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Titanium dioxide (TiO$_2$) thin films are commonly used as photocatalytic materials. Here, we enhance the photocatalytic activity of devices based on TiO$_2$ by combining nanostructured glass substrates with metallic plasmonic…

Close inspection of the pre-edge in oxygen near-edge x-ray absorption fine structure spectra of single step, gas phase synthesized titanium oxynitride photocatalysts with 20 nm particle size reveals an additional eg resonance in the VB that…

CO$_2$ photoreduction on photocatalysts is a nature-friendly solution to decrease the CO$_2$ amount, but the method still has low efficiency because of difficult separation and easy recombination of charge carriers in available catalysts.…

Sensing response of individual single-crystal titania nanowires configured as chemiresistors for detecting reducing (CO, H2) and oxidizing (O2) gases is shown to be sensitive to visible light illumination. It is assumed that doping of the…

Mesoscale and Nanoscale Physics · Physics 2015-01-09 Jie Zhang , Evgheni Strelcov , Andrei Kolmakov

In this letter, we propose that the narrowband photodetection can be realized in the skin layer of semiconductors with the spatially separated photo-excited carriers from the nanoscale heterolattice electronic transitions (NanoHLETs). The…

Mesoscale and Nanoscale Physics · Physics 2021-07-21 Zhipeng Wei , Xuan Fang , Peter Y. Yu , Jiaxu Yan , Dengkui Wang , Jilong Tang , Kewei Liu , Hai Xu , Xaiobo Chen , Lei Liu , D. Z. Shen

This work reports a pulsed laser-assisted synthesis, detailed structural characterization, and study of plasmonic properties of three sets of TiN/TiNO thin films with high electron density. The first two sets of TiN films were grown at 600C…

A simple refluxing wet-chemical approach is employed for fabricating In2S3/Pt-TiO2 heterogeneous catalysts for hydrogen generation under visible light irradiation. When the mass ratio between Pt-TiO2 and cubic-phased In2S3 (denoted as…

Surface fluorination of TiO$_2$ (F-TiO$_2$) has complicate photocatalytic behavior in degradation of organic compounds. This work attempts to establish an elegant scenario based on the band model to understand this behavior. Density…

Materials Science · Physics 2017-11-21 Huimin Gao , Daoyu Zhang , Minnan Yang , Shuai Dong

In two-dimensional materials research, oxidation is usually considered as a common source for the degradation of electronic and optoelectronic devices or even device failure. However, in some cases a controlled oxidation can open the…

We investigate the quasiparticle band structure of anatase TiO2, a wide gap semiconductor widely employed in photovoltaics and photocatalysis. We obtain GW quasiparticle energies starting from density-functional theory (DFT) calculations…

Materials Science · Physics 2012-04-23 Christopher E. Patrick , Feliciano Giustino

We have measured photoemission spectra of two kinds of TiO$_2$-capped VO$_2$ thin films, namely, that with rutile-type TiO$_2$ (r-TiO$_2$/VO$_2$) and that with amorphous TiO$_2$ (a-TiO$_2$/VO$_2$) capping layers. Below the Metal-insulator…

Strongly Correlated Electrons · Physics 2009-11-11 K. Maekawa , M. Takizawa , H. Wadati , T. Yoshida , A. Fujimori , H. Kumigashira , M. Oshima , Y. Muraoka , Y. Nagao , Z. Hiroi

The clean production of hydrogen as a zero-emission fuel can be done using photocatalysis, with TiO2 being one of the most promising photocatalysts. However, the activity of TiO2 anatase and rutile phases is still limited. In this study, an…

Materials Science · Physics 2025-08-19 Jacqueline Hidalgo-Jimenez , Taner Akbay , Tatsumi Ishihara , Kaveh Edalati

An attractive class of materials for photo(electro)chemical reactions are hybrids based on semiconducting metal oxides and nanocarbons (e.g. carbon nanotubes (CNT), graphene), where the nanocarbon acts as a highly-stable conductive scaffold…

The rutile TiO$_2$ (110) surface reduced by the bridging oxygen vacancy, bridging hydroxyl group or Ti interstitial atom has been investigated by calculating their electronic structures using the density functional theory plus U method. It…

Materials Science · Physics 2015-10-13 Daoyu Zhang , Minnan Yang , Shuai Dong

Titanium dioxide (TiO2) is a known photocatalyst with a capability of decomposing organic substance. However, the photocatalysis of the pure TiO2 is not effective for the indoor environment due to a lack of the ultraviolet irradiation…

Applied Physics · Physics 2019-05-17 Zhuoying Jiang , Xiong Yu

The electronic properties of quasi-one-dimensional anatase TiO2 nanostructures, in the form of thin nanowires having (101) and (001) facets, have been systematically investigated using the standard, hybrid density functional and…

Mesoscale and Nanoscale Physics · Physics 2014-07-08 Hatice Unal , Oguz Gulseren , Sinasi Ellialtioglu , Ersen Mete

Using an organometallic precursor, TiO$_2$ coatings were fabricated on surfaces of quartz, zircon and rutile sands. X ray Diffraction, X ray Fluorescence, UV Vis spectroscopy and surface area measurement were used to characterise support…

Materials Science · Physics 2021-06-08 Dorian A. H. Hanaor , Charles C. Sorrell

We address one of the main challenges to TiO2-photocatalysis, namely band gap narrowing, by combining nanostructural changes with doping. With this aim we compare TiO2's electronic properties for small 0D clusters, 1D nanorods and…

Materials Science · Physics 2010-01-18 D. J. Mowbray , J. I. Martinez , J. M. García-Lastra , K. S. Thygesen , K. W. Jacobsen

Titanium dioxide (TiO2) is a wide-gap semiconductor with numerous applications in photocatalysis, photovoltaics, and neuromorphic computing. The unique functional properties of this material critically depend on its ability to transport…

Materials Science · Physics 2024-11-26 Zhenbang Dai , Feliciano Giustino

Narrow-bandgap III-V semiconductor nanowires (NWs) with a suitable band structure and strong light-trapping ability are ideal for high-efficiency low-cost solar water-splitting systems. However, due to their nanoscale dimension, they suffer…