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The properties of the interface between solid and melt are key to solidification and melting, as the interfacial free energy introduces a kinetic barrier to phase transitions. This makes solidification happen below the melting temperature,…

Statistical Mechanics · Physics 2015-12-02 Bingqing Cheng , Gareth A. Tribello , Michele Ceriotti

The kinetics of interfaces in alloy solidification pose a classic free boundary problem. This paper introduces an approach that amalgamates the distinctive characteristics of sharp and diffuse interface models. The motion of the diffuse…

Materials Science · Physics 2024-05-31 Chuanqi Zhu , Yuichiro Koizumi

A new phase field model is introduced, which can be viewed as nontrivial generalisation of what is known as the Caginalp model. It involves in particular nonlinear diffusion terms. By formal asymptotic analysis, it is shown that in the…

Analysis of PDEs · Mathematics 2012-01-18 Sylvie Benzoni-Gavage , Laurent Chupin , Didier Jamet , Julien Vovelle

Four results associated with the diffuse-interface model (DIM) for contact lines are reported in this paper. First, a boundary condition is derived, which states that the fluid near a solid wall must have a certain density $\rho_{0}$…

Fluid Dynamics · Physics 2021-09-27 E. S. Benilov

Phase field models are powerful tools to tackle free boundary problems. For phase transformations involving diffusion, the evolution of the non conserved phase field is coupled to the evolution of the conserved diffusion field. Introducing…

Materials Science · Physics 2015-06-18 G. Boussinot , Efim A. Brener

The no-slip boundary condition at a solid-liquid interface is at the center of our understanding of fluid mechanics. However, this condition is an assumption that cannot be derived from first principles and could, in theory, be violated. We…

Soft Condensed Matter · Physics 2008-10-12 Eric Lauga , Michael P. Brenner , Howard A. Stone

A coarse grained description of a two phase fluid is used to study the steady state configuration of the interface separating the coexisting phases, and the motion of the contact line at which the interface intersects a solid boundary. The…

Statistical Mechanics · Physics 2009-10-31 Hsuan-Yi Chen , David Jasnow , Jorge Vinals

Topographical and diffuse interface reconfigurations occur with a change in the solidification rate. In this article we pursue the hypothesis that the interface configuration during solidification is determined by the rate of entropy…

Materials Science · Physics 2017-02-14 Yaw Delali Bensah , J. A. Sekhar

Using equilibrium and nonequilibrium molecular dynamics simulations, we determine the Kapitza resistance (or thermal contact resistance) at a model liquid solid interface. The Kapitza resistance (or the associated Kapitza length) can reach…

Materials Science · Physics 2009-11-07 Jean-Louis Barrat , François Chiaruttini

We analyze the stability of a planar solid-solid interface at which a chemical reaction occurs. Examples include oxidation, nitridation, or silicide formation. Using a continuum model, including a general formula for the stress-dependence…

Materials Science · Physics 2009-10-31 G. Grinstein , Yuhai Tu , J. Tersoff

Kapitza thermal resistance is a common feature of material interfaces. It is defined as the ratio of the thermal drop at the interface to the heat flux flowing across the interface. One expects that this resistance will depend on the…

Statistical Mechanics · Physics 2020-03-18 Jithu Paul , O. V. Gendelman

A new diffuse interface model has been proposed in this study for simulating binary alloy solidification under universal cooling conditions, involving both equilibrium and non-equilibrium solute partitioning. Starting from the Gibbs-Thomson…

Materials Science · Physics 2023-09-22 Chuanqi Zhu , Yusuke Seguchi , Masayuki Okugawa , Yuichiro Koizumi

A general adsorption model is developed to describe the interactions between near-wall fluid molecules and solid surface. This model serves as a framework for the theoretical modelling of the boundary slip phenomena. Based on this…

Soft Condensed Matter · Physics 2016-12-26 Jian-Jun Shu , Ji Bin Melvin Teo , Weng Kong Chan

The thin interface limit aims at minimizing the effects arising from a numerical interface thickness, inherent in diffuse interface models of solidification and microstructure evolution such as the phase field model. While the original…

Materials Science · Physics 2020-03-18 Amol Subhedar , Peter K. Galenko , Fathollah Varnik

The response and nonconserved dynamics of a two-phase interface in the presence of a temperature gradient oriented normally to the interface are considered. Two types of boundary conditions on the order parameter are considered, and the…

Condensed Matter · Physics 2009-10-22 D. Boyanovsky , D. Jasnow , J. Llambias , F. Takakura

We study the boundary conditions at a fluid-solid interface using molecular dynamics simulations covering a broad range of fluid-solid interactions and fluid densities, and both simple and chain-molecule fluids. The slip length is shown to…

Statistical Mechanics · Physics 2009-10-31 Marek Cieplak , Joel Koplik , Jayanth R. Banavar

The process of rapid solidification of a binary mixture is considered in the framework of local nonequilibrium model (LNM) based on the assumption that there is no local equilibrium in solute diffusion in the bulk liquid and at the…

Materials Science · Physics 2020-03-18 G. L. Buchbinder , P. K. Galenko

We present an approach to theoretical assessment of the mean specific interface area $(\delta{S}/\delta{V})$ for a well-stirred system of two immiscible liquids experiencing interfacial boiling. The assessment is based on the balance of…

Statistical Mechanics · Physics 2017-05-03 Denis S. Goldobin , Anastasiya V. Pimenova

Interactions between an evolving solid and inviscid flow can result in substantial computational complexity, particularly in circumstances involving varied boundary conditions between the solid and fluid phases. Examples of such…

Fluid Dynamics · Physics 2022-09-30 Emma M. Schmidt , J. Matt Quinlan , Brandon Runnels

A phase-field model that allows for quantitative simulations of low-speed eutectic and peritectic solidification under typical experimental conditions is developed. Its cornerstone is a smooth free-energy functional, designed so that the…

Materials Science · Physics 2009-11-11 R. Folch , M. Plapp
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