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Motivated for the fault tolerant quantum computation, quantum gate by adiabatic geometric phase shift is extensively investigated. In this paper, we demonstrate the nonadiabatic scheme for the geometric phase shift and conditional geometric…

Quantum Physics · Physics 2007-05-23 Wang Xiang-Bin , Matsumoto Keiji

Nonadiabatic transition dynamics lies at the core of many electron/hole transfer, photoactivated, and vacuum field-coupled processes. About a century after Ehrenfest proposed "Phasenraum" and the Ehrenfest theorem, we report a conceptually…

Quantum Physics · Physics 2024-04-09 Baihua Wu , Xin He , Jian Liu

The nonadiabatic dynamics of a many-body system driven through a quantum critical point can be controlled using counterdiabatic driving, where the formation of excitations is suppressed by assisting the dynamics with auxiliary multiple-body…

Quantum Physics · Physics 2014-12-08 Hamed Saberi , Tomáš Opatrný , Klaus Mølmer , Adolfo del Campo

Recently, geometric phases, which is fault tolerate to certain errors intrinsically due to its geometric property, are getting considerable attention in quantum computing theoretically. So far, only one experiment about adiabatic geometric…

Quantum Physics · Physics 2007-05-23 Jiangfeng Du , Mingjun Shi , Jihui Wu , Xianyi Zhou , Rongdian Han

Nonadiabatic molecular dynamics (NAMD) is widely used to describe hot electron relaxation and nonradiative recombination processes, but high computational costs limit its application to large supercells. Here, we implement a nonadiabatic…

Chemical Physics · Physics 2026-05-26 Xiaoke He , Hsiao-Yi Tsai , Ziwei Chai , Junwen Yin , Zhongfei Xu , Li-Min Liu

We present an approach for eliminating the gauge freedom for derivative couplings in nonadiabatic dynamics in the presence of geometric phase effects. This approach relies on a bottom-up construction of a parametric quantum Hamiltonian in…

Chemical Physics · Physics 2023-04-18 Alex Krotz , Roel Tempelaar

We present a novel quantum-classical approach to non-adiabatic dynamics, deduced from the coupled electronic and nuclear equations in the framework of the exact factorization of the electron-nuclear wave function. The method is based on the…

Chemical Physics · Physics 2015-08-19 Seung Kyu Min , Federica Agostini , E. K. U. Gross

Conditional geometric phase shift gate, which is fault tolerate to certain errors due to its geometric property, is made by NMR technique recently under adiabatic condition. By the adiabatic requirement, the result is inexact unless the…

Quantum Physics · Physics 2009-11-07 Wang Xiang-Bin , Matsumoto Keiji

We consider quantum dynamics for which the strict adiabatic approximation fails but which do not escape too far from the adiabatic limit. To treat these systems we introduce a generalisation of the time dependent wave operator theory which…

Quantum Physics · Physics 2015-06-16 David Viennot

In these lecture notes, partly based on a course taught at the Karpacz Winter School in March 2014, we explore the close connections between non-adiabatic response of a system with respect to macroscopic parameters and the geometry of…

Quantum Gases · Physics 2017-09-12 Michael Kolodrubetz , Dries Sels , Pankaj Mehta , Anatoli Polkovnikov

Understanding how non-adiabatic terms affect quantum dynamics is fundamental to improving various protocols for quantum technologies. We present a novel approach to computing the Adiabatic Gauge Potential (AGP), which gives information on…

Quantum Physics · Physics 2025-01-15 Ewen D C Lawrence , Sebastian F J Schmid , Ieva Čepaitė , Peter Kirton , Callum W Duncan

A first principles quantum formalism to describe the non-adiabatic dynamics of electrons and nuclei based on a second quantization representation (SQR) of the electronic motion combined with the usual representation of the nuclear…

Chemical Physics · Physics 2020-11-06 Sudip Sasmal , Oriol Vendrell

At present, several models for quantum computation have been proposed. Adiabatic quantum computation scheme particularly offers this possibility and is based on a slow enough time evolution of the system, where no transitions take place. In…

Quantum Physics · Physics 2012-10-12 P. J. Salas Peralta

We introduce an operational framework to analyze non-adiabatic Abelian and non-Abelian, cyclic and non-cyclic, geometric phases in open quantum systems. In order to remove the adiabaticity condition, we generalize the theory of dynamical…

Quantum Physics · Physics 2009-11-13 M. S. Sarandy , E. I. Duzzioni , M. H. Y. Moussa

Conical intersections are ubiquitous in polyatomic molecules and responsible for a wide range of phenomena in chemistry and physics. We introduce and implement a local diabatic representation for the correlated electron-nuclear dynamics…

Quantum Physics · Physics 2023-10-18 Bing Gu

Geometric quantum computation is the idea that geometric phases can be used to implement quantum gates, i.e., the basic elements of the Boolean network that forms a quantum computer. Although originally thought to be limited to adiabatic…

Quantum Physics · Physics 2016-09-16 Erik Sjöqvist , Vahid Azimi Mousolou , Carlo M. Canali

Nonadiabatic geometric phases are only dependent on the evolution path of a quantum system but independent of the evolution details, and therefore quantum computation based on nonadiabatic geometric phases is robust against control errors.…

Quantum Physics · Physics 2020-06-09 K. Z. Li , P. Z. Zhao , D. M. Tong

A precise definition of an adiabaticity parameter $\nu$ of a time-dependent Hamiltonian is proposed. A variation of the time-dependent perturbation theory is presented which yields a series expansion of the evolution operator…

High Energy Physics - Theory · Physics 2009-10-30 Ali Mostafazadeh

We consider the nonadiabatic energy fluctuations of a many-body system in a time-dependent harmonic trap. In the presence of scale-invariance, the dynamics becomes self-similar and the nondiabatic energy fluctuations can be found in terms…

Quantum Physics · Physics 2020-05-05 Mathieu Beau , Adolfo del Campo

We develop a unified theory for the nonadiabatic wave-packet dynamics of Bloch electrons subject to slowly varying spatial and temporal perturbations. Extending the conventional wave-packet ansatz to include interband contributions, we…

Materials Science · Physics 2026-04-13 Yafei Ren , M. E. Sanchez Barrero