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We develop a simple Landau-Ginzburg-type continuum theory of solvent-free ionic liquids and use it to predict the structure of the electrical double layer. The model captures overscreening from short-range correlations, dominant at small…

Classical Physics · Physics 2015-05-20 Martin Z. Bazant , Brian D. Storey , Alexei A. Kornyshev

Room temperature ionic liquids are attractive to numerous applications and particularly, to renewable energy devices. As solvent free electrolytes, they demonstrate a paramount connection between the material morphology and Coulombic…

Chemical Physics · Physics 2016-03-15 Nir Gavish , Arik Yochelis

We construct an explicitly solvable Landau mean-field theory for volume phase transitions of confined or fixed ions driven by relative concentrations of divalent and monovalent counterions. Such phase transitions have been widely studied in…

Soft Condensed Matter · Physics 2011-02-17 Kyle J. Welch , Fred Gittes

We investigate the quantum mechanical origin of resistive phase transitions in solids driven by a constant electric field in the vicinity of a metal-insulator transition. We perform a nonequilibrium mean-field analysis of a…

Strongly Correlated Electrons · Physics 2018-08-01 Jong E. Han , Jiajun Li , Camille Aron , Gabriel Kotliar

We investigate active electrolytes within the mean-field level of description. The focus is on how the double-layer structure of passive, thermalized charges is affected by active dynamics of all constituting ions. One feature of active…

Soft Condensed Matter · Physics 2018-05-23 Derek Frydel , Rudolf Podgornik

Mean-field theories claim that the capacitance of the double-layer formed at a metal/ionic conductor interface cannot be larger than that of the Helmholtz capacitor, whose width is equal to the radius of an ion. However, in some experiments…

Soft Condensed Matter · Physics 2015-03-17 M. S. Loth , Brian Skinner , B. I. Shklovskii

The primitive model of ionic systems is investigated within a field-theoretic description for the whole range of size-, \lambda, and charge, Z, ratios of the two ionic species. Two order parameters (OP) are identified, and their relations…

Statistical Mechanics · Physics 2009-11-11 A. Ciach , W. T. Gozdz , G. Stell

This paper presents an introduction to phase transitions and critical phenomena on the one hand, and nonequilibrium patterns on the other, using the Ginzburg-Landau theory as a unified language. In the first part, mean-field theory is…

Statistical Mechanics · Physics 2015-02-19 P. C. Hohenberg , A. P. Krekhov

In this review, we shortly summarize the basic theoretical milestones achieved in the mean-field theory of room temperature ionic liquids (RTILs) on charged electrodes since the publication of Kornyshev's seminal paper in 2007. We pay…

Soft Condensed Matter · Physics 2021-12-28 Yury A. Budkov , Andrei L. Kolesnikov

We propose a model describing the liquid-vapour phase transition according to a phase-field approach. The model takes up a setting proposed by the second author, where a phase field is introduced whose equilibrium values 0 and 1 are…

Mathematical Physics · Physics 2010-12-14 V. Berti , M. Fabrizio , D. Grandi

Photons mediate long-range optomechanical forces between atoms in high finesse resonators, which can induce the formation of ordered spatial patterns. When a transverse laser drives the atoms, the system undergoes a second order phase…

Quantum Physics · Physics 2016-08-10 Simon B. Jäger , Stefan Schütz , Giovanna Morigi

We look at the influence of external fields on systems described by generic free energy functional of the order parameter. The external force may have arbitrary spatial dependence, and the order parameter coupling may be nonlinear. The…

Statistical Mechanics · Physics 2023-01-05 Roni Kroll , Yoav Tsori

We present a general Ginzburg-Landau theory of electrostatic interactions and electric field effects for the order parameter, the polarization, and the charge density. Electric field effects are then investigated in near-critical fluids and…

Soft Condensed Matter · Physics 2007-05-23 Akira Onuki

A Landau-Ginzburg functional of two order parameters (charge-density $\phi$ and mass-density deviation $\eta$) is developed in order to yield a field theory relevant to ionic lattice gases as well as a family of off-lattice models of ionic…

Statistical Mechanics · Physics 2007-05-23 A. Ciach , G. Stell

Using dynamical mean-field theory (DMFT) we study a simplified model for heterostructures involving superconductors. The system is driven out-of-equilibrium by a voltage bias, imposed as an imbalance of chemical potential at the interface.…

Strongly Correlated Electrons · Physics 2016-03-21 A. Amaricci , M. Capone

Dynamics of charge density and lattice displacements after the neutral phase is photoexcited is studied by solving the time-dependent Schr\"odinger equation for a one-dimensional extended Peierls-Hubbard model with alternating potentials.…

Strongly Correlated Electrons · Physics 2007-05-23 Kenji Yonemitsu

In this study, we present theoretical investigations of phase transitions and critical phenomena in materials through the lens of second-order Ginzburg-Landau theory, in conjunction with considerations of symmetry groups and thermal…

The metal--insulator phase transition is considered on the basis of Ginzburg-Landau type equations with two different order parameters. An inclusion of magnetic field in this picture is an important step for understanding of behavior of the…

Strongly Correlated Electrons · Physics 2016-07-21 Leonid Dubovskii

Ionic liquids (ILs) are appealing electrolytes for their favorable physicochemical properties. However, despite their longstanding use, understanding the capacitive behavior of ILs remains challenging. This is largely due to the formation…

Soft Condensed Matter · Physics 2024-01-02 YeongKyu Lee , JunBeom Cho , Yongkyu Lee , Won Bo Lee , YongSeok Jho

While analyzing second order thermodynamical phase transitions, Lev Landau (the famous Russian physicist) introduced a very vital concept, the concept of an "order parameter". This not only amalgamated the previous fragmentary theoretical…

Statistical Mechanics · Physics 2014-02-28 Navinder Singh
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