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The LDA-1/2 method expands Slater's half occupation technique to infinite solid state materials by introducing a self-energy potential centered at the anions to cancel the energy associated with electron-hole self-interaction. To avoid an…

Computational Physics · Physics 2016-03-07 Kan-Hao Xue , Leonardo R. C. Fonseca , Xiang-Shui Miao

The LDA-1/2 method has proven to be a viable approach for calculating band gaps of semiconductors. To address its accuracy for finite systems, we apply LDA-1/2 to atoms and the molecules of the $GW100$ test set. The obtained energies of the…

Materials Science · Physics 2018-08-31 Ronaldo Rodrigues Pela , Andris Gulans , Claudia Draxl

The local-density approximation (LDA), together with the half-occupation (transition state) is notoriously successful in the calculation of atomic ionization potentials. When it comes to extended systems, such as a semiconductor infinite…

Materials Science · Physics 2009-11-13 Luiz G. Ferreira , Marcelo Marques , Lara K. Teles

The Kohn-Sham gaps of density functional theory (DFT) obtained in terms of local density approximation (LDA) or generalized gradient approximation (GGA) cannot be directly linked to the fundamental gaps of semiconductors, but in engineering…

Materials Science · Physics 2024-09-17 Hanli Cui , Shengxin Yang , Jun-Hui Yuan , Li-Heng Li , Fan Ye , Jinhai Huang , Kan-Hao Xue , Xiangshui Miao

DFT-1/2 is an efficient band gap rectification method for density functional theory (DFT) under local density approximation (LDA) or generalized gradient approximation. It was suggested that non-self-consistent DFT-1/2 should be used for…

Materials Science · Physics 2024-09-17 Hanli Cui , Shengxin Yang , Kan-Hao Xue , Jinhai Huang , Xiangshui Miao

Employing the $G_0W_0$ approximation of Hedin's $GW$ approach one can obtain quasi-particle energies of extended systems and molecules with good accuracy. However, for many materials, semi-local exchange-correlation functionals are…

Materials Science · Physics 2016-12-21 Ronaldo Rodrigues Pela , Ute Werner , Dmitrii Nabok , Claudia Draxl

This paper provides an accurate theoretical defect energy database for pure and Bi-containing III-V (III-V:Bi) materials and investigates efficient methods for high-throughput defect calculations based on corrections of results obtained…

Materials Science · Physics 2021-12-07 Maciej P. Polak , Robert Kudrawiec , Ryan Jacobs , Izabela Szlufarska , Dane Morgan

There has been a high demand in rectifying the band gap under-estimation problem in density functional theory (DFT), while keeping the computational load at the same level as local density approximation. DFT-1/2 and shell DFT-1/2 are useful…

Materials Science · Physics 2025-07-08 Shengxin Yang , Jiangzhen Shi , Kan-Hao Xue , Jun-Hui Yuan , Xiangshui Miao

Atomic effective pseudopotentials enable atomistic calculations at the level of accuracy of density functional theory for semiconductor nanostructures with up to fifty thousand atoms. Since they are directly derived from ab-initio…

Materials Science · Physics 2024-03-14 Surender Kumar , Hanh Bui , Gabriel Bester

The LDA-1/2 method is employed in density functional theory calculations for the electronic structure of III-V dilute bismide systems. For the representative example of Ga(SbBi) with Bi concentrations below $10 \%$, it is shown that this…

Materials Science · Physics 2020-08-12 Sven C. Liebscher , Lars C. Bannow , Jörg Hader , Jerome V. Moloney , Stephan W. Koch

Shell DFT-1/2 is a fast band gap rectification method that is versatile for semiconductor supercell and superlattice calculations, which involves two cutoff radii that have to be optimized. Although such optimization is trivial in terms of…

Materials Science · Physics 2025-03-27 Shanzhong Xie , Kan-Hao Xue , Zijian Zhou , Xiangshui Miao

The quasiparticle band structures of four polytypes 3C, 6H, 4H, and 2H of GaP, GaAs, GaSb, InP, InAs, and InSb are computed with high accuracy including spin-orbit interaction applying a recently developed approximate calculation scheme,…

Materials Science · Physics 2015-06-05 Abderrezak Belabbes , Christian Panse , Jürgen Furthmüller , Friedhelm Bechstedt

This work constitutes a comprehensive and improved account of electronic-structure and mechanical properties of silicon-nitride (Si3N4) polymorphs via van Leeuwen and Baerends (LB) exchange-corrected local density approximation (LDA) that…

Materials Science · Physics 2017-09-11 Prashant Singh , Manoj K. Harbola , Duane D. Johnson

First principle calculations based on LDA/GGA approximation for the exchange functional underestimate the position of the semi core 3d levels in GaX (X = N, P and As) semiconductors. A self-interaction correction scheme within the…

Materials Science · Physics 2007-06-05 Roby Cherian , Priya Mahadevan , Clas Persson

In solid-state physics/chemistry, a precise understanding of defect formation and its impact on the electronic properties of wide-bandgap insulators is a cornerstone of modern semiconductor technology. However, complexities arise in the…

Materials Science · Physics 2023-07-11 Harshan Reddy Gopidi , Lovelesh Vashist , Oleksandr I. Malyi

Density functional theory within the local or semilocal density approximations (DFT-LDA/GGA) has become a workhorse in electronic structure theory of solids, being extremely fast and reliable for energetics and structural properties, yet…

Theoretical simulation to phase change materials such as Ge-Sb-Te has suffered from two methodology issues. On the one hand, there is a lack of efficient band gap correction method for density functional theory, which is suitable for these…

Materials Science · Physics 2025-03-19 Shanzhong Xie , Kan-Hao Xue , Shaojie Yuan , Shengxin Yang , Heng Yu , Rongchuan Gu , Ming Xu , Xiangshui Miao

Very recently, in the 2011 version of the Wien2K code, the long standing shortcome of the codes based on Density Functional Theory, namely, its impossibility to account for the experimental band gap value of semiconductors, was overcome.…

Materials Science · Physics 2013-09-10 J. A. Camargo-Martinez , R. Baquero

An oversight of several previous local density approximation (LDA) results appears to have led to an incomplete picture of the actual capability of density functional theory (DFT), with emphasis on LDA, to describe and to predict the band…

Materials Science · Physics 2010-12-16 D. Bagayoko , G. L. Zhao , L. Franklin , E. C. Ekuma

Using seven semiconductors/insulators with band gaps covering the range from 1 eV to 10 eV we systematically explore the performance of two different variants of self-consistency associated with famous Hedin's system of equations: the full…

Materials Science · Physics 2022-01-20 Andrey L. Kutepov
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