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A highly-charged spherical colloid in a salt-free environment exerts such a powerful attraction on its counterions that a certain fraction condenses onto the surface of a particle. The degree of condensation depends on the curvature of the…

Monodisperse spherical colloidal particles confined within emulsion droplets can crystallize into icosahedral clusters. Experimentally it was observed that a few large colloidal particles added as defects preferentially migrate to the…

Soft Condensed Matter · Physics 2026-04-29 Praveen K. Bommineni , Junwei Wang , Nicolas Vogel , Michael Engel

Quasicrystals are fascinating structures, characterized by strong positional order but lacking the periodicity of a crystal. In colloidal systems, quasicrystals are typically predicted for particles with complex or highly specific…

Soft Condensed Matter · Physics 2022-02-28 Etienne Fayen , Marianne Impéror-Clerc , Laura Filion , Giuseppe Foffi , Frank Smallenburg

Despite many attempts, ordered equilibrium microphases have yet to be obtained in experimental colloidal suspensions. The recent computation of the equilibrium phase diagram of a microscopic, particle-based microphase former [Zhuang et al.,…

Soft Condensed Matter · Physics 2017-09-07 Yuan Zhuang , Patrick Charbonneau

We investigate sedimentation of model hard sphere-like colloidal dispersions confined in horizontal capillaries using laser scanning confocal microscopy, dynamical density functional theory, and Brownian dynamics computer simulations. For…

Soft Condensed Matter · Physics 2009-11-13 C. Patrick Royall , Joachim Dzubiella , Matthias Schmidt , Alfons van Blaaderen

We report observations of the self-assembly of coated droplets into regular clusters at the sudden expansion of a microfluidic channel. A double emulsion consisting of a regular train of coated microdroplets was created upstream of the…

Soft Condensed Matter · Physics 2020-10-19 Kerstin Schirrmann , Gabriel Cáceres-Aravena , Anne Juel

We theoretically study sedimentation-diffusion equilibrium of dilute binary, ternary, and polydisperse mixtures of colloidal particles with different buoyant masses and/or charges. We focus on the low-salt regime, where the entropy of the…

Soft Condensed Matter · Physics 2009-11-11 Jos Zwanikken , rene van Roij

We report experimental and simulation studies of the structure of a monolayer of indented ("lock and key") colloids, on a planar surface. On adding a non-absorbing polymer with prescribed radius and volume fraction, depletion interactions…

Particle tracking is a key to single-particle-level confocal microscopy observation of colloidal suspensions, emulsions, and granular matter. The conventional tracking method has not been able to provide accurate information on the size of…

Soft Condensed Matter · Physics 2013-01-31 Mathieu Leocmach , Hajime Tanaka

With an eye towards next-generation, smart, micro/nanofluidic devices, capable of responding to external stimuli or changes in environment, we demonstrate a means to achieve dynamic control of the spatio-temporal properties of the electric…

Fluid Dynamics · Physics 2017-08-08 Alicia M Boymelgreen , Tov Balli , Touvia Miloh , Gilad Yossifon

Colloidal particles can spontaneously self-assemble into ordered structures, which not only can manipulate the propagation of light, but also vibration or phonons. Using Monte Carlo simulation, we study the self-assembly of perfectly…

Soft Condensed Matter · Physics 2024-03-11 Ji-Dong Hu , Ting Wang , Qun-Li Lei , Yu-qiang Ma

Colloids that interact via a short-range attraction serve as the primary building blocks for a broad range of self-assembled materials. However, one of the well-known drawbacks to this strategy is that these building blocks rapidly and…

Soft Condensed Matter · Physics 2020-09-16 S. A. Mallory , M. L. Bowers , A. Cacciuto

We report on sytematic measurements of the low frequency conductivity in aequous supensions of highly charged colloidal spheres. System preparation in a closed tubing system results in precisely controlled number densities between 1E16/m3…

Soft Condensed Matter · Physics 2009-10-31 Dirk Hessinger , Martin Evers , Thomas Palberg

Unlike atoms, colloidal particles are not identical, but can only be synthesised within a finite size tolerance. Colloids are therefore polydisperse, i.e. mixtures of infinitely many components with sizes drawn from a continuous…

Soft Condensed Matter · Physics 2009-11-07 R. M. L. Evans , C. B. Holmes

Spherical microparticles dispersed in nematic liquid crystals have been extensively investigated in the past years. Here, we report experimental studies on the elastic deformation, colloidal interaction and self-assembly of hematite…

Soft Condensed Matter · Physics 2020-07-15 Devika V S , Ravi Kumar Pujala , Surajit Dhara

We simulate crystallisation of hard spheres with short-ranged attractive potentials, as a model self-assembling system. We show how measurements of correlation and response functions during assembly can be used to tune the interaction…

Soft Condensed Matter · Physics 2014-03-10 Daphne Klotsa , Robert L. Jack

Charged colloids can form ordered structures like Wigner crystals or glasses at very low concentrations due to long-range electrostatic repulsions. Here, we combine small-angle x-ray scattering (SAXS) and optical experiments with…

Soft Condensed Matter · Physics 2025-03-19 Hanna Anop , Laura Dal Compare , Frederic Nallet , Achille Giacometti , Eric Grelet

Theories of protein crystallization based on spheres that form close-packed crystals predict optimal assembly within a `slot' of second virial coefficients and enhanced assembly near the metastable liquid-vapor critical point. However, most…

Soft Condensed Matter · Physics 2014-04-04 Thomas K. Haxton , Stephen Whitelam

At low temperatures, colloidal particles with short-range attractive and long-range repulsive interactions can form various periodic microphases in bulk.In this paper, we investigate the self-assembly behaviour of colloids with competing…

Soft Condensed Matter · Physics 2023-12-12 Ningyi Li , Junhong Li , Lijingting Qing , Shicheng Ma , Yao Li , Baohui Li

Depletion interactions arise from entropic forces, and their ability to induce aggregation and even ordering of colloidal particles through self-assembly is well established, especially for spherical colloids. We vary the size and…

Soft Condensed Matter · Physics 2016-03-15 Andrew S. Karas , Jens Glaser , Sharon C. Glotzer