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We establish large deviation principles (LDPs) for empirical measures associated with a sequence of Gibbs distributions on $n$-particle configurations, each of which is defined in terms of an inverse temperature $% \beta_n$ and an energy…

Probability · Mathematics 2020-01-07 Paul Dupuis , Vaios Laschos , Kavita Ramanan

We use rigorous non-equilibrium thermodynamic arguments to prove (i) the residual entropy of any system is bounded below by the experimentally (calorimetrically) determined absolute temperature entropy, which itself is bounded below by the…

Statistical Mechanics · Physics 2011-06-13 P. D. Gujrati

A detailed analysis of the adiabatic-piston problem reveals peculiar dynamical features that challenge the general belief that isolated systems necessarily reach a static equilibrium state. In particular, the fact that the piston behaves…

Classical Physics · Physics 2009-11-07 B. Crosignani , P. Di Porto , C. Conti

A simple procedure is presented to study the conservation of energy equation with dissipation in continuum mechanics in 1D. This procedure is used to transform this nonlinear evolution-diffusion equation into a hyperbolic PDE; specifically,…

Classical Physics · Physics 2020-08-13 Hamid A Said

In stochastic thermodynamics work is a random variable whose average is bounded by the change in the free energy of the system. In most treatments, however, the work reservoir that absorbs this change is either tacitly assumed or modelled…

Quantum Physics · Physics 2021-03-10 Patryk Lipka-Bartosik , Paweł Mazurek , Michał Horodecki

We extend the stochastic energetics to a relativistic system. The thermodynamic laws and equipartition theorem are discussed for a relativistic Brownian particle and the first and the second law of thermodynamics in this formalism are…

High Energy Physics - Theory · Physics 2013-05-24 T. Koide , T. Kodama

Certain fluctuations in particle number at fixed total energy lead exactly to a cut-power law distribution in the one-particle energy, via the induced fluctuations in the phase-space volume ratio. The temperature parameter is expressed…

Statistical Mechanics · Physics 2014-12-10 Tamas Sandor Biro , Peter Van , Gergely Gabor Barnafoldi , Karoly Urmossy

Generalization through novel interpretations of the inner logic of the century-old Gibbs' statistical thermodynamics is presented: i) Identifying $k_B\to 0$ as classical energetics, one directly derives a pair of thermodynamic variational…

Statistical Mechanics · Physics 2025-08-26 Bing Miao , Hong Qian , Yong-Shi Wu

We present a general framework for systems which are prepared in a non-stationary non-equilibrium state in the absence of any perturbation, and which are then further driven through the application of a time-dependent perturbation. We…

Statistical Mechanics · Physics 2012-12-06 Gatien Verley , David Lacoste

Iafrate, Miller, and Strauch [Equipartition and a Distribution for Numbers: A Statistical Model for Benford's Law," arXiv:1503.08259] construct and test a statistical model for partitioning a conserved quantity. One consequence of their…

Data Analysis, Statistics and Probability · Physics 2016-04-20 Don S. Lemons

We review and investigate the general theory of thermodynamics of computation, and derive the fundamental inequalities that set the lower bounds of the work requirement and the heat emission during a computation. These inequalities…

Statistical Mechanics · Physics 2015-06-17 Takahiro Sagawa

We argue that a very large class of quantum pure states of isolated macroscopic bodies have sharply peaked energy distributions, with their width relative to the average scaling between $\sim N^{-1}$ and $\sim N^{-1/2}$, with $N \gg 1$, the…

Quantum Physics · Physics 2021-07-15 Víctor Romero-Rochín

Reciprocal relations correlate fairly accurately a great variety of experimental results. Nevertheless, the concepts of statistical fluctuations, and microscopic reversibility - the bases of the accepted proof of the relations by Onsager -…

Chemical Physics · Physics 2007-05-23 Elias P. Gyftopoulos

All current formulations of thermodynamics invoke some form of coarse-graining or ensembles as the supposed link between their own laws and the microscopic laws of motion. They deal only with ensemble-averages, expectation values,…

Classical Physics · Physics 2017-05-30 Chiara Marletto

Thermodynamics of power means applies to an ideal quantum gas which may be nonextensive. Transition to an ideal classical gas occurs when the empirical temperature exponents of the internal energy and absolute temperature coalesce. Limiting…

Statistical Mechanics · Physics 2007-05-23 B. H. Lavenda

The meaning of thermodynamic descriptions is found in large-deviations scaling of the fluctuations probabilities. The primary large-deviations rate function is the entropy, which is the basis for both fluctuation theorems and for…

Statistical Mechanics · Physics 2015-05-27 Eric Smith

Keldysh field theory, based on adiabatic assumptions, serves as an widely used framework for addressing nonequilibrium many-body systems. Nonetheless, the validity of such adiabatic assumptions when addressing interacting Gibbs states…

Quantum Physics · Physics 2024-09-04 Yi Zuo , Qinghong Yang , Bang-Gui Liu , Dong E Liu

Equilibrium thermodynamics is grounded in the law of energy conservation, with a specific focus on how systems exchange energy with their environment during transitions between equilibrium states. These transitions are typically…

Statistical Mechanics · Physics 2024-08-19 Karol Makuch

A new thermodynamic inequality is derived which leads to the maximum work that can be extracted from multi-heat baths with the assistance of discrete quantum feedback control. The maximum work is determined by the free-energy difference and…

Quantum Physics · Physics 2009-11-13 Takahiro Sagawa , Masahito Ueda

We consider the task of extracting work from quantum systems in the resource theory perspective of thermodynamics, where free states are arbitrary thermal states, and allowed operations are energy conserving unitary transformations. Taking…

Quantum Physics · Physics 2013-02-13 Paul Skrzypczyk , Anthony J. Short , Sandu Popescu