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This master's thesis investigates the thermal and photochemical dehydrogenation of ethylbenzene (EB) to styrene on the rutile TiO$_{2}$(110) surface. A dual-methodological quantum chemical approach is used for this investigation. While…

Materials Science · Physics 2026-04-30 Nico Yannik Merkt

The PTCDA (3,4,9,10-Perylene-tetracarboxylic dianhydride) and the NTCDA (1,4,5,8-Naphtalenetetracarboxylic dianhydride) are aromatic, stable, planar and highly symmetric with unusual electrical properties. The PTCDA is a semiconductor…

Other Condensed Matter · Physics 2007-05-23 S. T. Perez-Merchancano , G. E. Marques , L. E. Bolivar-Marinez

We determine the optical response of a thin and dense layer of interacting quantum emitters. We show that in such a dense system, the Lorentz redshift and the associated interaction broadening can be used to control the transmission and…

Quantum Physics · Physics 2016-07-12 Raiju Puthumpally-Joseph , Maxim Sukharev , Osman Atabek , Eric Charron

Conversion of solar energy with high quantum efficiencies is a key challenge in energy technologies. Excitation energy transfer (EET) mechanisms, such as F\"orster resonance energy transfer (FRET), play a crucial role in facilitating…

Electronic Energy Transfer (EET) between chromophores is fundamental in many natural light-harvesting complexes, serving as a critical step for solar energy funneling in photosynthetic plants and bacteria. The complicated role of the…

Chemical Physics · Physics 2024-02-05 Colin Coane , Marco Romanelli , Giulia Dall'Osto , Rosa Di Felice , Stefano Corni

We study within the perturbative many-body $GW$ and Bethe-Salpeter approach the low lying singlet charge-transfer excitations in molecular donor-acceptor complexes associating benzene, naphtalene and anthracene derivatives with the…

Materials Science · Physics 2015-05-30 X. Blase , C. Attaccalite

Metal oxide nanocrystals are emerging as extremely versatile material for addressing many of the current challenging demands of energy-conversion technology. Being able to exploit their full potential is not only an advantage but also a…

Chemical Physics · Physics 2021-09-02 Michele Ghini , Andrea Rubino , Andrea Camellini , Ilka Kriegel

We find that conjugated polymers can undergo reversible structural phase transitions during electrochemical oxidation and ion injection. We study poly[2,5-bis(thiophenyl)-1,4-bis(2-(2-(2-methoxyethoxy)ethoxy)ethoxy)benzene] (PB2T-TEG), a…

We demonstrate an ultrafast reversible modulation of resonant terahertz (THz) response in strongly photoexcited metamaterials. The transient spectral-temporal response of the dipole transition ~1.6 THz exhibits a distinct non-monotonic…

Materials Science · Physics 2019-03-12 I. Chatzakis , L. Luo , J. Wang , N-H. Shen , T. Koschny , J. Zhou , C. M. Soukoulis

Fulfilling the potential of the colloidal semiconductor quantum dots (QDs) in electrically driven applications remains a challenge largely since operation of such devices involves charged QDs with drastically different photo-physical…

We present a theoretical study of terahertz radiation-induced transitions between attractive and repulsive Fermi polaron states in monolayers of transition metal dichalcogenides. Going beyond the simple few-particle trion picture, we…

Mesoscale and Nanoscale Physics · Physics 2026-03-24 A. M. Shentsev , M. M. Glazov

We present a generic theory of primary photoexcitations in low band gap donor-acceptor conjugated copolymers. Because of the combined effects of strong electron correlations and broken symmetry, there is considerable mixing between a…

Mesoscale and Nanoscale Physics · Physics 2016-01-01 Karan Aryanpour , Tirthankar Dutta , Uyen N. V. Huynh , Zeev Valy Vardeny , Sumit Mazumdar

The electronic transport of electrons and holes through stacks of $\alpha$,$\ome ga$-dicyano-$\beta$,$\beta$'-dibutyl- quaterthiophene (DCNDBQT) as part of a nov el organic ferroic field-effect transistor (OFFET) is investigated. The novel…

Materials Science · Physics 2015-05-14 T. Kunze , S. Gemming , V. Pankoke , K. Morawetz , R. Luschtinetz , G. Seifert

The formation of donor-acceptor complexes (DACs) between the electron donor Dibenzotetrathiafulvalene (DBTTF) and the acceptor Hexaaza\-triphenylene\-hexacarbo\-nitrile (HATCN) results in a new phase with a distinctly different crystal…

When considering the optimal molecular packing to realize charge multiplication in organic photovoltaic materials, subtle changes in intermolecular charge transfer (CT) coupling can strongly modulate singlet fission. To understand why…

The optical emission spectra of semiconducting transition-metal dichalcogenide monolayers highlight fascinating recombination processes of charged excitons (trions). When charge tunable WSe$_2$ monolayers are moderately doped with…

Mesoscale and Nanoscale Physics · Physics 2025-01-22 V. Jindal , K. Mourzidis , A. Balocchi , C. Robert , P. Li , D. Van Tuan , L. Lombez , D. Lagarde , P. Renucci , T. Taniguchi , K. Watanabe , H. Dery , X. Marie

We report on THz, infrared reflectivity and transmission experiments for wave numbers from 10 to 8000 cm$^{-1}$ ($\sim$ 1 meV - 1 eV) and for temperatures from 5 to 295 K on the Kitaev candidate material {\alpha}-RuCl$_3$. As reported…

Strongly Correlated Electrons · Physics 2017-10-18 S. Reschke , F. Mayr , Zhe Wang , Seung-Hwan Do , K. -Y. Choi , A. Loidl

We present a conspectus of recent joint spectroscopic and computational studies which provided novel insight into the photochemistry of hydrogen-bonded complexes of the heptazine (Hz) chromophore with hydroxylic substrate molecules (water…

Chemical Physics · Physics 2020-07-01 Wolfgang Domcke , Andrzej L. Sobolewski , Cody W. Schlenker

A new type of detector for positron-emission tomography (PET) has been proposed recently, using a heavy organo-metallic liquid - TriMethyl Bismuth (TMBi) - as target material. TMBi is a transparent liquid with the high Z element Bismuth…

Instrumentation and Detectors · Physics 2023-01-12 S. Peters , B. Gerke , V. Hannen , C. Huhmann , N. Marquardt , K. Schäfers , D. Yvon , V. Sharyy , C. Weinheimer

High entropy oxides (HEO) hold the potential to revolutionize the conventional material paradigms by leveraging high order of chemical disorder that induces highly desirable exotic phases for advanced applications. Here, we devise a…

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