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An explanation for why hot water will sometime freeze more rapidly than cold water is offered. Two specimens of water from the same source will often have different spontaneous freezing temperatures; that is, the temperature at which…

Popular Physics · Physics 2010-03-17 James D. Brownridge

The "Mpemba effect" is the name given to the assertion that hot water freezes quicker than cold water1 or, in a modern and more general form, that the system that is initially more distant from its equilibrium state comes to this state…

Chemical Physics · Physics 2025-08-08 Andrei A. Klimov , Alexei V. Finkelstein

We review the Mpemba effect, where intially hot water freezes faster than initially cold water. While the effect appears impossible at first sight, it has been seen in numerous experiments, was reported on by Aristotle, Francis Bacon, and…

History and Philosophy of Physics · Physics 2011-11-10 Monwhea Jeng

Water exhibits many unique properties compared to other liquids, with some of these explained and others remaining enigmatic. Among them, it was proposed and extensively debated that hot water would freeze faster than cold water. Numerous…

Chemical Physics · Physics 2025-12-02 James D. Brownridge , Matthieu Zinet , Paul Sotta , Francois Ganachaud

Unlike most of the research on the Mpemba effect which has focused on verifying the observation that warm water freezes faster than cold water, our work quantitatively investigates the rates at which hot and cold water cool and the point at…

Popular Physics · Physics 2011-01-17 Andrew Wang , Monica Chen , Yanni Vourgourakis , Antonio Nassar

I suggest that the origin of the Mpemba effect (the freezing of hot water before cold) is freezing-point depression by solutes, either gaseous or solid, whose solubility decreases with increasing temperature so that they are removed when…

Chemical Physics · Physics 2017-01-30 J. I. Katz

Under certain conditions, two samples of fluid at different initial temperatures present a counterintuitive behavior known as the Mpemba effect: it is the hotter system that cools sooner. Here, we show that the Mpemba effect is present in…

Soft Condensed Matter · Physics 2017-10-06 Antonio Lasanta , Francisco Vega Reyes , Antonio Prados , Andrés Santos

As the temperature of a cooling object decreases as it relaxes to thermal equilibrium, it is intuitively assumed that a hot object should take longer to cool than a warm one. Yet, some 2,300 years ago, Aristotle observed that "to cool hot…

Statistical Mechanics · Physics 2020-08-07 Avinash Kumar , John Bechhoefer

An accurate experimental investigation on the Mpemba effect (that is, the freezing of initially hot water before cold one) is carried out, showing that in the adiabatic cooling of water a relevant role is played by supercooling as well as…

Chemical Physics · Physics 2009-11-13 S. Esposito , R. De Risi , L. Somma

A system initially far from equilibrium is expected to take more time to reach equilibrium than a system that was initially closer to equilibrium. The old puzzling observation (also called Mpemba effect) that when a sample of hot water and…

Statistical Mechanics · Physics 2010-11-18 P. Chaddah , S. Dash , Kranti Kumar , A. Banerjee

Under certain conditions, it takes a shorter time to cool a hot system than to cool the same system initiated at a lower temperature. This phenomenon - the "Mpemba Effect" - is well known in water, and has recently been observed in other…

Statistical Mechanics · Physics 2017-09-28 Zhiyue Lu , Oren Raz

In the 1960s, Tanzanian student Erasto Mpemba and his teacher published an article with the title "Cool" in the journal Physics Education (Mpemba, E. B. - Osborne, D. G.: Cool?. In: Physics Education, vol.4, 1969, pp. 172-175.). In this…

Physics Education · Physics 2015-06-05 Marek Balazovic , Boris Tomasik

The name "Mpemba effect" was given to the finding that "If two systems are cooled, the water that starts hotter may freeze first", confirmed by numerous of observations. Now this paradoxical state-ment obtained a more general form "the…

Chemical Physics · Physics 2025-03-31 Alexei V. Finkelstein

The so-called Mpemba effect, i.e. the observation that the warmer of two otherwise identical systems cools faster when both are refrigerated in the same thermal reservoir, is a hotly debated topic in condensed mater physics and statistical…

Materials Science · Physics 2019-09-11 A. Gijón , A. Lasanta , E. R. Hernández

The quicker freezing of hotter water, than a colder sample, when quenched to a common lower temperature, is referred to as the Mpemba effect (ME). While this counter-intuitive fact remains a surprize since long, efforts have begun to…

Statistical Mechanics · Physics 2023-09-08 Sohini Chatterjee , Soumik Ghosh , Nalina Vadakkayil , Tanay Paul , Sanat K. Singha , Subir K. Das

The Mpemba effect is a counterintuitive physical phenomenon where a hot system cools faster than a warm one. In recent years, theoretical analyses of the Mpemba effect have been developed for microscopic systems and experimentally verified.…

Statistical Mechanics · Physics 2025-03-12 Tan Van Vu , Hisao Hayakawa

The Mpemba effect describes the situation in which a hot system cools faster than an identical copy that is initiated at a colder temperature. In many of the experimental observations of the effect, e.g. in water and clathrate hydrates, it…

Statistical Mechanics · Physics 2023-05-23 Roi Holtzman , Oren Raz

The Mpemba effect refers to the surprising observation where, under certain conditions, a far-from-equilibrium state can relax toward equilibrium faster than a state closer to equilibrium. A paradigmatic example is provided by the curious…

Quantum Physics · Physics 2025-03-25 Stefano Longhi

The Mpemba effect, in which a hotter system cools faster than a colder one, remains one of the most intriguing anomalies in thermodynamics. Here, we investigate its microscopic origin within the framework of quantum resource theories and…

Quantum Physics · Physics 2026-04-17 Doruk Can Alyürük , Mahir H. Yeşiller , Vlatko Vedral , Onur Pusuluk

The Mpemba effect occurs when a system prepared at a hot temperature cools down faster to the bath temperature than an identical system starting at a warm temperature. We derive the condition for the Mpemba effect in the small-diffusion…

Statistical Mechanics · Physics 2023-05-31 Matthew R. Walker , Marija Vucelja
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