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Materials containing high densities of exceptionally displaceable ions (e.g. perovskites) have extremely large ratios of their static to high-frequency dielectric constants, > 2. Large polarons form in such materials as their electronic…

Superconductivity · Physics 2020-08-26 David Emin

Exceptionally displaceable ions, evidenced by huge ratios of materials static to high-frequency dielectric constants, enable short-range electron-phonon interactions to stabilize large planar bipolarons. These large bipolarons are compact…

Superconductivity · Physics 2024-06-06 David Emin

Polarons are composite quasiparticles comprising electronic charge carriers taken together with the alterations they induce in surrounding condensed matter. Strong-coupling polarons form when electronic charge carriers become self-trapped:…

Strongly Correlated Electrons · Physics 2022-05-09 David Emin

There is a growing understanding that transport properties of complex oxides and individual molecules are dominated by polaron physics. In superconducting oxides the long-range Froehlich and short-range Jahn-Teller electron-phonon…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 A. S. Alexandrov

The BCS theory has been extended by us to the strong-coupling regime where carriers are small lattice polarons and bipolarons. Here I review the multi-polaron strong-coupling theory of superconductivity. Attractive electron correlations,…

Superconductivity · Physics 2008-05-23 A. S. Alexandrov

It is widely accepted that phonon-mediated high-temperature superconductivity is impossible at ambient pressure, because of the very large effective masses of polarons/bipolarons at strong electron-phonon coupling. Here we challenge this…

Superconductivity · Physics 2019-04-29 John Sous , Monodeep Chakraborty , Roman V. Krems , Mona Berciu

Planar large-bipolarons can form if the ratio of the surrounding mediums static to high-frequency dielectric constants is especially large. A large-bipolaron in p-doped La2CuO4 is modeled as two electrons being removed from the out-of-plane…

Superconductivity · Physics 2017-12-19 David Emin

A conduction electron (or hole) together with its self-induced polarisation in a polar semiconductor or an ionic crystal forms a quasi-particle, which is called a polaron. The polaron concept is of interest, not only because it describes…

Strongly Correlated Electrons · Physics 2007-05-23 J. T. Devreese

Distinctive normal-state properties of cuprate superconductors follow from their charge carriers forming a large-bipolaron liquid. The very weak scattering of the slow-moving heavy-massed excitations of the liquid by acoustic phonons yields…

Superconductivity · Physics 2017-12-19 David Emin

Employing unbiased sign-problem-free quantum Monte Carlo, we investigate the effects of long-range Coulomb forces on BEC of bipolarons using a model of bond phonon-modulated electron hopping. In absence of long-range repulsion, this model…

Superconductivity · Physics 2023-12-19 J. Sous , C. Zhang , M. Berciu , D. R. Reichman , B. V. Svistunov , N. V. Prokof'ev , A. J. Millis

The 2D lattice gas model with competing short and long range interactions is appliedused for calculation of the incoherent charge transport in the classical strongly-correlated charge segregated polaronic state. We show, by means of…

Strongly Correlated Electrons · Physics 2015-05-18 J. Miranda , T. Mertelj , V. Kabanov , D. Mihailovic

When the electron-phonon coupling is quadratic in the phonon coordinates, electrons can pair to form bipolarons due to phonon zero-point fluctuations, a purely quantum effect. We study superconductivity originating from this pairing…

Superconductivity · Physics 2024-09-18 Zhaoyu Han , Steven A. Kivelson , Pavel A. Volkov

In systems with linear electron-phonon interaction (EPI), bound states of polarons, or bipolarons, form by gaining energy from the lattice deformation. The quadratic EPI case is fundamentally different: bipolarons form because electrons…

Strongly Correlated Electrons · Physics 2025-01-14 Zhongjin Zhang , Anatoly Kuklov , Nikolay Prokof'ev , Boris Svistunov

Light-mass bipolarons in off-diagonally coupled electron-phonon systems provide a potential route to bipolaronic high-Tc superconductivity. While there has been numerical progress in the physically relevant limit of slow phonons, more…

Superconductivity · Physics 2023-08-28 Martin Grundner , Tizian Blatz , John Sous , Ulrich Schollwöck , Sebastian Paeckel

Phonon-mediated superconductivity is conventionally thought to be capped at a transition temperature $T_{\mathrm{c}}$ no larger than roughly one-tenth of the phonon frequency $\Omega$, a bound rooted in the breakdown of Migdal-Eliashberg…

Superconductivity · Physics 2026-05-19 John Sous

Electronic charge carriers in ionic materials can self-trap to form large polarons. Interference between the ionic displacements associated with oppositely charged large polarons increases as they approach one another. Initially this…

Other Condensed Matter · Physics 2018-02-05 David Emin

We have measured resistivity as a function of temperature and pressure of Ti4O7 twinned crystals using different contact configurations. Pressures over 4kbar depress the localization of bipolarons and allow the study of the electrical…

Strongly Correlated Electrons · Physics 2009-11-10 C. Acha , M. Monteverde , M. Nunez-Regueiro , A. Kuhn , M. A. Alario Franco

Developing a theory of high-temperature superconductivity in copper oxides is one of the outstanding problems in physics. It is a challenge that has defeated theoretical physicists for more than twenty years. Attempts to understand this…

Superconductivity · Physics 2015-05-20 Guo-meng Zhao

The formation of the electron-phonon induced bipolaron is shown to be feasible in organic semiconductors at the interface with dielectric gates due to the coupling of the carriers with interface vibrational modes and to the weak to…

Strongly Correlated Electrons · Physics 2015-11-26 C. A. Perroni , V. Cataudella

Small lattice bipolarons driven by external harmonic fields are considered in the adiabatic approximation. Resonant excitation of ions modulates the trapping potential and promotes hole transfer between neighboring atomic layers. It leads…

Superconductivity · Physics 2016-07-14 Pavel Kornilovitch
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