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We investigate the electric double layer formed between charged walls of a slit-like pore and a solvent primitive model (SPM) for electrolyte solution. The recently developed version of the weighted density functional approach for…

Soft Condensed Matter · Physics 2014-07-14 O. Pizio , S. Sokołowski

Using ab initio methods, we examine the the charge distribution at the interface of alpha-alumina-supported Pt films, and we consider the influence of this interface on CO adsorption. We demonstrate that a combination of electrostatic…

Materials Science · Physics 2012-03-12 Valentino R. Cooper , Alexie M. Kolpak , Yashar Yourdshahyan , Andrew M. Rappe

We examine the phase transition of polymer adsorption as well as the underlying kinetics of polymer binding from dilute solutions on a structureless solid surface. The emphasis is put on the properties of regular multiblock copolymers,…

Soft Condensed Matter · Physics 2009-09-03 A. Milchev , V. Rostiashvili , S. Bhattacharya , T. Vilgis

Inverse patchy colloids are nano- to micro-scale particles with a surface divided into differently charged regions. This class of colloids combines directional, selective bonding with a relatively simple particle design: owing to the…

Soft Condensed Matter · Physics 2021-01-22 Emanuela Bianchi , Peter D. J. van Oostrum , Christos N. Likos , Gerhard Kahl

We propose a theoretical investigation of the physical adsorption of neutral comb-polymers with an adsorbing skeleton and non-adsorbing side-chains on a flat surface. Such polymers are particularly interesting as "dynamic coating" matrices…

Soft Condensed Matter · Physics 2009-11-11 Anna Sartori , Albert Johner , Jean-Louis Viovy , Jean-Francois Joanny

The computational study of the interaction between charged, ligand-protected metal nanoparticles and model lipid membranes has been recently addressed both at atomistic and coarse grained level. Here we compare the performance of three…

Biological Physics · Physics 2017-03-02 Sebastian Salassi , Federica Simonelli , Davide Bochicchio , Riccardo Ferrando , Giulia Rossi

Using a linear hydrodynamic model (HDM) we investigate theoretically the interaction between penetrating electron beams and sub-5 nm metallic spherical nanoparticles (NPs), and provide an analytical expression of the electron energy loss…

Mesoscale and Nanoscale Physics · Physics 2025-11-04 Mattin Urbieta , Eduardo Ogando , Alberto Rivacoba , Javier Aizpurua , Nerea Zabala

A comparative dynamic Monte Carlo simulation study of polydisperse living polymer brushes, created by surface initiated living polymerization, and conventional polymer monodisperse brush, comprising linear polymer chains, grafted to a…

Soft Condensed Matter · Physics 2012-12-04 K. Jalili , F. Abbasi , A. Milchev

Electrochemical phenomena in biology often unfold in confined geometries where micrometer- to millimeter-scale domains coexist with nanometer-scale interfacial diffuse charge layers. We analyze a model lipid membrane-electrolyte system…

Soft Condensed Matter · Physics 2025-08-20 Joshua B. Fernandes , Hyeongjoo Row , Kranthi K. Mandadapu , Karthik Shekhar

The importance of electrostatic interactions in soft matter and biological systems can often be traced to non-uniform charge effects, which are commonly described using a multipole expansion of the corresponding charge distribution. The…

Soft Condensed Matter · Physics 2018-04-23 Anže Lošdorfer Božič

We consider a functional surface comprising thermoresponsive polymer chains, the material that has found numerous technological and biomedical applications. However, to achieve the required time and length scales for computer modelling of…

Soft Condensed Matter · Physics 2023-08-16 D. Yaremchuk , O. Kalyuzhnyi , J. Ilnytskyi

Platinum step edges dominate electrocatalytic activity in fuel cells and electrolysers, yet their atomistic electrochemical behaviour remains poorly understood. Here, we employ \textit{ab initio} molecular dynamics under controlled…

Materials Science · Physics 2025-10-15 Matthew T. Darby , Muhammad Saleh , Marialore Sulpizi , Clotilde S. Cucinotta

Inclusions in mobile brushes experience apparent (depletion) attraction, which arises from a tendency to minimize the volume of depletion zones around the inclusions, thereby to maximize the entropy of the surrounding polymers. Here, we…

Soft Condensed Matter · Physics 2025-07-23 Ji Woong Yu , Daeseong Yong , Bae-Yeun Ha , Changbong Hyeon

Polymer electrolytes are intensely investigated for use as solid electrolytes in next generation lithium-ion and lithium-metal batteries. However, little is known about the structural and dynamical properties of polymer electrolytes close…

Soft Condensed Matter · Physics 2021-12-02 Andreas Thum , Diddo Diddens , Andreas Heuer

Molecular Dynamics simulations of a coarse-grained bead-spring model of flexible macromolecules tethered with one end to the surface of a cylindrical pore are presented. Chain length $N$ and grafting density $\sigma$ are varied over a wide…

Soft Condensed Matter · Physics 2007-05-23 Dimitar I. Dimitrov , Andrey Milchev , Kurt Binder , Dieter W. Heermann

Besides direct molecular interactions, proteins and nanoparticles embedded in or adsorbed to membranes experience indirect interactions that are mediated by the membranes. These membrane-mediated interactions arise from the membrane…

Soft Condensed Matter · Physics 2024-07-08 Francesco Bonazzi , Thomas R. Weikl

We present LayerPCM, an extension of the polarizable-continuum model coupled to real-time time-dependent density-functional theory for an efficient and accurate description of the electrostatic interactions between molecules and…

Materials Science · Physics 2021-06-17 Jannis Krumland , Gabriel Gil , Stefano Corni , Caterina Cocchi

The binding of a cationic surfactant (hexadecyltrimethylammonium bromide, CTAB) to a negatively charged natural polysaccharide (pectin) at air-solution interfaces, was investigated on single interfaces and in foams, versus the linear charge…

Soft Condensed Matter · Physics 2010-05-20 Marie-Hélène M. H. Ropers , Bruno Novales , François Boué , Monique A. V. Axelos

We investigate numerically and on the scaling level the adsorption of a charged colloid on an oppositely charged flexible membrane. We show that the long ranged character of the electrostatic interaction leads to a wrapping reentrance of…

Biological Physics · Physics 2009-11-10 Christian C. Fleck , Roland R. Netz

Many biological systems fold thin sheets of lipid membrane into complex three-dimensional structures. This microscopic origami is often mediated by the adsorption and self-assembly of proteins on a membrane. As a model system to study…

Soft Condensed Matter · Physics 2016-10-11 Raphael Sarfati , Eric R. Dufresne
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