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During the past 15 years, the density matrix renormalization group (DMRG) has become increasingly important for ab initio quantum chemistry. The underlying matrix product state (MPS) ansatz is a low-rank decomposition of the full…

Strongly Correlated Electrons · Physics 2014-05-22 Sebastian Wouters

Over the past decade the in-medium similarity renormalization group (IMSRG) approach has proven to be a powerful and versatile ab initio many-body method for studying medium-mass nuclei. So far, the IMSRG was limited to the approximation in…

Nuclear Theory · Physics 2021-04-27 M. Heinz , A. Tichai , J. Hoppe , K. Hebeler , A. Schwenk

This study examines several techniques to improve the efficiency of the linearized multireference driven similarity renormalization group truncated to one- and two-body operators [MR-LDSRG(2)]. We propose a sequential MR-LDSRG(2)…

Chemical Physics · Physics 2019-03-29 Tianyuan Zhang , Chenyang Li , Francesco A. Evangelista

We first derive the Rayleigh-Schr\"odinger many-body perturbation theory up to third order (RSPT3) for Hamiltonians with three-body interaction. The structure of closed-shell nuclei in a wide mass range from 4He to 48Ca has been…

Nuclear Theory · Physics 2018-10-23 B. S. Hu , T. Li , F. R. Xu

The quantum chemical version of the density matrix renormalization group (DMRG) method has established itself as one of the methods of choice for calculations of strongly correlated molecular systems. Despite its great ability to capture…

Chemical Physics · Physics 2021-08-31 Pavel Beran , Mikuláš Matoušek , Michał Hapka , Katarzyna Pernal , Libor Veis

We present a second-order N-electron valence state perturbation theory (NEVPT2) based on a density matrix renormalization group (DMRG) reference wave function that exploits a Cholesky decomposition of the two-electron repulsion integrals…

Chemical Physics · Physics 2017-03-07 Leon Freitag , Stefan Knecht , Celestino Angeli , Markus Reiher

We apply the renormalization group optimized perturbation theory (RGOPT)to evaluate the QCD (matter) pressure at the two-loop level considering three flavors of massless quarks in a dense and cold medium. Already at leading order…

High Energy Physics - Phenomenology · Physics 2019-12-11 Jean-Loïc Kneur , Marcus Benghi Pinto , Tulio Eduardo Restrepo

UGA-SSMRPT2, the spin-free perturbative analogue of Mukerjee's State-Specific Multireference Coupled Cluster Theory (MkMRCC) is known to be successful for size-extensive and intruder-free construction of dissociation curves. This work…

Chemical Physics · Physics 2026-02-05 Shamik Chanda , Pratyush Bhattacharjya , Avijit Sen , Sangita Sen

The non-perturbative {\it ab initio} calculations of infinite nuclear matter using In-Medium Similarity Renormalization Group (IMSRG) method is developed in this work, which enables calculations with chiral two and three-nucleon forces at…

Nuclear Theory · Physics 2025-02-27 Xin Zhen , Rongzhe Hu , Haoyu Shang , Jiawei Chen , Junchen Pei , Furong Xu

The recent development of the density matrix renormalization group (DMRG) method in multireference quantum chemistry makes it practical to evaluate static correlation in a large active space, while dynamic correlation provides a critical…

Strongly Correlated Electrons · Physics 2020-08-20 Zhen Luo , Yingjin Ma , Xicun Wang , Haibo Ma

The density matrix renormalization group (DMRG) is applied to some one-dimensional reaction-diffusion models in the vicinity of and at their critical point. The stochastic time evolution for these models is given in terms of a non-symmetric…

Statistical Mechanics · Physics 2011-10-11 Enrico Carlon , Malte Henkel , Ulrich Schollwoeck

We develop and test methods that include second and third-order perturbation theory (MP3) using orbitals obtained from regularized orbital-optimized second-order perturbation theory, $\kappa$-OOMP2, denoted as MP3:$\kappa$-OOMP2. Testing…

Chemical Physics · Physics 2019-10-15 Luke W. Bertels , Joonho Lee , Martin Head-Gordon

We present an efficient implementation of the Density Matrix Renormalization Group (DMRG) algorithm that includes an optimal ordering of the proton and neutron orbitals and an efficient expansion of the active space utilizing various…

Nuclear Theory · Physics 2015-11-18 Ö. Legeza , L. Veis , A. Poves , J. Dukelsky

The Density Matrix Renormalization Group (DMRG) is a state-of-the-art numerical technique for a one dimensional quantum many-body system; but calculating accurate results for a system with Periodic Boundary Condition (PBC) from the…

Strongly Correlated Electrons · Physics 2016-11-29 Dayasindhu Dey , Debasmita Maiti , Manoranjan Kumar

We explore the application of the nonperturbative functional renormalization group (NPFRG) within its most common approximation scheme based on truncations of the derivative expansion, to the $Z_2$-symmetric scalar $\varphi^4$ theory as the…

Statistical Mechanics · Physics 2026-03-24 Ivan Balog , Lucija Nora Farkaš , Maroje Marohnić , Gilles Tarjus

Efficiently recovering dynamic correlation in strongly correlated systems without incurring prohibitive computational costs remains a central challenge in quantum chemistry. In this Perspective, we review and benchmark methods capable of…

Chemical Physics · Physics 2026-05-22 Michał Hapka , Aleksandra Tucholska , Katarzyna Pernal

The density matrix renormalization group (DMRG) method generates the low-energy states of linear systems of $N$ sites with a few degrees of freedom at each site by starting with a small system and adding sites step by step while keeping…

Strongly Correlated Electrons · Physics 2016-10-05 Manoranjan Kumar , Dayasindhu Dey , Aslam Parvej , S. Ramasesha , Zoltán G. Soos

Simulating strongly correlated systems in two dimensions is notoriously challenging due to rapid entanglement growth and frustration. Here, we introduce the adaptive projected-purified pseudoboson density-matrix renormalization group…

Strongly Correlated Electrons · Physics 2026-02-17 Fabian J. Pauw , Thomas Köhler , Ulrich Schollwöck , Sebastian Paeckel

The density matrix renormalization group (DMRG) method introduced by White for the study of strongly interacting electron systems is reviewed; the method is variational and considers a system of localized electrons as the union of two…

Strongly Correlated Electrons · Physics 2009-10-31 G. Fano , F. Ortolani , L. Ziosi

In the last decade, the quantum chemical version of the density matrix renormalization group (DMRG) method has established itself as the method of choice for calculations of strongly correlated molecular systems. Despite its favourable…

Chemical Physics · Physics 2016-11-15 Libor Veis , Andrej Antalík , Jiří Brabec , Frank Neese , Örs Legeza , Jiří Pittner