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Work fluctuations and work probability distributions are fundamentally different in systems with short- ranged versus long-ranged correlations. Specifically, in systems with long-ranged correlations the work distribution is extraordinarily…

Statistical Mechanics · Physics 2018-04-18 J. K. Bhattacharjee , T. R. Kirkpatrick , J. V. Sengers

Nonequilibrium systems exchange the energy with an environment in the form of work and heat. The work done on a system obeys the fluctuation theorem, while the dissipated heat which differs from the work by the internal energy change does…

Statistical Mechanics · Physics 2014-02-04 Jae Dong Noh

The characteristic function of the work performed by an external time-dependent force on a Hamiltonian quantum system is identified with the time-ordered correlation function of the exponentiated system's Hamiltonian. A similar expression…

Statistical Mechanics · Physics 2009-11-13 Peter Talkner , Eric Lutz , Peter Hanggi

We study the work fluctuations of two types of finite quantum spin chains under the application of a time-dependent magnetic field in the context of the fluctuation relation and Jarzynski equality. The two types of quantum chains correspond…

Statistical Mechanics · Physics 2008-05-30 Sven Dorosz , Thierry Platini , Dragi Karevski

Long-ranged, or power-law, behavior of correlation functions in both space and time is discussed for classical systems and for quantum systems at finite temperature, and is compared with the corresponding behavior in quantum systems at zero…

Statistical Mechanics · Physics 2009-10-28 T. R. Kirkpatrick , D. Belitz

Approximate expressions for correlation functions in binary inhomogeneous mixtures are derived in a framework of the mesoscopic theory [Ciach A., Mol. Phys., 2011, {\textbf{109}}, 1101]. Fluctuation contribution is taken into account in a…

Soft Condensed Matter · Physics 2020-05-26 A. Ciach , O. Patsahan , A. Meyra

The classical Jarzynski equality establishes an exact relation between the stochastic work performed on a system driven out of thermal equilibrium and the free energy difference in a corresponding quasi-static process. This fluctuation…

Quantum Physics · Physics 2025-08-21 Konstantin Beyer , Walter T. Strunz

This is a brief review of recently derived relations describing the behaviour of systems far from equilibrium. They include the Fluctuation Theorem, Jarzynski's and Crooks' equalities, and an extended form of the Second Principle for…

Statistical Mechanics · Physics 2009-11-11 Jorge Kurchan

Fluctuation theorems are fundamental extensions of the second law of thermodynamics for small nonequilibrium systems. While work and heat are equally important forms of energy exchange, fluctuation relations have not been experimentally…

Statistical Mechanics · Physics 2022-02-24 Markus Rademacher , Michael Konopik , Maxime Debiossac , David Grass , Eric Lutz , Nikolai Kiesel

A recent theorem giving the initial behavior of very short-time fluctuations of particle displacements in classical many-body systems is discussed. It has applications to equilibrium and non-equilibrium systems, one of which is a series…

Statistical Mechanics · Physics 2007-07-31 Ramses van Zon , S. S. Ashwin , E. G. D. Cohen

We use dynamic equations to derive a relation between correlation functions and response or relaxation functions in many-body systems. The relation is very general and holds both in equilibrium, when the usual fluctuation-dissipation…

Statistical Mechanics · Physics 2024-07-09 T. R. Kirkpatrick , D. Belitz

We consider in this paper, a few important issues in non-equilibrium work fluctuations and their relations to equilibrium free energies. First we show that Jarzynski identity can be viewed as a cumulant expansion of work. For a switching…

Statistical Mechanics · Physics 2015-05-20 M Suman Kalyan , G Anjan Prasad , V S S Sastry , K P N Murthy

We study the dynamics of density fluctuations in purely diffusive systems away from equilibrium. Under some conditions the static density correlation function becomes long-ranged. We then analyze this behavior in the framework of…

Condensed Matter · Physics 2009-10-22 I. Pagonabarraga , M. Rubi

We compare the fluctuation relations for work and entropy in underdamped and overdamped systems, when the friction coefficient of the medium is space-dependent. We find that these relations remain unaffected in both cases. However, for the…

Statistical Mechanics · Physics 2015-06-15 Sourabh Lahiri , Shubhashis Rana , A. M. Jayannavar

There are only a very few known relations in statistical dynamics that are valid for systems driven arbitrarily far-from-equilibrium. One of these is the fluctuation theorem, which places conditions on the entropy production probability…

Statistical Mechanics · Physics 2009-09-25 Gavin E. Crooks

Thermodynamics constrains changes to the energy of a system, both deliberate and random, via its first and second laws. When the system is not in equilibrium, fluctuation theorems such as the Jarzynski equality further restrict the…

Traditionally, it is understood that fluctuations in the equilibrium distribution are not evident in thermodynamic systems of large $N$ (the number of particles in the system) \cite{Huang1}. In this paper we examine the validity of this…

Mathematical Physics · Physics 2007-10-03 Kieran Kelly , Przemysław Repetowicz , Seosamh macRéamoinn

We review generalized Fluctuation-Dissipation Relations which are valid under general conditions even in ``non-standard systems'', e.g. out of equilibrium and/or without a Hamiltonian structure. The response functions can be expressed in…

Statistical Mechanics · Physics 2019-09-10 A. Sarracino , A. Vulpiani

The Fluctuation Theorems are a group of exact relations that remain valid irrespective of how far the system has been driven away from equilibrium. Other than having practical applications, like determination of equilibrium free energy…

Statistical Mechanics · Physics 2016-11-04 Sourabh Lahiri , A. M. Jayannavar

We present a fluctuation relation for heat dissipation in a nonequilibrium system. A nonequilibrium work is known to obey the fluctuation theorem in any time interval $t$. A heat, which differs from a work by an energy change, is shown to…

Statistical Mechanics · Physics 2012-06-19 Jae Dong Noh , Jong-Min Park
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