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For charged systems in heterogeneous dielectric media, a key obstacle for molecular dynamics (MD) simulations is the need to solve the Poisson equation in the media. This obstacle can be bypassed using MD methods that treat the local…

Soft Condensed Matter · Physics 2013-09-27 Vikram Jadhao , Francisco J. Solis , Monica Olvera de la Cruz

We present two successive mean-field approximations for describing the mechanical properties and the swelling equilibrium of polyelectrolyte gels in contact with a salt solution. The first mean-field approximation reduces the many-chain…

Soft Condensed Matter · Physics 2019-11-22 Jonas Landsgesell , Christian Holm

We study charge regulation of colloidal particles inside aqueous electrolyte solutions. To stabilize colloidal suspension against precipitation, colloidal particles are synthesized with either acidic or basic groups on their surface. In…

Soft Condensed Matter · Physics 2020-09-16 Amin Bakhshandeh , Derek Frydel , Yan Levin

We present an extension to the Poisson-Boltzmann model where the dipolar features of solvent molecules are taken explicitly into account. The formulation is derived at mean-field level and can be extended to any order in a systematic…

Soft Condensed Matter · Physics 2012-01-31 Ariel Abrashkin , David Andelman , Henri Orland

We calculate the ion and composition distributions around colloid particles in an aqueous mixture, accounting for preferential adsorption, electrostatic interaction, selective solvation among ions and polar molecules, and…

Soft Condensed Matter · Physics 2011-11-04 Ryuichi Okamoto , Akira Onuki

Strongly interacting binary mixtures of superparamagnetic colloidal particles confined to a two-dimensional water-air interface are examined by theory, computer simulation and experiment. The mixture exhibits a partial clustering in…

Soft Condensed Matter · Physics 2009-11-11 Norman Hoffmann , Florian Ebert , Christos N. Likos , Hartmut Löwen , Georg Maret

We introduce and analyze $d$ dimensional Coulomb gases with random charge distribution and general external confining potential. We show that these gases satisfy a large deviations principle. The analysis of the minima of the rate function…

Mathematical Physics · Physics 2015-06-18 Luis Carlos Garcia del Molino , Khashayar Pakdaman , Jonathan Touboul

The Poisson-Boltzmann mean-field description of ionic solutions has been successfully used in predicting charge distributions and interactions between charged macromolecules. While the electrostatic model of charged fluids, on which the…

Soft Condensed Matter · Physics 2014-04-22 Dan Ben-Yaakov , David Andelman , Daniel Harries , Rudi Podgornik

We investigate sedimentation of model hard sphere-like colloidal dispersions confined in horizontal capillaries using laser scanning confocal microscopy, dynamical density functional theory, and Brownian dynamics computer simulations. For…

Soft Condensed Matter · Physics 2009-11-13 C. Patrick Royall , Joachim Dzubiella , Matthias Schmidt , Alfons van Blaaderen

A multicomponent mixture of Janus colloids with distinct catalytic coats and phoretic mobilities is a promising theoretical system to explore the collective behavior arising from nonreciprocal interactions. An active colloid produces (or…

Soft Condensed Matter · Physics 2024-02-15 Gennaro Tucci , Ramin Golestanian , Suropriya Saha

Interparticle interactions in charge-stabilized colloidal suspensions, of arbitrary salt concentration, are described at the level of effective interactions in an equivalent one-component system. Integrating out from the partition function…

Soft Condensed Matter · Physics 2009-10-31 A. R. Denton

We investigate the effects of long-ranged Coulomb interactions in a tilted Dirac semimetal in two dimensions by using the perturbative renormalization-group method. Depending on the magnitude of the tilting parameter, the undoped system can…

Strongly Correlated Electrons · Physics 2018-01-24 Yu-Wen Lee , Yu-Li Lee

For general dimension $d$ we prove the equidistribution of energy at the micro-scale in $\mathbb R^d$, for the optimal point configurations appearing in Coulomb gases at zero temperature. At the microscopic scale, i.e. after blow-up at the…

Mathematical Physics · Physics 2016-11-23 Mircea Petrache , Simona Rota Nodari

The electrostatic complexation between DOTAP-DOPC unilamellar liposomes and an oppositely charged polyelectrolyte (NaPA) has been investigated in a wide range of the liposome surface charge density. We systematically characterized the…

Soft Condensed Matter · Physics 2015-03-11 Simona Sennato , Laura Carlini , Domenico Truzzolillo , Federico Bordi

We develop a comprehensive continuum model capable of treating both electrostatic and structural interactions in liquid dielectrics. Starting from a two-order parameter description in terms of charge density and polarization, we derive a…

Soft Condensed Matter · Physics 2023-02-08 Ralf Blossey , Rudolf Podgornik

We study the melting behavior of charged colloidal crystals, using a simulation technique that combines a continuous mean-field Poisson-Boltzmann description for the microscopic electrolyte ions with a Brownian-dynamics simulation for the…

Soft Condensed Matter · Physics 2009-11-13 J. Dobnikar , Y. Chen , R. Rzehak , H. H. von Grünberg

Colloidal suspensions with free polymer coils which are larger than the colloidal particles are considered. The polymer-colloid interaction is modeled by an extension of the Asakura-Oosawa model. Phase separation occurs into dilute and…

Soft Condensed Matter · Physics 2009-10-31 Richard P. Sear

Stabilization and dispersion of electrical charge by colloids in non-polar media, such as nano-particles or inverse micelles, is significant for a variety of chemical and technological applications, ranging from drug delivery to e-ink. Many…

Chemical Physics · Physics 2019-04-16 Sariel Bier , Arik Yochelis

Structural and thermodynamic properties of the model solution containing charged oligomers and the equivalent number of counterions were studied by means of the canonical Monte Carlo simulation technique. The oligomers are represented as…

Soft Condensed Matter · Physics 2012-02-21 T. Sajevic , J. Rescic , V. Vlachy

We develop a theory for the optical conductivity of doped multilayer graphene including the effects of electron-electron interactions. Applying the quantum kinetic formalism, we formulate a set of pseudospin Bloch equations that governs the…

Mesoscale and Nanoscale Physics · Physics 2018-04-03 Xiao Li , Wang-Kong Tse