

Numerical Analysis · Mathematics 2018-01-19 Alexander Alekseenko , Jeffrey Limbacher

In this study, using the analytical and recurrence relations suggested by the authors in previous works, the new efficient and reliable program procedure for the overlap integrals over Slater type orbitals (STOs) is presented. The proposed…

Chemical Physics · Physics 2015-05-13 I. I. Guseinov , B. A. Mamedov

A fast algorithm (linear in the degrees of freedom) for the solution of linear variable-coefficient rational-order fractional integral and differential equations is described. The approach is related to the ultraspherical method for…

Numerical Analysis · Mathematics 2017-12-04 Nicholas Hale , Sheehan Olver

In the wake of many new ML-inspired approaches for reconstructing and representing high-quality 3D content, recent hybrid and explicitly learned representations exhibit promising performance and quality characteristics. However, their…

Computer Vision and Pattern Recognition · Computer Science 2024-06-03 Stavros Diolatzis , Tobias Zirr , Alexandr Kuznetsov , Georgios Kopanas , Anton Kaplanyan

Slater basis functions have desirable properties that can improve electronic structure simulations, but improved numerical integration methods are needed. This work builds upon the SlaterGPU library for evaluation of Hamiltonian matrix…

Chemical Physics · Physics 2025-10-20 Alexander Stark , Nathan Meier , Jeffrey Hatch , Joshua Kammeraad , Duy-Khoi Dang , Paul Zimmerman

We introduce an accurate and efficient method for a class of nonlocal potential evaluations with free boundary condition, including the 3D/2D Coulomb, 2D Poisson and 3D dipolar potentials. Our method is based on a Gaussian-sum approximation…

Computational Physics · Physics 2016-12-09 Lukas Exl , Norbert J. Mauser , Yong Zhang
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