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Probing optical excitations with high resolution is important for understanding their dynamics and controlling their interaction with other photonic elements. This can be done using state-of-the-art electron microscopes, which provide the…

Materials Science · Physics 2021-10-13 Renwen Yu , Andrea Konečná , F. Javier García de Abajo

The interaction of graphene with metallic substrates reveals phenomena and properties of great relevance for applications in nanotechnology. In this review, the vibrational characterization by means of various inelastic scattering…

Materials Science · Physics 2016-01-08 Antonio Politano

The tip of a scanning tunnelling microscope can inject hot electrons into a surface with atomic precision. Their subsequent dynamics and eventual decay can result in atomic manipulation of an adsorbed molecule, or in light emission from the…

Chemical Physics · Physics 2019-07-19 Rebecca M. Purkiss , Henry G. Etheridge , Peter A. Sloan , Kristina R. Rusimova

We couple photoluminescent semiconducting 7-atom wide armchair edge graphene nanoribbons to plasmonic nanoantenna arrays and demonstrate an enhancement of the photoluminescence and Raman scattering intensity of the nanoribbons by more than…

Photoemission electron microscopy was used to image the electrons photoemitted from specially tailored Ag nanoparticles deposited on a Si substrate (with its native oxide SiO$_{x}$). Photoemission was induced by illumination with a Hg…

Interest in the magnetism of organic compounds is growing because of new organic magnets, spin-based electronics and the diverse properties of magnetic edge states in graphene nanoribbons. Electron spin resonance spectroscopy combined with…

Mesoscale and Nanoscale Physics · Physics 2025-04-28 Gregory Czap , Christoph Wolf , Jose Reina-Gálvez , Mark H. Sherwood , Christopher P. Lutz

Using photonic devices, we developed a new approach to traditional spectroscopy where the spectral cross-correlation with a template spectrum can be done entirely on-device. By creating photonic devices with a carefully designed, modulated…

Correlative light and electron microscopy promises to combine molecular specificity with nanoscale imaging resolution. However, there are substantial technical challenges including reliable co-registration of optical and electron images,…

Strong coupling between cavity photons and molecular vibrations can lead to the formation of vibron-polaritons. In a recent experiment with PVAc molecules in a metal-metal microcavity [A.Shalabney et al., Ang.Chem.Int.Ed. 54 7971 (2015)],…

Optics · Physics 2016-08-31 Artem Strashko , Jonathan Keeling

We report on photoassociation spectroscopy probing the $c^3\Sigma_{1}^+$ potential of the bi-alkali NaCs molecule, identifying eleven vibrational lines between $v' = 0$ and $v' = 25$ of the excited $c^3\Sigma_{1}^+$ potential, and resolving…

Spectroscopic studies of electronic phenomena in graphene are reviewed. A variety of methods and techniques are surveyed, from quasiparticle spectroscopies (tunneling, photoemission) to methods probing density and current response (infrared…

Mesoscale and Nanoscale Physics · Physics 2014-07-28 D. N. Basov , M. M. Fogler , A. Lanzara , Feng Wang , Yuanbo Zhang

Photonic molecules - particular systems composed of coupled optical resonators - emulate the behavior of complex physical systems exhibiting discrete energy levels. In this work, we present a novel photonic molecule composed of two strongly…

Optics · Physics 2023-12-06 Sara Kacmoli , Deborah L. Sivco , Claire F. Gmachl

Scanning tunneling spectroscopy measures how a single electron with definite energy propagates between a sample surface and the tip of a scanning tunneling microscope. In the simplest description, the differential conductance measured is…

Mesoscale and Nanoscale Physics · Physics 2019-05-07 Mikko M. Ervasti , Fabian Schulz , Peter Liljeroth , Ari Harju

Here we present theoretical studies of the effect of vibronic coupling on nonlinear transport characteristics (current-voltage and conductance-voltage) in molecular electronic devices. Considered device is composed of molecular quantum dot…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Kamil Walczak

Moving the detection wavelength in vibrational sum-frequency generation (VSFG) spectroscopy to the near-infrared (> 700 nm) can potentially enable the study of molecular interfaces absorbing in the visible and give access to buried…

Optics · Physics 2024-05-10 Zsuzsanna Heiner , Valentin Petrov , Mark Mero

In this letter, we report that the special coupling between Dirac fermion and lattice vibrations, in other words, electron-phonon coupling (EPC), in silicene layers on Ag(111) surface was probed by an in-situ Raman spectroscopy. We find the…

Materials Science · Physics 2015-05-20 Jincheng Zhuang , Xun Xu , Yi Du , Kehui Wu , Lan Chen , Weichang Hao , Jiaou Wang , Wai Kong Yeoh , Xiaolin Wang , Shi Xue Dou

Atomic resolution imaging in transmission electron microscopy (TEM) and scanning TEM (STEM) of light elements in electron-transparent materials has long been a challenge. Biomolecular materials, for example, are rapidly altered when…

Instrumentation and Detectors · Physics 2018-12-05 Fehmi S. Yasin , Tyler R. Harvey , Jordan J. Chess , Jordan S. Pierce , Colin Ophus , Peter Ercius , Benjamin J. McMorran

The interplay between discrete vibrational and electronic degrees of freedom directly influences the chemical and physical properties of molecular systems. This coupling is typically studied through optical methods such as fluorescence,…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 B. J. LeRoy , S. G. Lemay , J. Kong , C. Dekker

Vibrational spectroscopy, comprised of infrared absorption and Raman scattering spectroscopy, is widely used for label-free optical sensing and imaging in various scientific and industrial fields. The group theory states that the two…

Chemical Physics · Physics 2019-10-09 Kazuki Hashimoto , Venkata Ramaiah Badarla , Akira Kawai , Takuro Ideguchi

In this paper we discuss two approximate methods previously suggested for modeling hyperfine spectral line emission for molecules whose collisional transitions rates between hyperfine levels are unknown. Hyperfine structure is seen in the…

Astrophysics of Galaxies · Physics 2015-05-18 Eric Keto , George Rybicki