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We present the numerical implementation of the time-dependent complete-active-space self-consistent-field (TD-CASSCF) method [Phys. Rev. A, 88, 023402 (2013)] for atoms driven by a strong linearly polarized laser pulse. The present…

We introduce novel high order well-balanced finite volume methods for the full compressible Euler system with gravity source term. They require no a priori knowledge of the hydrostatic solution which is to be well-balanced and are not…

Numerical Analysis · Mathematics 2020-12-16 Jonas P. Berberich , Roger Käppeli , Praveen Chandrashekar , Christian Klingenberg

We have recently discussed an algorithm to automatically generate auxiliary basis sets (ABSs) of the standard form for density fitting (DF) or resolution-of-the-identity (RI) calculations in a given atomic orbital basis set (OBS) of any…

Computational Physics · Physics 2023-10-30 Susi Lehtola

Continuous wavefront sensing on future space telescopes allows relaxation of stability requirements while still allowing on-orbit diffraction-limited optical performance. We consider the suitability of phase retrieval to continuously…

Instrumentation and Methods for Astrophysics · Physics 2023-09-14 Hyukmo Kang , Kyle Van Gorkom , Jess Johnson , Ole Singlestad , Aaron Goldtooth , Daewook Kim , Ewan S. Douglas

Two-level domain decomposition preconditioners lead to fast convergence and scalability of iterative solvers. However, for highly heterogeneous problems, where the coefficient function is varying rapidly on several possibly non-separated…

Numerical Analysis · Mathematics 2022-07-13 Alexander Heinlein , Kathrin Smetana

We introduce higher order polynomial deformations of $A_1$ Lie algebra. We construct their unitary representations and the corresponding single-variable differential operator realizations. We then use the results to obtain exact (Bethe…

Mathematical Physics · Physics 2015-05-18 Yuan-Harng Lee , Wen-Li Yang , Yao-Zhong Zhang

In this work, we propose two-level space-time domain decomposition preconditioners for parabolic problems discretized using finite elements. They are motivated as an extension to space-time of balancing domain decomposition by constraints…

Numerical Analysis · Computer Science 2017-01-16 Santiago Badia , Marc Olm

A solver for the Poisson equation for 1D, 2D and 3D regular grids is presented. The solver applies the convolution theorem in order to efficiently solve the Poisson equation in spectral space over a rectangular computational domain.…

Mathematical Software · Computer Science 2023-01-04 Joseph Saverin

We introduce an energy functional for ground-state electronic structure calculations. Its variables are the natural spin-orbitals of singlet many-body wave functions and their joint occupation probabilities deriving from controlled…

Chemical Physics · Physics 2016-12-04 Ralph Gebauer , Morrel H. Cohen , Roberto Car

We are interested in coupled semi-linear wave equations satisfying the null condition in two space dimensions, a basic model in nonlinear wave equations. Our aim is to establish global existence of smooth solutions to this system with large…

Analysis of PDEs · Mathematics 2025-07-21 Bingbing Ding , Shijie Dong , Gang Xu

A nonlinear multigrid solver for two-phase flow and transport in a mixed fractional-flow velocity-pressure-saturation formulation is proposed. The solver, which is under the framework of the full approximation scheme (FAS), extends our…

Numerical Analysis · Mathematics 2021-09-17 Chak Shing Lee , François P. Hamon , Nicola Castelletto , Panayot S. Vassilevski , Joshua A. White

Convergence of domain decomposition methods rely heavily on the efficiency of the coarse space used in the second level. The GenEO coarse space has been shown to lead to a fully robust two-level Schwarz preconditioner which scales well over…

Numerical Analysis · Mathematics 2020-08-04 Frédéric Nataf

Building upon recent results obtained in [7,8,9], we describe an efficient second order, A-stable scheme for solving the wave equation, based on the method of lines transpose (MOL$^T$), and the resulting semi-discrete (i.e. continuous in…

Numerical Analysis · Mathematics 2015-12-17 Matthew Causley , Andrew Christlieb , Eric Wolf

We present a self-consistent approach for computing the correlated quasiparticle spectrum of charged excitations in iterative $\mathcal{O}[N^5]$ computational time. This is based on the auxiliary second-order Green's function approach [O.…

Chemical Physics · Physics 2020-10-05 Oliver J. Backhouse , George H. Booth

A class of second-order algorithms is proposed for minimizing smooth nonconvex functions that alternates between regularized Newton and negative curvature steps in an iteration-dependent subspace. In most cases, the Hessian matrix is…

Optimization and Control · Mathematics 2023-08-22 Serge Gratton , Sadok Jerad , Philippe L. Toint

In recent years, a new class of mixed finite elements -- compatible-strain mixed finite elements (CSMFEs) -- has emerged that uses the differential complex of nonlinear elasticity. Their excellent performance in benchmark problems, such as…

Numerical Analysis · Mathematics 2025-04-29 Mohsen Jahanshahi , Damiano Pasini , Arash Yavari

In this paper, we study the nuclear gradients of heat bath configuration interaction self-consistent field (HCISCF) wave functions and use them to optimize molecular geometries for various molecules. We show that the HCISCF nuclear…

Chemical Physics · Physics 2022-09-14 James E. T. Smith , Joonho Lee , Sandeep Sharma

The analysis of fields in periodic dielectric structures arise in numerous applications of recent interest, ranging from photonic bandgap (PBG) structures and plasmonically active nanostructures to metamaterials. To achieve an accurate…

Computational Physics · Physics 2012-11-22 Andrew D. Baczewski , Nicholas C. Miller , Balasubramaniam Shanker

The presence of second-order smoothness for objective functions of optimization problems can provide valuable information about their stability properties and help us design efficient numerical algorithms for solving these problems. Such…

Optimization and Control · Mathematics 2023-08-04 N. T. V. Hang , M. E. Sarabi

A high-order accurate adjoint-based optimization framework is presented for unsteady multiphysics problems. The fully discrete adjoint solver relies on the high-order, linearly stable, partitioned solver introduced in [1], where different…

Numerical Analysis · Mathematics 2019-01-01 Daniel Z. Huang , Per-Olof Persson , Matthew J. Zahr