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The eigenstate thermalization hypothesis (ETH) provides a powerful framework for understanding thermalization in isolated quantum many-body systems, yet a complete and conceptually transparent derivation has remained elusive. In this work,…

Statistical Mechanics · Physics 2025-12-23 Yucheng Wang

This thesis describes the development of the density matrix embedding theory (DMET) and its applications to lattice strongly correlated electron problems, including a review of DMET theory and algorithms (Ch 2), investigation of finite size…

Strongly Correlated Electrons · Physics 2018-03-29 Bo-Xiao Zheng

The self-energy functional theory (SFT) is generalized to describe the real-time dynamics of correlated lattice-fermion models far from thermal equilibrium. This is achieved by means of a reformulation of the original equilibrium theory in…

Strongly Correlated Electrons · Physics 2013-10-21 Felix Hofmann , Martin Eckstein , Enrico Arrigoni , Michael Potthoff

Site-occupation embedding theory (SOET) is an alternative formulation of density-functional theory (DFT) for model Hamiltonians where the fully-interacting Hubbard problem is mapped, in principle exactly, onto an impurity-interacting…

Strongly Correlated Electrons · Physics 2018-06-13 Bruno Senjean , Naoki Nakatani , Masahisa Tsuchiizu , Emmanuel Fromager

Finite temperature density functional theory provides, in principle, an exact description of the thermodynamical equilibrium of many-electron systems. In practical applications, however, the functionals must be approximated. Efficient and…

Statistical Mechanics · Physics 2015-05-19 S. Pittalis , C. R. Proetto , A. Floris , A. Sanna , C. Bersier , K. Burke , E. K. U. Gross

We extend our density matrix embedding theory (DMET) [Phys. Rev. Lett. 109 186404 (2012)] from lattice models to the full chemical Hamiltonian. DMET allows the many-body embedding of arbitrary fragments of a quantum system, even when such…

Strongly Correlated Electrons · Physics 2013-11-15 Gerald Knizia , Garnet Kin-Lic Chan

Density functional theory (DFT) has greatly expanded our ability to affordably compute and understand electronic ground states, by replacing intractable {\em ab initio} calculations by models based on paradigmatic physics from high- and…

Chemical Physics · Physics 2023-03-29 Tim Gould , Derk P. Kooi , Paola Gori-Giorgi , Stefano Pittalis

Density functional theory (DFT) has transformed our ability to investigate and understand electronic ground states. In its original formulation, however, DFT is not suited to addressing (e.g.) degenerate ground states, mixed states with…

Chemical Physics · Physics 2025-10-30 Tim Gould , Leeor Kronik , Stefano Pittalis

We argue that the success of DFT can be understood in terms of a semiclassical expansion around a very specific limit. This limit was identified long ago by Lieb and Simon for the total electronic energy of a system. This is a universal…

Chemical Physics · Physics 2021-05-18 Pavel Okun , Kieron Burke

The recently proposed density functional theory for steady-state transport (i-DFT) is extended to include temperature gradients between the leads. Within this framework, a general and exact expression is derived for the linear Seebeck…

Strongly Correlated Electrons · Physics 2019-12-04 Nahual Sobrino , Roberto D'Agosta , Stefan Kurth

Density functional theory (DFT) embedding provides a formally exact framework for interfacing correlated wave-function theory (WFT) methods with lower-level descriptions of electronic structure. Here, we report techniques to improve the…

Chemical Physics · Physics 2015-06-12 Jason D. Goodpaster , Taylor A. Barnes , Frederick R. Manby , Thomas F. Miller

We introduce Extended Density Matrix Embedding Theory (EDMET), a static quantum embedding theory explicitly self-consistent with respect to local two-body physics. This overcomes the biggest practical and conceptual limitation of more…

Strongly Correlated Electrons · Physics 2021-12-22 Charles J. C. Scott , George H. Booth

We present an implementation of Triplet Excitation-Energy Transfer (TEET) couplings based on subsystem-based Time-Dependent Density-Functional Theory (sTDDFT). TEET couplings are systematically investigated by comparing "exact" and…

Chemical Physics · Physics 2023-12-13 Sabine Käfer , Niklas Niemeyer , Johannes Tölle , Johannes Neugebauer

We extend density matrix embedding theory to periodic systems, resulting in an electronic band structure method for solid-state materials. The electron correlation can be captured by means of a local impurity model using various choices of…

Strongly Correlated Electrons · Physics 2019-09-27 Hung Q. Pham , Matthew R. Hermes , Laura Gagliardi

The eigenstate thermalization hypothesis (ETH), which asserts that every eigenstate of a many-body quantum system is indistinguishable from a thermal ensemble, plays a pivotal role in understanding thermalization of isolated quantum…

Statistical Mechanics · Physics 2025-05-27 Shoki Sugimoto , Ryusuke Hamazaki , Masahito Ueda

The Extended Koopman's Theorem (EKT) provides a straightforward way to compute charged excitations from any level of theory. In this work we make the link with the many-body effective energy theory (MEET) that we derived to calculate the…

Strongly Correlated Electrons · Physics 2021-08-17 S. Di Sabatino , J. Koskelo , J. Prodhon , J. A. Berger , M. Caffarel , P. Romaniello

We propose a method for estimating smooth real-frequency self-energy in the dynamical mean-field theory with the finite-temperature exact diagonalization (DMFT-ED). One of the benefits of DMFT-ED calculations is that one can obtain…

Strongly Correlated Electrons · Physics 2019-06-10 Yuki Nagai , Hiroshi Shinaoka

A new reference state for density functional theory, termed the independent atom ansatz, is introduced in this work. This ansatz allows for the exact representation of electron density in terms of non-interacting, atom-localized orbitals.…

Chemical Physics · Physics 2024-05-03 Alexander V. Mironenko

The Eigenstate-Thermalization-Hypothesis (ETH) has been established as the general framework to understand quantum statistical mechanics. Only recently has the attention been paid to so-called full ETH, which accounts for higher-order…

Statistical Mechanics · Physics 2025-04-10 Silvia Pappalardi , Felix Fritzsch , Tomaž Prosen

We use field-theoretic methods to explore the statistics of eigenfunctions of the Floquet operator for a large family of Floquet random quantum circuits. The correlation function of the quasienergy eigenstates is calculated and shown to…

Quantum Physics · Physics 2022-10-14 Yunxiang Liao , Victor Galitski