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Electronic structure methods for accurate calculation of molecular properties have a high cost that grows steeply with the problem size, therefore, it is helpful to have the underlying atomic basis functions that are less in number but of…

Chemical Physics · Physics 2019-03-15 Dimitri N. Laikov

The potential-energy and quadrupole-moment functions of the H$_2$ ground electronic state are well known in literature (Komasa et al., 2019; Wolniewicz et al., 1998), and the line list of the vibrational-rotational transitions was…

Chemical Physics · Physics 2023-08-22 V. G. Ushakov , S. A. Balashev , E. S. Medvedev

I construct the spectral function of the Luther-Emery model which describes one-dimensional fermions with one gapless and one gapped degree of freedom, i.e. superconductors and Peierls and Mott insulators, by using symmetries, relations to…

Strongly Correlated Electrons · Physics 2009-10-31 Johannes Voit

We study observables in a conformal field theory which are very closely related to the ones used to describe hadronic events at colliders. We focus on the correlation functions of the energies deposited on calorimeters placed at a large…

High Energy Physics - Theory · Physics 2009-10-16 Diego M. Hofman , Juan Maldacena

We consider neutral- and charged-current Drell Yan lepton-pair production at hadron colliders, and include dominant classes of electroweak and mixed QCD-electroweak corrections to all orders in perturbation theory. The accurate description…

High Energy Physics - Phenomenology · Physics 2024-04-24 Luca Buonocore , Luca Rottoli , Paolo Torrielli

A new reference state for density functional theory, termed the independent atom ansatz, is introduced in this work. This ansatz allows for the exact representation of electron density in terms of non-interacting, atom-localized orbitals.…

Chemical Physics · Physics 2024-05-03 Alexander V. Mironenko

We introduce a method for accurate quantum chemical calculations based on a simple variational wave function, defined by a single geminal that couples all the electrons into singlet pairs, combined with a real space correlation factor. The…

Materials Science · Physics 2009-10-22 M. Marchi , S. Azadi , M. Casula , S. Sorella

Recently, ``Higgsless'' models of electroweak symmetry breaking have been proposed. Based on compactified five-dimensional gauge theories, these models achieve unitarity of electroweak boson self-interactions through the exchange of a tower…

High Energy Physics - Phenomenology · Physics 2009-11-10 R. Sekhar Chivukula , Hong-Jian He , Masafumi Kurachi , Elizabeth H. Simmons , Masaharu Tanabashi

Doubly occupied configuration interaction (DOCI) with optimized orbitals often accurately describes strong correlations while working in a Hilbert space much smaller than that needed for full configuration interaction. However, the scaling…

Chemical Physics · Physics 2016-02-25 Thomas M. Henderson , Ireneusz W. Bulik , Tamar Stein , Gustavo E. Scuseria

Analytical formulas for the excitation energies as well as for the electric quadrupole reduced transition probabilities in the ground, beta and gamma bands were derived within the coherent state model for the near vibrational and well…

Nuclear Theory · Physics 2015-05-30 A. A. Raduta , R. Budaca , Amand Faessler

The accurate treatment of electronic effects in multi-million atom simulations of radiation-induced collision cascades is crucial for reliable predictions of primary radiation damage. In this work, we explore the performance of a recently…

Materials Science · Physics 2024-01-10 Andrea E. Sand , Glen P. Kiely , Artur Tamm , Alfredo A. Correa

Correlation functions of hadrons can be accessed in high-energy collisions of atomic nuclei, revealing information about the underlying interaction. This work complements experimental efforts to study nucleon-deuteron $Nd$ -- with $N=p$…

Nuclear Theory · Physics 2023-06-06 M. Viviani , S. König , A. Kievsky , L. E. Marcucci , B. Singh , O. Vázquez Doce

Diradical molecules are essential species involved in many organic and inorganic chemical reactions. The computational study of their electronic structure is often challenging, because a reliable description of the correlation, and in…

Chemical Physics · Physics 2014-06-18 Andrea Zen , Emanuele Coccia , Ye Luo , Sandro Sorella , Leonardo Guidoni

Collider experiments often exploit information about the quantum numbers of final state hadrons to maximize their sensitivity, with applications ranging from the use of tracking information (electric charge) for precision jet substructure…

High Energy Physics - Phenomenology · Physics 2022-05-05 Yibei Li , Ian Moult , Solange Schrijnder van Velzen , Wouter J. Waalewijn , Hua Xing Zhu

We assess the predictive accuracy of perturbation theory based estimates of changes in covalent bonding due to linear alchemical interpolations among molecules. We have investigated $\sigma$ bonding to hydrogen, as well as $\sigma$ and…

The nonlinear gravitational-wave (GW) memory effect$\unicode{x2014}$a permanent shift in the GW strain that arises from nonlinear GW interactions in the wave zone$\unicode{x2014}$is a prediction of general relativity which has not yet been…

General Relativity and Quantum Cosmology · Physics 2025-12-01 Arwa Elhashash , David A. Nichols

The systematic shifts of the transition frequencies in the molecular hydrogen ions are of relevance to ultra-high-resolution radio-frequency, microwave and optical spectroscopy of these systems, performed in ion traps. We develop the…

Atomic Physics · Physics 2015-06-16 Dimitar Bakalov , Stephan Schiller

A method for increasing the accuracy of configuration interaction (CI) calculations of molecules and other electronic systems is proposed. The energy defect of a given calculation is associated with the electron pair origin of…

Chemical Physics · Physics 2025-11-18 Jerry L. Whitten

We present a semi-relativistic model for the description of the ionization process of atomic hydrogen by electron impact in the first Born approximation by using the Darwin wave function to describe the bound state of atomic hydrogen and…

Atomic Physics · Physics 2007-05-23 Y. Attaourti , S. Taj , B. Manaut

We analyse the correlated back and forth dynamics and dynamic heterogeneities, i.e. the presence of fast and slow ions, for a lithium metasilicate system via computer simulations. For this purpose we define, in analogy to previous work in…

Disordered Systems and Neural Networks · Physics 2009-11-07 Andreas Heuer , Magnus Kunow , Michael Vogel , Radha D. Banhatti