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We propose the design of low strained and energetically favourable mono and bilayer graphene overlayer on anatase TiO$_2$ (001) surface and examined the electronic structure of the interface with the aid of first principle calculations. In…

Materials Science · Physics 2020-12-22 Shashi B. Mishra , Somnath C. Roy , B. R. K. Nanda

The computational modeling of many engineering problems using the Finite Element method involves the modeling of two or more bodies that meet through an interface. The interface can be physical, as in multi-physics and contact problems, or…

Numerical Analysis · Computer Science 2009-09-30 G. Haikal

In this work, we perform ab initio calculations, based on the density functional theory, of the effects on the graphene bilayer when we intercalate carbon atoms between the layers. We use the unit cell of the bilayer to construct larger…

Mesoscale and Nanoscale Physics · Physics 2020-01-31 A. K. M. Pinto , N. F. Frazão , D. L. Azevedo , F. Moraes

Structural correlations at a liquid-solid interface were explored with molecular dynamics simulations of a model aluminium system using the Ercolessi-Adams potential and up to 4320 atoms. Substrate atoms were pinned to their equilibrium…

Materials Science · Physics 2007-05-23 Adham Hashibon , Joan Adler , Michael W. Finnis , Wayne D. Kaplan

A lattice-gas model is suggested for describing the ordering phenomena in alkali-metal fullerides of face-centered-cubic structure assuming the electric charge of alkali ions residing in either octahedral or tetrahedral interstitial sites…

Condensed Matter · Physics 2009-10-28 Laszlo Udvardi , Gyorgy Szabo

We use conformal field theory to construct model wavefunctions for a gapless interface between lattice versions of a bosonic Laughlin state and a fermionic Moore-Read state, both at $\nu=1/2$. The properties of the resulting model state,…

Strongly Correlated Electrons · Physics 2021-05-28 Błażej Jaworowski , Anne E. B. Nielsen

Numerically minimizing a continuous free-energy functional which yields several modulated phases, we obtain the order-parameter profiles and interfacial free energies of symmetric and non-symmetric tilt boundaries within the lamellar phase,…

Soft Condensed Matter · Physics 2009-10-31 R. R. Netz , D. Andelman , M. Schick

Understanding the interface between metals and two-dimensional materials is critical for their application in electronics and for the development of metal-mediated exfoliation of large area monolayers. Studying the intricate interactions at…

Potential steps exceeding 1 eV are regularly formed at metal|insulator interfaces, even when the interaction between the materials at the interface is weak physisorption. From first-principles calculations on metal|h-BN interfaces we show…

Mesoscale and Nanoscale Physics · Physics 2014-12-01 Menno Bokdam , Geert Brocks , Paul J. Kelly

This work describes the development of a third-generation charge optimized many-body (COMB3) potential for Al-C and its application to the investigation of aluminum/graphene nanostructures. In particular, the new COMB3 potential was used to…

Materials Science · Physics 2019-12-04 Difan Zhang , Alexandre F. Fonseca , Tao Liang , Simon R. Phillpot , Susan B. Sinnott

The nature of electron correlations in bilayer graphene has been investigated. An analytic expression for the radial distribution function is derived for an ideal electron gas and the corresponding static structure factor is evaluated. We…

Mesoscale and Nanoscale Physics · Physics 2015-05-20 D. S. L. Abergel , Tapash Chakraborty

Atomistic simulations of electrochemical interfaces remain challenging due to the long time scales required to adequately sample the structure of the electric double layer. The emergence of efficient, short-range machine learning…

Metal-organic frameworks (MOFs) are nanoporous compounds composed of metal ions and organic linkers. MOFs play an important role in industrial applications such as gas separation, gas purification, and electrolytic catalysis. Important MOF…

Machine Learning · Computer Science 2020-11-02 Shehtab Zaman , Christopher Owen , Kenneth Chiu , Michael Lawler

An exact description of $\pi$ electrons based on the tight-binding model of graphene as an alternant, plane macromolecule is presented. The model molecule can contain an arbitrary number of benzene rings and has armchair- and zigzag-shaped…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Alexander Onipko

We have used first-principles methods to investigate how metal atoms dispersed in the interlayer space of graphitic materials affect their hydrogen-binding properties. We have considered ideal stage-one metal-intercalated graphites of…

Materials Science · Physics 2008-06-19 Manuel Cobian , Jorge Iniguez

The alignment of the frontier orbital energies of an adsorbed molecule with the substrate Fermi level at metal-organic interfaces is a fundamental observable of significant practical importance in nanoscience and beyond. Typical density…

Mesoscale and Nanoscale Physics · Physics 2017-03-07 Zhenfei Liu , David A. Egger , Sivan Refaely-Abramson , Leeor Kronik , Jeffrey B. Neaton

One of the enticing features common to most of the two-dimensional electronic systems that are currently at the forefront of materials science research is the ability to easily introduce a combination of planar deformations and bending in…

Mesoscale and Nanoscale Physics · Physics 2014-09-29 Gareth Wyn Jones , Vitor M. Pereira

Using density-functional-theory we study the electronic and structural properties of a monolayer of Cu on the fcc (100) and (111) surfaces of the late 4d transition metals, as well as a monolayer of Pd on Mo bcc(110). We calculate the…

We develop several configuration interaction approaches for characterizing the electronic structure of an adsorbate on a metal surface (at least in model form). When one can separate adsorbate from substrate, these methods can achieve a…

Chemical Physics · Physics 2020-02-26 Zuxin Jin , Wenjie Dou , Joseph E. Subotnik

We introduce a minimum tight-binding model with only three parameters extracted from graphene and untwisted bilayer graphene. This model reproduces quantitatively the electronic structure of not only these two systems and bulk graphite near…

Mesoscale and Nanoscale Physics · Physics 2018-09-12 Xianqing Lin , David Tománek