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Introducing hierarchical disorder from multiple defects into materials through nanostructuring is one of the most promising directions to achieve extremely low thermal conductivities and thus improve thermoelectric performance. The success…

Materials Science · Physics 2019-09-16 Laura de Sousa Oliveira , Vassilios Vargiamidis , Neophytos Neophytou

Among all materials, mono-crystalline diamond has one of the highest measured thermal conductivities, with values above 2000 W/m/K at room temperature. This stems from momentum-conserving `normal' phonon-phonon scattering processes…

Declining the lattice thermal conductivity in graphene is essential for its thermoelectric applications. In high electron density systems, scatterings of phonons by electrons are no less than the phonon scatterings by other phonons. With…

Materials Science · Physics 2019-08-08 Ajit Jena , Wu Li

Last few years have witnessed significant enhancement of thermoelectric figure of merit of lead telluride (PbTe) via nanostructuring. Despite the experimental progress, current understanding of the electron transport in PbTe is based on…

Mesoscale and Nanoscale Physics · Physics 2017-09-26 Qichen Song , Te-Huan Liu , Jiawei Zhou , Zhiwei Ding , Gang Chen

Based on the Landauer formalism, we demonstrate that the thermal conductance due to the propagation of surface phonon-polaritons along a polar nanowire is independent of the material characteristics and is given by Pi^2kB^2T/3h. The giant…

Mesoscale and Nanoscale Physics · Physics 2016-11-25 Jose Ordonez-Miranda , Laurent Tranchant , Beomjoon Kim , Yann Chalopin , Thomas Antoni , Sebastian Volz

Based on the Debye-Callaway and the Klemens model, as well as molecular dynamics, the paper proposes mechanism of thermal conductivity reduction by embedding dense 60{\deg} shuffle-set dislocation arrays into silicon nano-films. Thermal…

Mesoscale and Nanoscale Physics · Physics 2016-07-12 Zhimin Jiang , Haisheng Fang , Zhenya Lv , Xiangang Luo , Lili Zheng

Using non-equilibrium molecular dynamics (NEMD) simulation, we study thermal properties of the so-called nanoporous graphene (NPG) sheet which contains a series of nanoporous in an ordered way and was synthesized recently (Science 360…

Computational Physics · Physics 2021-07-29 Farrokh Yousefi , Farhad Khoeini , Ali Rajabpour

Nonequilibrium electron distribution in a superlattice subjected to a homogeneous electric field (biased superlattice with equipopulated levels) is studied within the tight-binding approximation, taking into account the scattering by…

Materials Science · Physics 2015-05-13 A. Hernandez-Cabrera , P. Aceituno , F. T. Vasko

While using first-principles-based Boltzmann transport equation approach to predict the thermal conductivity of crystalline semiconductor materials has been a routine, the validity of the approach is seldom tested for high-temperature…

Mesoscale and Nanoscale Physics · Physics 2020-03-05 Xiaokun Gu , Shouhang Li , Hua Bao

We investigate the harmonic and anharmonic contributions to the phonon spectrum of lead telluride, and perform a complete characterization of how the anharmonic effects dominate the phonons in PbTe as temperature increases. This effect is…

Materials Science · Physics 2015-08-10 A. H. Romero , E. K. U. Gross , M. J. Verstraete , Olle Hellman

Understanding phonon scattering by topological defects in graphene is of particular interest for thermal management in graphene-based devices. We present a study that quantifies the roles of the different mechanisms governing defect phonon…

Materials Science · Physics 2016-11-04 Ziming Zhu , Xiaolong Yang , Mingyuan Huang , Qingfeng He , Guang Yang , Zhao Wang

Using the linearized Boltzmann transport equation and perturbation theory, we analyze the reduction in the intrinsic thermal conductivity of few-layer graphene sheets accounting for all possible three-phonon scattering events. Even with…

Mesoscale and Nanoscale Physics · Physics 2015-05-28 Dhruv Singh , Jayathi Y. Murthy , Timothy S. Fisher

We study the thermal transport properties of twisted-layer graphite nanofibers. We show that in the presence of a twisted layer, the phonon thermal conductance of a graphite nanofiber varies remarkably with the twisted angle and can reach…

Mesoscale and Nanoscale Physics · Physics 2022-08-31 Van-Truong Tran , Thanh-Tra Vu , Philippe Dollfus , Jérôme Saint-Martin , Marco Pala

Low thermal conductivity is favorable for preserving the temperature gradient between the two ends of a thermoelectric material in order to ensure continuous electron current generation. In high-performance thermoelectric materials, there…

We carry out a systematic study of the thermal conductivity of four single-layer transition metal dichalcogenides, MX$_2$ (M = Mo, W; X = S, Se) from first-principles by solving the Boltzmann Transport Equation (BTE). We compare three…

Materials Science · Physics 2019-03-29 Pol Torres , Francesc Xavier Alvarez , Xavier Cartoixà , Riccardo Rurali

We calculate the lattice thermal conductivities of the pyrite-type ZnSe2 at pressures of 0 and 10 GPa using the linearized phonon Boltzmann transport equation. We obtain a very low value [0.69 W/(mK) at room temperature at 0 GPa],…

Materials Science · Physics 2020-10-07 Tiantian Jia , Jesus Carrete , Zhenzhen Feng , Shuping Guo , Yongsheng Zhang , Georg K. H. Madsen

Diminution of the thermal conductivity is a crucial aspect in thermoelectric research. We report a systematic and significant reduction of the cross-plane thermal conductivity in a model system consisting of DC sputtered TiNiSn and HfNiSn…

Boundary scattering in hierarchically disordered nanomaterials is an effective way to reduce the thermal conductivity of thermoelectric materials and increase their performance. In this work we investigate thermal transport in silicon based…

Materials Science · Physics 2019-02-27 Dhritiman Chakraborty , Laura de Sousa Oliveira , Neophytos Neophytou

Surface scattering is the key limiting factor to thermal transport in dielectric crystals as the length scales are reduced or when temperature is lowered. To explain this phenomenon, it is commonly assumed that the mean free paths of heat…

Materials Science · Physics 2017-08-17 Andrea Cepellotti , Nicola Marzari

In this article, we address lattice heat transport in single-walled carbon nanotubes (CNTs) by a quantum mechanical calculation of three-phonon scattering rates in the framework of the Boltzmann transport equation (BTE) and classical…

Mesoscale and Nanoscale Physics · Physics 2020-05-06 Daniel Bruns , Alireza Nojeh , A. Srikantha Phani , Jörg Rottler
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