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Multifunctional properties in quantum systems require the interaction between different degrees of freedom. As such, spin-phonon coupling emerges as an ideal mechanism to tune multiferroicity, magnetism, and magnetoelectric response. In…

By applying Wannier-based extended Kugel-Khomskii model, we carry out first-principles calculations and electronic structure analysis to understand the spin-phonon coupling effect in transition-metal perovskites. We demonstrate the…

Materials Science · Physics 2017-08-17 Hongwei Wang , Lixin He , Hong Jiang , Cameron Steele , Xifan Wu

The coupling between localized spins and phonons can lead to shifts in the dielectric constant of insulating materials at magnetic ordering transitions. Studies on isostructural SeCuO3 (ferromagnetic) and TeCuO3 (antiferromagnetic)…

Materials Science · Physics 2009-04-14 G. Lawes , T. Kimura , C. M. Varma , M. A. Subramanian , R. J. Cava , A. P. Ramirez

Chiral symmetry breaking of phonons plays an essential role in emergent quantum phenomena owing to its strong coupling to spin degree of freedom. However, direct experimental evidence of the chiral phonon-spin coupling is lacking. In this…

We have investigated the temperature-dependent Raman-active phonons and the magnetic properties of Gd(Co1/2Mn1/2)O3 perovskite ceramics in the temperature range from 40 K to 300 K. The samples crystallized in an orthorhombic distorted…

Materials Science · Physics 2015-06-17 R. X. Silva , H. Reichlova , X. Marti , D. A. B. Barbosa , M. W. Lufaso , A. P. Ayala , C. W. A. Paschoal

Magnetic order typically emerges due to the short-range exchange interaction between the constituent electronic spins. Recent discoveries have found a crucial role for spin-phonon coupling in various phenomena from optical ultrafast…

Mesoscale and Nanoscale Physics · Physics 2024-05-16 Petros Andreas Pantazopoulos , Johannes Feist , Francisco J. García-Vidal , Akashdeep Kamra

We report on the microwave, terahertz (THz), infrared and Raman spectroscopic studies of $BiMn_{7}O_{12}$ ceramics, shedding more light into the nature of two structural phase transitions and their possible relation with ferroelectricity in…

Materials Science · Physics 2024-01-08 A. Maia , M. Kempa , V. Bovtun , R. Vilarinho , C. Kadlec , J. Agostinho Moreira , A. A. Belik , P. Proschek , S. Kamba

Spin-phonon coupling originated from spin-lattice correlation depends upon different exchange interactions in transition metal oxides containing 3d magnetic ions. Spin-lattice coupling can influence the coupling mechanism in magnetoelectric…

Strongly Correlated Electrons · Physics 2021-09-09 P. Pal , Shalini Badola , P. K. Biswas , Ranjana R. Das , Surajit Saha , S. D. Kaushik , P. N. Vishwakarma , A. K. Singh

In order to explore the consequences of spin-orbit coupling on spin-phonon interactions in a set of chemically-similar mixed metal oxides, we measured the infrared vibrational properties of Co$_4B_2$O$_9$ ($B$ = Nb, Ta) as a function of…

Materials Science · Physics 2023-05-26 K. Park , J. Kim , S. Choi , S. Fan , C. Kim , D. G. Oh , N. Lee , S. -W. Cheong , V. Kiryukhin , Y. J. Choi , D. Vanderbilt , J. H. Lee , J. L. Musfeldt

Hybrid or metal organic framework (MOF) perovskites of general composition, ABX$_3$, are known to show interesting properties which can lead to variety of technological applications. Our first principles study shows they are also potential…

Materials Science · Physics 2016-09-06 Hrishit Banerjee , Sudip Chakraborty , Tanusri Saha-Dasgupta

Spin-phonon coupling effects, as reflected in phonon frequency shifts between ferromagnetic (FM) and G-type antiferromagnetic (AFM) configurations in cubic CaMnO$_3$, SrMnO$_3$, BaMnO$_3$, LaCrO$_3$, LaFeO$_3$ and La$_2$(CrFe)O$_6$, are…

Strongly Correlated Electrons · Physics 2012-11-20 Jiawang Hong , Alessandro Stroppa , Jorge Íñiguez , Silvia Picozzi , David Vanderbilt

This a review article, which presents a general framework for the analysis of interatomic magnetic interactions in the spin-density-functional theory, which is based on the magnetic force theorem, make a link with the models for…

Materials Science · Physics 2007-05-23 I. V. Solovyev

Polarization induced spin switching of atoms in magnetic materials opens for possibilities to design and develop advanced spintronic devices, in particular, storage devices where the magnetic state can be controlled by an electric field. We…

Materials Science · Physics 2018-10-09 Indukuru Ramesh Reddy , Peter M. Oppeneer , Kartick Tarafder

Hybrid organic-inorganic perovskites are famous for the diversity of their chemical compositions, phases and phase transitions, and associated physical properties. We use a combination of experimental and computational techniques to reveal…

Multiferroicity and magnetodielectric coupling in metal-organic-frameworks (MOFs) is rare and so far restricted mainly to formate-based systems with perovskite structure. In the course of this work we designed a tetragonal framework…

Materials Science · Physics 2017-10-31 Tathamay Basu , A. Jesche , B. Bredenkotter , M. Grzywa , D. Denysenko , D. Volkmer , A. Loidl , S. Krohns

We show by extensive Monte Carlo simulations that we need a multi-spin interaction in addition to pairwise interactions in order to reproduce the temperature dependence of the experimental magnetization observed in the perovskite compound…

Strongly Correlated Electrons · Physics 2024-02-13 Yethreb Essouda , Hung T. Diep , Mohamed Ellouze

Both the Dzyaloshiskii-Moriya interaction and the exchange-striction are shown to affect dynamically the magnetoelectric excitations in the perovskite multiferroic RMnO3. The exchange-striction results in a biquadratic interaction between…

Strongly Correlated Electrons · Physics 2015-10-28 Chenglong Jia , Jamal Berakdar

Transition-metal perovskite oxides exhibit moderately correlated metallic phases, several of which exhibit a $T^2$ resistivity scaling up to temperatures far exceeding the regime where Fermi-liquid electron-electron scattering is expected…

Materials Science · Physics 2026-04-02 Jennifer Coulter , Fabian B. Kugler , Harrison LaBollita , Antoine Georges , Cyrus E. Dreyer

Magnetoelectric multiferroic materials, particularly with the perovskite structure, are receiving a lot of attention because of their inherent coupling between electrical polarization and magnetic ordering. However, very few types of direct…

Applied Physics · Physics 2017-09-07 Hong Jian Zhao , M. N. Grisolia , Yurong Yang , Jorge Iniguez , M. Bibes , Xiang Ming Chen , L. Bellaiche

Recently, the perovskite BiCoO$_3$ has been shown experimentally to be isostructural with PbTiO$_3$, while simultaneously the $d^6$ Co$^{3+}$ ion has a high spin ground state with $C$-type antiferromagnetic ordering. Using hybrid density…

Materials Science · Physics 2016-05-04 Leigh Weston , Xiangyuan Cui , Simon P. Ringer , Catherine Stampfl
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