Related papers: Torsional and rotational coupling in non-rigid mol…
A proof-of-principle experiment is reported, where torsional motion of a molecule, consisting of a pair of phenyl rings, is induced by strong laser pulses. A nanosecond laser pulse spatially aligns the carbon-carbon bond axis, connecting…
Torque is ubiquitous in many molecular systems, including collisions, chemical reactions, vibrations, electronic excitations and especially rotor molecules. We present a straightforward theoretical method based on forces acting on atoms and…
Following excitation by a strong ultra-short laser pulse, molecules develop coordinated rotational motion, exhibiting transient alignment along the direction of the laser electric field, followed by periodic full and fractional revivals…
We propose and computationally study a method for simultaneously orienting the angular momentum of asymmetric top molecules along: 1) a laboratory-fixed direction; 2) the molecular intermediate moment of inertia axis; 3) the laser field…
We investigate rotational state changes in a single collision of diatomic molecular ions, polar or apolar, with an atomic ion. Rotational state changes may occur since the angular degree of freedom of the molecular ions interacts with the…
In this work, we investigate the influence of torsion, Aharonov-Bohm flux, and external magnetic fields on the linear and nonlinear optical properties of a confined quantum system. The confinement potential is not assumed a priori, but…
We present a theoretical study of the time-dependent laser alignment of molecules taking into account the hyperfine coupling due to nuclear-quadrupole interactions. The coupling of nuclear spins to the overall angular momentum of molecules…
Coherent motion of electrons in a twisted quantum ring is considered to explore the effect of torsion inherent to the ring. Internal torsion of the ring composed of helical atomic configuration yields a non-trivial quantum phase shift in…
The dynamics of non-polar diatomic molecules interacting with a far-detuned narrow-band laser field, that only may drive rotational transitions, is studied. The rotation of the molecule is considered both classically and quantum…
It is demonstrated that strong laser pulses can introduce torsional motion in the axially chiral molecule 3,5-diflouro-3',5'-dibromo-biphenyl (DFDBrBPh). A nanosecond laser pulse spatially aligns the stereogenic carbon-carbon (C-C) bond…
The amplitude and probability of quantum transitions are represented as a path integrals in energy state space of the investigated multi-level quantum system. Using this approach we consider rotational dynamics of nitrogen molecules…
A moderately intense $450$ fs laser pulse is used to create rotational wave packets in gas phase $\rm{I_2}$ molecules. The ensuing time-dependent alignment, measured by Coulomb explosion imaging with a delayed probe pulse, exhibits the…
A theoretical model of nuclear spin conversion in molecules controlled by an external electromagnetic radiation resonant to rotational transition has been developed. It has been shown that one can produce an enrichment of spin isomers and…
Planar rotors can be realized by confining molecular ions or charged nanoparticles together with atomic ions in a Paul trap. We study the case of molecular ions or charged nanoparticles that have an electric dipole moment which couples to…
We investigate the torsional vibrations in biphenyl-like molecular junctions and transport properties in the presence of an external THz field. Ab-initio calculations including external electric fields show that the torsional angle {\phi}…
We formulate the theory for a diatomic molecule in a spatially degenerate electronic state interacting with a non-resonant laser field and investigate its rovibrational structure in the presence of the field. We report on \textit{ab initio}…
We review on the theoretical status of intense laser orientation and alignment. The evolution of the rotational wave packet and its dynamics leading to orientation and alignment is the topic of the present discussion. The major part of the…
We investigate the ultracold collisions of rotationally excited dipolar molecules in free-space, taking the hetero-nuclear bi-alkali molecule of KRb as an example. We show that we can sharply tune the elastic, inelastic and reactive rate…
We examine the potential-energy curves and polarization of the dipole moments of two static polar molecules under the influence of an external dc electric field and their anisotropic dipole-dipole interaction. We model the molecules as…
In novel ultra-pure materials electrons can form a viscous fluid, which is fundamentally different by its dynamics from the electron gas in ordinary conductors with significant density of defects. The shape of the non-stationary flow of…