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Using seven semiconductors/insulators with band gaps covering the range from 1 eV to 10 eV we systematically explore the performance of two different variants of self-consistency associated with famous Hedin's system of equations: the full…

Materials Science · Physics 2022-01-20 Andrey L. Kutepov

A few self-consistent schemes to solve the Hedin equations are presented. They include vertex corrections of different complexity. Commonly used quasiparticle approximation for the Green function and static approximation for the screened…

Strongly Correlated Electrons · Physics 2016-10-12 Andrey L. Kutepov

Superconductors are often discussed in the mean-field approximation that breaks $U(1)$ symmetry. Since the $U(1)$ symmetry underlies the charge conservation, naive application of response theory sometimes gives results that are not…

Superconductivity · Physics 2024-10-25 Sena Watanabe , Haruki Watanabe

A few approximate schemes to solve the Hedin equations self-consistently introduced in (Phys. Rev. B 94, 155101 (2016)) are explored and tested for the 3D electron gas at metallic densities. We calculate one electron spectra, dielectric…

Strongly Correlated Electrons · Physics 2017-07-12 A. L. Kutepov , G. Kotliar

Hedin's scheme is solved with the inclusion of the vertex function ($GW\Gamma$) for a set of small molecules. The computational scheme allows for the consistent inclusion of the vertex both at the polarizability level and in the…

Materials Science · Physics 2017-08-17 Emanuele Maggio , Georg Kresse

Hedin's $GW$ approximation to the electronic self-energy has been impressively successful to calculate quasiparticle energies, such as ionization potentials, electron affinities, or electronic band structures. The success of this fairly…

Chemical Physics · Physics 2024-10-31 Arno Förster , Fabien Bruneval

First principle calculations based on LDA/GGA approximation for the exchange functional underestimate the position of the semi core 3d levels in GaX (X = N, P and As) semiconductors. A self-interaction correction scheme within the…

Materials Science · Physics 2007-06-05 Roby Cherian , Priya Mahadevan , Clas Persson

Theoretical studies of semiconductors and band insulators are usually based on variants of the $GW$ method without full self-consistency, like single-shot $G^0W^0$ or quasiparticle self-consistent $GW$. Fully self-consistent $GW$ provides a…

Strongly Correlated Electrons · Physics 2024-10-28 Viktor Christiansson , Francesco Petocchi , Philipp Werner

We present an approach to calculate the optical absorption spectra that combines the quasiparticle self-consistent GW method [Phys. Rev. B, 76 165106 (2007)] for the electronic structure with the solution of the ladder approximation to the…

Materials Science · Physics 2018-03-21 Brian Cunningham , Pooya Azarhoosh , Dimitar Pashov , Myrta Gruening , Mark van Schilfgaarde

A novel picture of the quasiparticle (QP) gap in prototype semiconductors Si and Ge emerges from an analysis based on all-electron, self-consistent, GW calculations. The deep-core electrons are shown to play a key role via the exchange…

Materials Science · Physics 2009-11-07 Wei Ku , A. G. Eguiluz

We present an approach to calculate the electronic structure for a range of materials using the quasiparticle self-consistent GW method with vertex corrections included in the screened Coulomb interaction W. This is achieved by solving the…

Materials Science · Physics 2023-10-10 Brian Cunningham , Myrta Gruening , Dimitar Pashov , Mark van Schilfgaarde

Within many-body perturbation theory, Hedin's formalism offers a systematic way to iteratively compute the self-energy $\Sigma$ of any interacting system, provided one can evaluate the interaction vertex $\Gamma$ exactly. This is however…

Chemical Physics · Physics 2022-11-04 Carlos Mejuto-Zaera , Vojtěch Vlček

The accurate prediction of band gaps and structural properties in periodic systems continues to be one of the central goals of electronic structure theory. However, band gaps obtained from popular exchange-correlation functionals (such as…

Materials Science · Physics 2022-03-18 Ravindra Shinde , Sharma S. R. K. C. Yamijala , Bryan M. Wong

The vertex function ($\Gamma$) within the Green's function formalism encapsulates information about all higher-order electron-electron interaction beyond those mediated by density fluctuations. Herein, we present an efficient approach that…

Chemical Physics · Physics 2023-03-28 Guorong Weng , Rushil Mallarapu , Vojtech Vlcek

For materials which are incorrectly predicted by density functional theory to be metallic, an iterative procedure must be adopted in order to perform GW calculations. In this paper we test two iterative schemes based on the quasi-particle…

Materials Science · Physics 2007-05-23 V. A. Popa , G. Brocks , P. J. Kelly

We present a systematic study of vertex corrections in the homogeneous electron gas at metallic densities. The vertex diagrams are built using a recently proposed positive-definite diagrammatic expansion for the spectral function. The…

Strongly Correlated Electrons · Physics 2016-11-15 Y. Pavlyukh , A. -M. Uimonen , G. Stefanucci , R. van Leeuwen

The good performance of the GW approximation for band-structure calculations in solids was long taken as a sign that the sum of self-energy diagrams is converged and that all omitted terms are small. However, with modern computational…

Materials Science · Physics 2007-05-23 Arno Schindlmayr

We compute the electronic band structure and optical properties of boron arsenide using the relativistic quasiparticle self-consistent $GW$ approach, including electron-hole interactions through solution of the Bethe-Salpeter equation. We…

Materials Science · Physics 2019-06-07 John Buckeridge , David O. Scanlon

The conductivity of the two-dimensional Hubbard model is particularly relevant for high-temperature superconductors. Vertex corrections are expected to be important because of strongly momentum dependent self-energies. We use the…

Strongly Correlated Electrons · Physics 2015-03-17 Dominic Bergeron , Vasyl Hankevych , Bumsoo Kyung , A. -M. S. Tremblay

Self-consistent solutions of Hedin's diagrammatic theory equations (HE) for the two-site Hubbard Model (HM) have been studied. They have been found for three-point vertices of increasing complexity ($\Gamma=1$ (GW approximation),…

Strongly Correlated Electrons · Physics 2016-05-27 A. L. Kutepov
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