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What is the best description that we can construct of a thermodynamic system that is not in equilibrium, given only one, or a few, extra parameters over and above those needed for a description of the same system at equilibrium? Here, we…

Statistical Mechanics · Physics 2007-07-05 Gavin E. Crooks

In statistical physics, the challenging combinatorial enumeration of the configurations of a system subject to hard constraints (microcanonical ensemble) is mapped to a mathematically easier calculation where the constraints are softened…

Statistical Mechanics · Physics 2017-11-01 Tiziano Squartini , Diego Garlaschelli

Concepts of everyday use like energy, heat, and temperature have acquired a precise meaning after the development of thermodynamics. Thermodynamics provides the basis for understanding how heat and work are related and with the general…

Statistical Mechanics · Physics 2007-05-23 D. Reguera , J. M. Rubi , J. M. G. Vilar

Thermodynamic and dynamical properties of systems with long-range pairwise interactions (LRI), which decay as $1/r^{d+\sigma}$ at large distances $r$ in $d$ dimensions, are reviewed. Two broad classes of such systems are discussed. (i)…

Statistical Mechanics · Physics 2013-12-03 Freddy Bouchet , Shamik Gupta , David Mukamel

Ensemble inequivalence has been observed in several systems. In particular it has been recently shown that negative specific heat can arise in the microcanonical ensemble in the thermodynamic limit for systems with long-range interactions.…

Statistical Mechanics · Physics 2009-11-07 F. Leyvraz , S. Ruffo

A new approach to non-extensive thermodynamical systems with non-additive energy and entropy is proposed. The main idea of the paper is based on the statistical matching of the thermodynamical systems with the additive multi-step Markov…

Data Analysis, Statistics and Probability · Physics 2007-05-23 S. S. Apostolov , Z. A. Mayzelis , O. V. Usatenko , V. A. Yampol'skii

We examine the long-term behaviour of non-integrable, energy-conserved, 1D systems of macroscopic grains interacting via a contact-only generalized Hertz potential and held between stationary walls. Existing dynamical studies showed the…

Statistical Mechanics · Physics 2017-05-24 Michelle Przedborski , Surajit Sen , Thad A. Harroun

Ensemble inequivalence has been observed in several systems. In particular it has been recently shown that negative specific heat can arise in the microcanonical ensemble in the thermodynamic limit for systems with long-range interactions.…

Statistical Mechanics · Physics 2015-06-24 F. Leyvraz , S. Ruffo

The existence of the thermodynamic limit in spin systems with short- and long-range interactions is established. We consider the infinite-volume limit with a fixed shape of the system. The variational expressions of the entropy density and…

Statistical Mechanics · Physics 2015-03-18 Takashi Mori

To describe the nonequilibrium states of a system we introduce a new thermodynamic parameter - the lifetime of a system. The statistical distributions which can be obtained out of the mesoscopic description characterizing the behaviour of a…

Statistical Mechanics · Physics 2007-05-23 V. V. Ryazanov , S. G. Shpyrko

Non-reciprocal interactions are a generic feature of non-equilibrium systems. We define a non-reciprocal generalization of the kinetic Ising model in one spatial dimension. We solve the model exactly using two different approaches for…

Statistical Mechanics · Physics 2025-04-02 Gabriel Artur Weiderpass , Mayur Sharma , Savdeep Sethi

It is often incorrectly assumed that the number of microstates \Omega (E,V,N,...) available to an isolated system can have arbitrary dependence on the extensive variables E,V,N, .... However, this is not the case for natural systems which…

Statistical Mechanics · Physics 2013-07-31 K. Michaelian , I. Santamaría-Holek , A. Pérez-Madrid

The theory of small-system thermodynamics was originally developed to extend the laws of thermodynamics to length scales of nanometers. Here we review this "nanothermodynamics," and stress how it also applies to large systems that subdivide…

Statistical Mechanics · Physics 2020-07-28 Ralph V. Chamberlin , Michael R. Clark , Vladimiro Mujica , George H. Wolf

We investigate a two-level system in resonant contact with a larger environment. The environment typically is in a canonical state with a given temperature initially. Depending on the precise spectral structure of the environment and the…

Quantum Physics · Physics 2009-11-13 Harry Schmidt , Guenter Mahler

After reviewing some fundamental results derived from the introduction of the generalized Gibbs canonical ensemble, such as the called thermodynamic uncertainty relation, it is described a physical scenario where such a generalized ensemble…

Statistical Mechanics · Physics 2007-05-23 L. Velazquez

All ensembles of statistical mechanics are equivalent in the sense that they give the equivalent thermodynamic functions in the thermodynamic limit. However, when investigating microscopic structures in the first-order phase transition…

Statistical Mechanics · Physics 2019-05-13 Yasushi Yoneta , Akira Shimizu

In bulk systems the calculation of the main thermodynamic quantities leads to the same expectation values in the thermodynamic limit, regardless of the choice of the statistical ensemble. Single linear molecules can be still regarded as…

Soft Condensed Matter · Physics 2013-05-29 M. Süzen , M. Sega , C. Holm

Quantum systems are invariably open, evolving under surrounding influences rather than in isolation. Standard open quantum system methods eliminate all information on the environmental state to yield a tractable description of the system…

Quantum Physics · Physics 2014-09-26 Jake Iles-Smith , Neill Lambert , Ahsan Nazir

We propose a variational formulation for the nonequilibrium thermodynamics of discrete open systems, i.e., discrete systems which can exchange mass and heat with the exterior. Our approach is based on a general variational formulation for…

Mathematical Physics · Physics 2018-12-05 François Gay-Balmaz , Hiroaki Yoshimura

The laws of thermodynamics provide a clear concept of the temperature for an equilibrium system in the continuum limit. Meanwhile, the equipartition theorem allows one to make a connection between the ensemble average of the kinetic energy…

Statistical Mechanics · Physics 2009-11-13 Alex V. Popov , Rigoberto Hernandez