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Stacking two-dimensional (2D) materials into multi-layers or heterostructures, known as van der Waals (vdW) epitaxy, is an essential degree of freedom for tuning their properties on demand. Few-layer black phosphorus (FLBP), a material with…

Materials Science · Physics 2016-02-17 Zhi-Xin Hu , Xianghua Kong , Jingsi Qiao , Bruce Normand , Wei Ji

Black phosphorus (BP) with its enticing electric and optical properties is intensely researched in the field of optoelectronics. In this paper, Q-switched pulses at 1550 nm and 2 um wavelengths are obtained by inserting bulk-structured BP…

Optics · Physics 2015-04-29 Tian Jiang , Ke Yin , Xin Zheng , Hao Yu , Xiang-Ai Cheng

Phosphorene, the 2D material derived from black phosphorus, has recently attracted a lot of interest for its properties, suitable for applications in material science. In particular, the physical features and the prominent chemical…

Artificial monolayer black phosphorus, the so-called phosphorene has attracted global interest with its distinguished anisotropic optoelectronic and electronic properties. Here, we unraveled the shear-induced direct to indirect gap…

Materials Science · Physics 2015-05-14 Baisheng Sa , Yan-Ling Li , Zhimei Sun , Jingshan Qi , Cuilian Wen , Bo Wu

We report operating temperatures and heating coefficients measured in a multi-layer black phosphorus device as a function of injected electrical power. By combining micro-Raman spectroscopy and electrical transport measurements, we have…

Materials Science · Physics 2015-12-15 Michael Engel , Mathias Steiner , Shu-Jen Han , Phaedon Avouris

Few-layer black phosphorus (BP), also known as phosphorene, is poised to be the most attractive graphene analogue owing to its high mobility approaching that of graphene, and its thickness- tunable band gap that can be as large as that of…

Materials Science · Physics 2015-03-13 Joon-Seok Kim , Yingnan Liu , Weinan Zhu , Seohee Kim , Di Wu , Li Tao , Ananth Dodabalapur , Keji Lai , Deji Akinwande

Atomic layers of Black Phosphorus (BP) present unique opto-electronic properties dominated by a direct tunable bandgap in a wide spectral range from visible to mid-infrared. In this work, we investigate the infrared photoluminescence of BP…

Mesoscale and Nanoscale Physics · Physics 2021-01-13 Etienne Carré , Lorenzo Sponza , Alain Lusson , Ingrid Stenger , Etienne Gaufrès , Annick Loiseau , Julien Barjon

The electronic structure evolutions of few-layer black phosphorus (BP) under pressure shows a wealth of phenomena, such as the nonmonotonic change of direct gap at the {\Gamma} point, the layer-number dependence, and the distinct responses…

Mechanical straining-induced bandgap modulation in two-dimensional (2D) materials has been confined to volatile and narrow modulation due to substrate slippage and poor strain transfer. We report the thermomechanical modulation of the…

Black phosphorus exhibits a layered structure similar to graphene, allowing mechanical exfoliation of ultrathin single crystals. Here we demonstrate few-layer black phosphorus field effect devices on Si/SiO$_2$ and measure charge carrier…

Mesoscale and Nanoscale Physics · Physics 2015-06-18 Steven P. Koenig , Rostislav A. Doganov , Hennrik Schmidt , A. H. Castro Neto , Barbaros Oezyilmaz

We systematically explore chemical functionalization of monolayer black phosphorene via chemisorption of oxygen and fluorine atoms. Using the cluster expansion technique, with vary- ing concentration of the adsorbate, we determine the…

Materials Science · Physics 2016-04-14 Suhas Nahas , Barun Ghosh , Somnath Bhowmick , Amit Agarwal

Phosphorene is a novel two-dimensional material that can be isolated through mechanical exfoliation from layered black phosphorus, but unlike graphene and silicene, monolayer phosphorene has a large band gap. It was thus unsuspected to…

Materials Science · Physics 2015-02-18 Qihang Liu , Xiuwen Zhang , L. B. Abdalla , A. Fazzio , Alex Zunger

Black phosphorus thin films might offer attractive alternatives to narrow gap compound semiconductors for optoelectronics across mid- to near-infrared frequencies. In this work, we calculate the optical conductivity tensor of multilayer…

Materials Science · Physics 2014-09-18 Tony Low , A. S. Rodin , A. Carvalho , Yongjin Jiang , Han Wang , Fengnian Xia , A. H. Castro Neto

Chemical doping of bulk black phosphorus is a well-recognized way to reduce surface oxidation and degradation. Here, we report on the fabrication of terahertz frequency detectors consisting of an antenna-coupled field-effect transistor…

Mesoscale and Nanoscale Physics · Physics 2019-03-08 Leonardo Viti , Antonio Politano , Kai Zhang , Miriam Serena Vitiello

Discovery of atomically thin black phosphorus (called phosphorene) holds promise to be used as an alternative two-dimensional material to graphene and transition metal dichalcogenides especially as an anode material for lithium-ion…

Phosphorene, a two-dimensional (2D) monolayer of black phosphorus, has attracted considerable theoretical interest, although the experimental realization of monolayer, bilayer, and few-layer flakes has been a significant challenge. Here we…

Black phosphorus (BP) has recently attracted significant interest due to its unique electronic and optical properties. Doping is an effective strategy to tune a material's electronic structures, however, the direct and controllable growth…

Materials Science · Physics 2020-07-21 Mingqiang Liu , Simin Feng , Yi Hou , Shilong Zhao , Lei Tang , Jiaman Liu , Feng Wang , Bilu Liu

Isolation and characterization of mechanically exfoliated black phosphorus flakes with a thickness down to two single-layers is presented. A modification of the mechanical exfoliation method, which provides higher yield of atomically thin…

The effect of the number of stacking layers and the type of stacking on the electronic and optical properties of bilayer and trilayer black phosphorus are investigated by using first principles calcula- tions within the framework of density…

Mesoscale and Nanoscale Physics · Physics 2015-10-28 Deniz Cakir , Cem Sevik , Francois M. Peeters

This study presents a comprehensive first-principles investigation of the structural, electronic and optical properties of monolayer \ch{Mo_{1-x}W_xS2} alloys, systematically exploring the full compositional range ($x=0$ to $1$) using…