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Phosphorene is a promising two dimensional (2D) material with a direct band gap, high carrier mobility, and anisotropic electronic properties. Phosphorene-based electronic devices, however, are found to degrade upon exposure to air. In this…

Materials Science · Physics 2016-04-14 Gaoxue Wang , William J. Slough , Ravindra Pandey , Shashi P. Karna

The electronic properties of the layered black phosphorus (black-P) and its monolayer counterpart phosphorene are investigated by using the first-principles calculations based on the density functional theory (DFT). The room-temperature…

Materials Science · Physics 2014-04-22 H. Y. Lv , W. J. Lu , D. F. Shao , Y. P. Sun

Two-dimensional (2D) carbon-based materials have attracted considerable interest due to their diverse structural and electronic properties, making them ideal for next-generation flat electronics. Among these materials, metallic-like porous…

The anisotropic nature of the new two-dimensional (2D) material phosphorene, in contrast to other 2D materials such as graphene and transition metal dichalcogenide (TMD) semiconductors, allows excitons to be confined in a…

Phosphorene has been rediscovered recently, establishing itself as one of the most promising two dimensional group-V elemental monolayers with direct band gap, high carrier mobility, and anisotropic electronic properties. In this letter,…

Materials Science · Physics 2016-03-24 Gaoxue Wang , G. C. Loh , Ravindra Pandey , Shashi P. Karna

Low-connectivity polymer networks were recently found to behave auxetically when subjected to small tensions, that is, their Poisson's ratio $\nu$ becomes negative. In addition, for specific state points, numerical simulations revealed that…

Soft Condensed Matter · Physics 2024-01-30 Andrea Ninarello , José Ruiz-Franco , Emanuela Zaccarelli

Auxetic materials, or negative-Poisson's-ratio materials, are important technologically and fascinating theoretically. When loaded by external stresses, their internal strains are governed by correlated motion of internal structural degrees…

Materials Science · Physics 2012-04-16 Raphael Blumenfeld , Sam F. Edwards

We systematically evaluate the prospects of a novel 2D nanomaterial, phosphorene, as anode for Na-ion batteries. Using first-principles calculations, we determine the Na adsorption energy, specific capacity and Na diffusion barriers on…

Materials Science · Physics 2015-06-24 Vadym V. Kulish , Oleksandr I. Malyi , Clas Persson , Ping Wu

A symmetry-extended Maxwell treatment of the net mobility of periodic bar-and-joint frameworks is used to derive a sufficient condition for auxetic behaviour of a 2D material. The type of auxetic behaviour that can be detected by symmetry…

Materials Science · Physics 2015-06-16 H. Mitschke , G. E. Schroeder-Turk , K. Mecke , P. W. Fowler , S. D. Guest

In recent years, new flexible functional materials have attracted increasing interest, but there is a lack of the designing mechanisms of flexibility design with superstructures. In traditional engineering mechanics, the maximum bending…

Soft Condensed Matter · Physics 2023-09-06 Yang Li , Le Zhang , Dehua Wang , Limei Hou , Shanmei Du , Yang Deng , Yanfeng Du , Yingfei Xin , Chongyang Fu , Yan Gu , Xiaoxiong Wang

Three two-dimensional phosphorus nitride (PN) monolayer sheets (named as $\alpha$-, $\beta$-, and $\gamma$-PN, respectively) with fantastic structures and properties are predicted based on first-principles calculations. The $\alpha$-PN and…

Materials Science · Physics 2015-10-02 ShuangYing Ma , Chaoyu He , L. Z. Sun , Haiping Lin , Youyong Li , K. W. Zhang

We compute binding energies, Stark shifts, electric-field-induced dissociation rates, and the Franz-Keldysh effect for excitons in phosphorene in various dielectric surroundings. All three effects show a pronounced dependence on the…

Mesoscale and Nanoscale Physics · Physics 2020-09-23 Høgni C. Kamban , Thomas G. Pedersen , Nuno M. R. Peres

Against common sense, auxetic materials expand or contract perpendicularly when stretched or compressed, respectively, by uniaxial strain, being characterized by a negative Poisson's ratio $\nu$. The amount of deformation in response to the…

Soft Condensed Matter · Physics 2022-02-22 Andrea Ninarello , José Ruiz-Franco , Emanuela Zaccarelli

We report the computational discovery and characterization of Dodecaphenylyne (DP), a novel carbon allotrope with a distinctive geometric arrangement. DP structural, thermodynamic, mechanical, electronic, and optical properties were…

In a very recent experimental work [Gao et al., 2018 Adv. Mater. 30, 1707055], a graphene-like CuSe monolayer was realized. Motivated by this success, we performed first-principles calculations to investigate its electronic transport and…

Mesoscale and Nanoscale Physics · Physics 2019-04-18 Yipeng An , Yusheng Hou , Hui Wang , Jie Li , Ruqian Wu , Chengyan Liu , Tianxing Wang , Jutao Jiao

Anthracyne (2DDA). 2DDA consists of chains of Dewar-anthracenes connected by acetylenic linkages. DFT-based simulations show that 2DDA is thermally stable and exhibits no imaginary phonon modes, confirming its dynamic stability. 2DDA is…

This paper is devoted to the exploration of rectangular finite elements' ability to model the stress-strain state of isotropic and orthotropic materials with a negative Poisson's ratio, known as auxetic materials. By employing linear…

Computational Physics · Physics 2025-05-13 A. V. Mazaev

The Seebeck coefficient is an important quantity in determining the thermoelectric efficiency of a material. Phosphorene is a two-dimensional material with a puckered structure, which makes its properties anisotropic. In this work, a…

Materials Science · Physics 2023-01-05 M. Amir Bazrafshan , Farhad Khoeini

Anisotropic materials, with orientation-dependent properties, have attracted more and more attention due to their compelling tunable and flexible performance in electronic and optomechanical devices. So far, two-dimensional (2D) black…

Materials Science · Physics 2020-12-17 Xuefei Liu , Zhaofu Zhang , Zhao Ding , Bing Lv , Zijiang Luo , Jian-Sheng Wang , Zhibin Gao

Phosphorene, a single atomic layer of black phosphorus, has recently emerged as a new twodimensional (2D) material that holds promise for electronic and photonic technology. Here we experimentally demonstrate that the electronic structure…

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