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We investigate the propagation of surface-enhanced resonant Raman scattering (SERRS) light by several micrometers through a one-dimensional hotspot (1D HS) located between a plasmonic nanowire dimer (NWD). The propagation exhibits the…

Optics · Physics 2021-06-23 Tamitake Itoh , Yuko S. Yamamoto , Jeyadevan Balachandran

The hotspots, which are typically found in nanogaps between metal structures, are critical for the enhancement of the electromagnetic field. Surface-enhanced Raman scattering (SERS), a technique known for its exceptional sensitivity and…

One-dimensional junctions between parallel and closely arranged multiple silver nanowires (NWs) exhibit a large electromagnetic (EM) enhancement factor (FR) owing to both localized and surface plasmon resonances. Such junctions are referred…

Optics · Physics 2024-10-30 Tamitake Itoh , Yuko S. Yamamoto

We investigated the spectral properties of electromagnetic (EM) enhancement of one-dimensional hotspots (1D HSs) generated between silver nanowire (NW) dimers. The EM enhancement spectra were directly derived by dividing the spectra of…

Optics · Physics 2024-01-10 Tamitake Itoh , Yuko S. Yamamoto

Surface enhanced Raman scattering (SERS) in nanoscale hotspots has been placed great hopes upon for identification of minimum chemical traces and in-situ investigation of single molecule structures and dynamics. However, previous work…

Optics · Physics 2016-09-19 Jing Long , Hui Yi , Hongquan Li , Tian Yang

This study found that plasmonic hotspots (HSs) between silver nanoparticles (NPs) and silver nanowires (NWs) generated two-photon excited emissions, including hyper-Rayleigh, hyper-Raman, and two-photon fluorescence of dye molecules with…

Optics · Physics 2025-07-22 Tamitake Itoh , Yuko S. Yamamoto

Nanoscale gaps between adjacent metallic nanostructures give rise to extraordinarily large field enhancements, known as "hot spots", upon illumination. Incident light with the electric field polarized across the gap (along the interparticle…

Mesoscale and Nanoscale Physics · Physics 2013-03-27 Joseph B. Herzog , Mark W. Knight , Yajing Li , Kenneth M. Evans , Naomi J. Halas , Douglas Natelson

New type of plasmonic nanoparticles - silver octopods that can be synthesized with a variety of shapes - have been demonstrated to show versatile optical response using the discrete dipole approximation. The octopods show a complex behavior…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 Ivan I. Naumov , Zhiyong Li , Alexander M. Bratkovsky

Single-molecule surface enhanced Raman scattering (SM-SERS) is one of the vital applications of plasmonic nanoparticles. The SM-SERS sensitivity critically depends on plasmonic hot-spots created at the vicinity of such nanoparticles. In…

In analogy to cavity optomechanics, enhancing specific sidebands of a Raman process with narrowband optical resonators would allow for parametric amplification, entanglement of light and molecular vibrations, and reduced transduction noise.…

Optics · Physics 2023-01-09 Ilan Shlesinger , Isabelle M. Palstra , A. Femius Koenderink

We report on the experimental observation of mirror enhanced directional surface enhanced Raman scattering (SERS) from a self-assembled monolayer of molecules coupled to a nanowire-nanoparticle (NW-NP) junction on a mirror in remote…

Optics · Physics 2021-11-17 Sunny Tiwari , Adarsh B Vasista , Diptabrata Paul , G. V. Pavan Kumar

The spectral relationships between surface enhanced resonant Raman scattering (SERRS) and plasmon resonance observed in far field scattering cross are investigated using single silver nanoparticle dimers with focusing on the lowest energy…

Optics · Physics 2023-04-07 Tamitake Itoh , Yuko S. Yamamoto

Herein we report experimental evidence of directional SERS from molecules situated inside a single nanowire-nanoparticle junction cavity. The emission was confined to a narrow range of wavevectors perpendicular to the axis of the cavity. In…

Detection of enantiomers is a challenging problem in drug development as well as environmental and food quality monitoring where traditional optical detection methods suffer from low signals and sensitivity. Application of surface enhanced…

We present SERS-active metal holographic metasurfaces fabricated from metal periodical nanograting deposited on a dielectric substrate. The metasurface consists of a modulated dielectric, which is covered by a thin silver layer. The…

Trisoctahedral (TOH) shaped Au nanocrystals (NCs) have emerged as a new class of metal nanoparticles (MNP) due to its superior catalystic and SERS activities caused by the presence of high density atomic steps and dangling bonds on their…

Materials Science · Physics 2017-05-15 Achyut Maity , Arpan Maiti , Biswarup Satpati , Avinash Patsha , Sandip Dhara , Tapas Kumar Chini

Surface-enhanced Raman scattering (SERS) provides critical insights into analyte structure, dynamic processes, and intermolecular interactions at the single-molecule level. By exploiting the hotspot formation in the vicinity of plasmonic…

We explored the surface enhanced Raman scattering (SERS) activity of the InN nanostructures, possessing surface electron accumulation (SEA), using the Rhodamine 6G (R6G) molecules. SERS enhancement is observed for the InN nanostructures…

Materials Science · Physics 2018-08-14 Kishore K. Madapu , Sandip Dhara

We present a microscopic model for surface-enhanced Raman scattering (SERS) from molecules adsorbed on small noble-metal nanoparticles. In the absence of direct overlap of molecular orbitals and electronic states in the metal, the main…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Vitaliy N. Pustovit , Tigran V. Shahbazyan

Plasmonic nanostructures enhance nonlinear response, such as surface enhanced Raman scattering (SERS), by localizing the incident field into hot spots. The localized hot spot field can be enhanced even further when linear Fano resonances…

Optics · Physics 2018-05-22 Selen Postaci , Bilge Can Yildiz , Alpan Bek , Mehmet Emre Tasgin
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