Related papers: Superintermolecular orbitals in the C$_{60}$/penta…
A large body of knowledge about magnetism is attained from models of interacting spins, which usually reside on magnetic ions. Proposals beyond the ionic picture are uncommon and seldom verified by direct observations in conjunction with…
We report about high spatial resolution observations made with the IRAM interferometer of the CO emission from a 1.1x1.1 kpc plane-of-sky field on a spiral arm of Messier 81. With a beam of 5''(90 pc), we identify 6 giant molecular cloud…
The transition strengths for the four infrared-active vibrations of charged C$_{60}$ molecules are evaluated in self-consistent density functional theory using the local density approximation. The oscillator strengths for the second and…
Spin-orbit coupling (SOC) lifts molecular orbital degeneracy, enabling bi-level electronic platforms suitable for next-generation digital devices. However, common light-atom molecular feedstocks exhibit weak SOC due to the absence of heavy…
Molecules present a versatile platform for quantum information science, and are candidates for sensing and computation applications. Robust spin-optical interfaces are key to harnessing the quantum resources of materials. To date,…
The absolute differential oscillator strengths (DOS's) for the photoabsorption of the Ne, Ar, and Xe atoms encapsulated in the C$_{60}$ have been evaluated using the time-dependent-density-functional-theory, which solves the quantum…
A peculiar manifestation of orbital angular momentum is proposed for a zeolite-templated carbon system, C36H9. The structure, being a network of nanoflakes in the shape of a "pinwheel", lacks inversion symmetry. While the unit cell is…
The intrinsic spin-orbit coupling (ISOC) in bilayer graphene is investigated. We find that the largest ISOC between $\pi$ electrons origins from the following hopping processes: a $\pi$ electron hops to $\sigma$ orbits of the other layer…
Isomerism in complex organic molecules provides key insights into the formation mechanisms and physical conditions of the interstellar medium (ISM). Among the C$_2$H$_5$NO isomers, only acetamide and trans-N-methylformamide (trans-NMF) have…
We report the first high-resolution (sub-arcminute) large-scale mapping $^{12}$CO and $^{13}$CO observations of the molecular clouds associated with the giant outer Galaxy HII region CTB~102 (KR 1). These observations were made using a…
In atoms spin-orbit coupling (SOC) cannot raise the angular momentum above a maximum value or lower it below a minimum. Here we show that this need not be the case in materials built from nanoscale structures including multi-nuclear…
We investigate the molecular gas content and the excitation and fragmentation properties in the central region of the spiral galaxy Messier 81 in both the ^{12}CO(1-0) and ^{12}CO(2-1) transitions. We have recently observed the two…
We present here the 7.0-8.7 micron spectrum of the bright reflection nebula NGC 7023. Our observations are made with the Short Wavelength Spectrometer (SWS) on the European satellite Infrared Space Observatory (ISO). The vibrational bands…
Spin-orbit coupling (SOC) is a fundamental interaction in solids which can induce a broad spectrum of unusual physical properties from topologically non-trivial insulating states to unconventional pairing in superconductors. In iron-based…
Microscope mode imaging for secondary ion mass spectrometry is a technique with the promise of simultaneous high spatial resolution and high speed imaging of biomolecules from complex surfaces. Technological developments such as new…
Compact Obscured Nuclei (CONs) account for a significant fraction of the population of luminous and ultraluminous infrared galaxies (LIRGs and ULIRGs). These galaxy nuclei are compact, with radii of 10-100~pc, with large optical depths at…
Observations towards IRC +10216 of CS, SiO, SiS, NaCl, KCl, AlCl, AlF, and NaCN have been carried out with the IRAM 30-m telescope in the 80-357.5 GHz frequency range. A large number of rotational transitions covering a wide range of energy…
Large organic molecules and carbon clusters are basic building blocks of life, but their existence in the universe has not been confirmed beyond doubt. A number of unidentified absorption features (arising in the diffuse inter-stellar…
The simulated matter distribution on large scales is studied using core-sampling, cluster analysis, inertia tensor analysis, and minimal spanning tree techniques. Seven simulations in large boxes for five cosmological models with COBE…
The ground state of spin-1 ultracold bosons trapped in a periodic one-dimensional optical superlattice is studied. The two sites of the unit cell have an energy shift between them, whose competition with the spin-dependent strength is the…