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We performed comparable polarized Raman scattering studies of MoTe2 and WTe2. By rotating crystals to tune the angle between the principal axis of the crystals and the polarization of the incident/scattered light, we obtained the angle…

Polarized Raman scattering measurements on IrTe$_2$ single crystals carried out over 15~K - 640~K temperature range, and across the structural phase transition, reveal new insights regarding the crystal symmetry.\ In the high temperature…

Superconductivity · Physics 2016-09-20 N. Lazarević , E. S. Bozin , M. Šćepanović , M. Opačić , Hechang Lei , C. Petrovic , Z. V. Popović

The paper presents detailed Raman scattering study of the unusually broad E2g phonon mode in MgB2 crystal. For the first time, it is shown by the polarized Raman scattering on few-micron-size crystallites with natural faces that the…

Superconductivity · Physics 2012-12-18 J. Hlinka , I. Gregora , J. Pokorny , A. Plecenik , P. Kus , L. Satrapinsky , S. Benacka

We study the second-order Raman process of mono- and few-layer MoTe$_2$, by combining {\em ab initio} density functional perturbation calculations with experimental Raman spectroscopy using 532, 633 and 785 nm excitation lasers. The…

Characterization of strain in two-dimensional (2D) crystals is important for understanding their properties and performance. Using first-principles calculations, we study the effects of uniaxial strain on the Raman-active modes in monolayer…

Materials Science · Physics 2016-02-02 Danna Doratotaj , Jeffrey R. Simpson , Jia-An Yan

We report on room-temperature Raman scattering measurements in few-layer crystals of exfoliated molybdenum ditelluride (MoTe$_{2}$) performed with the use of 632.8 nm (1.96 eV) laser light excitation. In agreement with recent study reported…

The polarized Raman scattering spectra from freshly cleaved $ab$, $ac$, and $bc$ surfaces of high quality twin free YBa$_2$Cu$_3$O$_{6.5}$ (Ortho-II) single crystals ($T_c$=57.5 K and $\Delta T = 0.6$ K) were studied between 80 and 300 K.…

Superconductivity · Physics 2008-03-14 M. N. Iliev , V. G. Hadjiev , S. Jandl , D. Le Boeuf , V. N. Popov , D. Bonn , R. Liang , W. N. Hardy

The selection rules for dipole and Raman activity can be relaxed due to local distortion of a crystalline structure. In this situation a dipole-inactive mode can become simultaneously active in Raman scattering and in dipole interaction…

Disordered Systems and Neural Networks · Physics 2009-09-25 Lev I. Deych , M. Erementchouk , V. A. Ignatchenko

By performing density functional theory-based ab-initio calculations, Raman active phonon modes of novel single-layer two-dimensional (2D) materials and the effect of in-plane biaxial strain on the peak frequencies and corresponding…

Mesoscale and Nanoscale Physics · Physics 2018-04-04 M. Yagmurcukardes , C. Bacaksiz , E. Unsal , B. Akbali , R. T. Senger , H. Sahin

Resonance Raman scattering, which probes electrons, phonons and their interplay in crystals, is extensively used in two-dimensional materials. Here we investigate Raman modes in MoSe$_2$ at different laser excitation energies from 2.33 eV…

The structural polymorphism in transition metal dichalcogenides (TMDs) provides exciting opportunities for developing advanced electronics. For example, MoTe$_2$ crystallizes in the 2H semiconducting phase at ambient temperature and…

A Raman spectroscopy study was carried out for ZnGeN2 with direction of propagation along the (0001) crystallographic direction on hexagonal single crystal platelets obtained by reaction of gaseous ammonia with a Zn-Ge-Sn liquid alloy at…

Materials Science · Physics 2017-03-08 Eric W. Blanton , Mark Hagemann , Keliang He , Jie Shan , Walter R. L. Lambrecht , Kathleen Kash

We have performed polarized and temperature-dependent Raman scattering measurements on extremely large magnetoresitance compounds TaAs$_2$ and NbAs$_2$. In both crystals, all the Raman active modes, including six A$_g$ modes and three B$_g$…

We present a first-principles machine-learning computational framework to investigate anharmonic effects in polarization-orientation (PO) Raman spectra of molecular crystals, focusing on anthracene and naphthalene. By combining machine…

Materials Science · Physics 2026-01-15 Paolo Lazzaroni , Shubham Sharma , Mariana Rossi

Ferroaxial order is characterized by the breaking of mirror symmetry parallel to the crystallographic principal axis, which often originates from spontaneous rotational distortions of the crystal lattice. Such rotational distortions are, by…

We investigated polarization dependence of the Raman modes in black phosphorus (BP) using five different excitation wavelengths. The crystallographic orientation was determined by comparing polarized optical microscopy with high-resolution…

Mesoscale and Nanoscale Physics · Physics 2015-11-10 Jungcheol Kim , Jae-Ung Lee , Jinhwan Lee , Hyo Ju Park , Zonghoon Lee , Changgu Lee , Hyeonsik Cheong

We synthesized distorted octahedral(T') molybdenum ditelluride (MoTe2) and investigated its vibrational properties with Raman spectroscopy, density functional theory and symmetry analysis. Compared to the results from high temperature…

Mesoscale and Nanoscale Physics · Physics 2016-08-22 Shao-Yu Chen , Thomas Goldstein , Dhandapani Venkataraman , Ashwin Ramasubramaniam , Jun Yan

The anharmonic lattice dynamics of oxide and halide perovskites play a crucial role in their mechanical and optical properties. Raman spectroscopy is one of the key methods used to study these structural dynamics. However, despite decades…

Raman spectra obtained by the inelastic scattering of light by crystalline solids contain contributions from first-order vibrational processes (e.g. the emission or absorption of one phonon, a quantum of vibration) as well as higher-order…

Materials Science · Physics 2017-08-22 Yannick Gillet , Stefan Kontur , Matteo Giantomassi , Claudia Draxl , Xavier Gonze

We employ a combined experimental-theoretical study of the first- and second-order Raman modes of monoclinic $\beta$-Ga$_{2}$O$_{3}$. The investigated materials is of particular interest due to its deep-UV bandgap paired with a high…

Materials Science · Physics 2022-01-19 Benjamin M. Janzen , Roland Gillen , Zbigniew Galazka , Janina Maultzsch , Markus R. Wagner
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