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We demonstrate a scaling method for non-Markovian Monte Carlo wave-function simulations used to study open quantum systems weakly coupled to their environments. We derive a scaling equation, from which the result for the expectation values…

Quantum Physics · Physics 2009-11-10 J. Piilo , S. Maniscalco , A. Messina , F. Petruccione

Correlation clustering is a widely studied framework for clustering based on pairwise similarity and dissimilarity scores, but its best approximation algorithms rely on impractical linear programming relaxations. We present faster…

Data Structures and Algorithms · Computer Science 2022-06-27 Nate Veldt

Parallel tempering, also known as replica exchange Monte Carlo, is studied in the context of two simple free energy landscapes. The first is a double well potential defined by two macrostates separated by a barrier. The second is a `golf…

Statistical Mechanics · Physics 2013-05-29 Jon Machta

We present the theory, implementation, and benchmark results for a frozen natural spinors-based lower scaling four-component relativistic coupled cluster method. The natural spinors are obtained by diagonalizing the one-body reduced density…

Chemical Physics · Physics 2022-06-15 Somesh Chamoli , Kshitijkumar Surjuse , Malaya K. Nayak , Achintya Kumar Dutta

This paper presents a stable finite element approximation for the acoustic wave equation on second-order form, with perfectly matched layers (PML) at the boundaries. Energy estimates are derived for varying PML damping for both the discrete…

Numerical Analysis · Mathematics 2022-06-20 Gustav Ludvigsson , Kenneth Duru , Gunilla Kreiss

We describe an efficient approximation algorithm for evaluating the ground-state energy of the classical Ising Hamiltonian with linear terms on an arbitrary planar graph. The running time of the algorithm grows linearly with the number of…

Quantum Physics · Physics 2009-09-16 Nikhil Bansal , Sergey Bravyi , Barbara M. Terhal

Accurate theoretical methods are needed to correctly describe adsorption on solid surfaces or in porous materials. The random phase approximation with singles corrections scheme (RPA) and the second order M{\o}ller-Plesset perturbation…

Chemical Physics · Physics 2020-01-08 Jiří Klimeš , David P. Tew

A quenched second order phase transition is modeled by an effective $\Phi^4$-theory with a time-dependent Hamiltonian $\hat{H} (t)$, whose symmetry is broken spontaneously in time. The quantum field evolves out of equilibrium…

High Energy Physics - Phenomenology · Physics 2009-11-07 Sang Pyo Kim , Supratim Sengupta , F. C. Khanna

Sample-based quantum diagonalization (SQD) is a hybrid quantum-classical algorithm for estimating ground-state energies in electronic-structure calculations. It uses a quantum processor as a sampler to construct a variational subspace, with…

Quantum Physics · Physics 2026-04-21 Byeongyong Park , Sanha Kang , Jongseok Seo , Juhee Baek , Doyeol Ahn , Keunhong Jeong

In finite-size scaling analyses of Monte Carlo simulations of second-order phase transitions one often needs an extended temperature range around the critical point. By combining the parallel tempering algorithm with cluster updates and an…

Statistical Mechanics · Physics 2015-05-28 Elmar Bittner , Wolfhard Janke

We propose a two-step algorithm for optimal controlled islanding that partitions a power grid into islands of limited volume while optimizing several criteria: high generator coherency inside islands, minimum power flow disruption due to…

Optimization and Control · Mathematics 2017-05-09 Mikhail Goubko , Vasily Ginz

The well-known spatial integration schemes in molecular electronic structure theory, immune to cusps and point singularities of some kind at atomic positions, use a set of weighting functions to split the integrand into a sum of…

Chemical Physics · Physics 2022-09-14 Dimitri N. Laikov

We present a method for calculation of the second-order exchange-dispersion energy in the framework of the symmetry-adapted perturbation theory (SAPT) for weakly interacting monomers described with multiconfigurational wave functions. The…

Chemical Physics · Physics 2019-10-11 Hapka Michał , Przybytek Michał , Pernal Katarzyna

An algorithm, based on numerical description of the terms of many-body perturbation theory (Goldstone diagrams), is presented. The algorithm allows the use of the same piece of computer code to evaluate any particular diagram in any…

Atomic Physics · Physics 2015-05-13 V. A. Dzuba

A novel general approximation scheme (NGAS) proposed earlier (ref.2-3) is applied to the problem of the quartic anharmonic (QAHO) and the double-well-oscillator (QDWO) in quantum theory by choosing the infinite square-well-potential in one…

Quantum Physics · Physics 2014-05-13 B. P. Mahapatra , N. B. Pradhan

The modified Poisson-Boltzmann theory of the restricted primitive model double layer is revisited and recast in a fresh, slightly broader perspective. Derivation of relevant equations follow the techniques utilized in the earlier MPB4 and…

Statistical Mechanics · Physics 2017-10-05 L. B. Bhuiyan , C. W. Outhwaite

We present a classically solvable model that leads to optimized low-depth quantum circuits leveraging separable pair approximations. The obtained circuits are well suited as a baseline circuit for emerging quantum hardware and can, in the…

Quantum Physics · Physics 2022-04-07 Jakob S. Kottmann , Alán Aspuru-Guzik

Motivated by the recently proposed parallel orbital-updating approach in real space method, we propose a parallel orbital-updating based plane-wave basis method for electronic structure calculations, for solving the corresponding eigenvalue…

Computational Physics · Physics 2017-09-13 Yan Pan , Xiaoying Dai , Stefano de Gironcoli , Xin-Gao Gong , Gian-Marco Rignanese , Aihui Zhou

We study the phase diagram of a class of models in which a generalized cluster interaction can be quenched by Ising exchange interaction and external magnetic field. We characterize the various phases through winding numbers. They may be…

Statistical Mechanics · Physics 2017-09-06 Wei Nie , Feng Mei , Luigi Amico , Leong Chuan Kwek

We numerically examine divergences of the total energy in metallic systems of approximate many-body theories using Hartree--Fock as a reference, including perturbative (M\oller-Plesset, MP), coupled cluster (CC) and configuration…

Chemical Physics · Physics 2012-08-31 James J. Shepherd , Andreas Grüneis