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Integral equation theory is applied to a coarse-grained model of water to study potential of mean force between hydrophobic solutes. Theory is shown to be in good agreement with the available simulation data for methane-methane and…

Soft Condensed Matter · Physics 2015-05-28 S. A. Egorov

The diffuse-interface model (DIM) is a tool for studying interfacial dynamics. In particular, it is used for modeling contact lines, i.e., curves where a liquid, gas, and solid are in simultaneous contact. As well as all other models of…

Soft Condensed Matter · Physics 2021-09-17 E. S. Benilov

We discuss the reliability of integral-equation methods based on several commonly used closure relations in determining the phase diagram of coarse-grained models of soft-matter systems characterized by mutually interacting soft and…

Soft Condensed Matter · Physics 2015-10-28 Roberto Menichetti , Andrea Pelissetto , Giuseppe D'Adamo , Carlo Pierleoni

In this paper we present a simulation study of water-like anomalies in core-softened system introduced in our previous publications. We investigate the anomalous regions for a system with the same functional form of the potential but with…

Soft Condensed Matter · Physics 2015-05-30 Yu. D. Fomin , E. N. Tsiok , V. N. Ryzhov

A core-softened model of a glass forming fluid is numerically studied in the limit of very low temperatures. The model shows two qualitatively different behaviors depending on the strength of the attraction between particles. For no or low…

Statistical Mechanics · Physics 2009-11-07 E. A. Jagla

Repulsively interacting particles in a periodic potential can form bound composite objects, whose dissociation is suppressed by a band gap. Nearly pure samples of such repulsively bound pairs of cold atoms -- "dimers" -- have recently been…

Other Condensed Matter · Physics 2008-03-31 David Petrosyan , Bernd Schmidt , James R. Anglin , Michael Fleischhauer

The relation between liquid-liquid phase transitions and waterlike density anomalies in core-softened potentials of fluids was investigated in an exactly solvable one dimensional lattice model and a in a three dimensional fluid with…

Soft Condensed Matter · Physics 2015-03-11 Marco Aurélio A. Barbosa , Evy Salcedo , Marcia Barbosa

The three-dimensional Gaussian core model (GCM) for soft-matter systems has repulsive interparticle interaction potential $\phi (r) = \varepsilon\, {\rm exp}\left[ -(r/\sigma)^{2} \right]$, with $r$ the distance between a pair of atoms, and…

Soft Condensed Matter · Physics 2021-01-18 George Ruppeiner , Peter Mausbach , Helge-Otmar May

We report a computer-simulation study of the equilibrium phase diagram of a three-dimensional system of particles with a repulsive step potential. The phase diagram is obtained using free-energy calculations. At low temperatures, we observe…

Soft Condensed Matter · Physics 2015-05-13 N. V. Gribova , Yu. D. Fomin , Daan Frenkel , V. N. Ryzhov

We perform an extensive computational study of binary mixtures of water and short-chain alcohols resorting to two-scale potential models to account for the singularities of hydrogen bonded liquids. Water molecules are represented by a well…

Soft Condensed Matter · Physics 2017-04-26 A. P. Furlan , E. Lomba , M. C. Barbosa

We investigate a lattice-fluid model of water, defined on a 3-dimensional body-centered cubic lattice. Model molecules possess a tetrahedral symmetry, with four equivalent bonding arms. The model is similar to the one proposed by Roberts…

Soft Condensed Matter · Physics 2016-08-31 M. Pretti , C. Buzano

We show that the existence of the water-like anomalies in kinetic coefficients in the core-softened systems depends on the trajectory in $\rho-T$ plane along which the kinetic coefficients are calculated. In particular, it is shown that the…

Soft Condensed Matter · Physics 2010-08-06 Yu. D. Fomin , V. N. Ryzhov

Based on the thermodynamic perturbation theory (TPT) and the Random phase approximation (RPA), we present a statistical theory of solutions of electrically neutral soft molecules, every of which is modelled as a set of sites that interact…

Soft Condensed Matter · Physics 2019-03-12 Yu. A. Budkov

Effective pair interactions with a soft-repulsive component are a well-known feature of polymer solutions and colloidal suspensions, but they also provide a key to interpret the high-pressure behaviour of simple elements. We have computed…

Soft Condensed Matter · Physics 2009-09-08 Santi Prestipino , Franz Saija , Gianpietro Malescio

A key challenge for soft materials design and coarse-graining simulations is determining interaction potentials between components that give rise to desired condensed-phase structures. In theory, the Ornstein-Zernike equation provides an…

Soft Condensed Matter · Physics 2021-02-22 Rhys E. A. Goodall , Alpha A. Lee

We establish the equivalence of a recently introduced discrete model of the hydrophobic interaction, as well as its extension to continuous state variables, with the Ising model in a magnetic field with temperature-dependent strength. In…

Statistical Mechanics · Physics 2016-08-15 G. M. Schütz , I. Ispolatov , G. T. Barkema , B. Widom

The integral equations for the correlation functions of an inhomogeneous fluid mixture are derived using a functional Taylor expansion of the free energy around an inhomogeneous equilibrium distribution. The system of equations is closed by…

Soft Condensed Matter · Physics 2007-05-23 M. Oettel

We have studied the structure and thermodynamic properties of isotropic three-dimensional core-softened fluid by using the second-order Ornstein-Zernike integral equations completed by the hypernetted chain and Percus-Yevick closures. The…

Soft Condensed Matter · Physics 2011-06-17 O. Pizio , Z. Sokolowska , S. Sokolowski

We apply a phenomenological theory of polar liquids to calculate the interaction energy between two plane surfaces at nm-distances. We show that depending on the properties of the surface-liquid interfaces, the interacting surfaces induce…

Soft Condensed Matter · Physics 2013-04-24 P. O. Fedichev , L. I. Menshikov

This work addresses research questions arising from the application of geometrically exact beam theory in the context of fluid-structure interaction (FSI). Geometrically exact beam theory has proven to be a computationally efficient way to…

Computational Engineering, Finance, and Science · Computer Science 2022-07-13 Nora Hagmeyer , Matthias Mayr , Ivo Steinbrecher , Alexander Popp