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Motivated by recent experiments, we present a theoretical investigation of how the electro-osmotic flow occurring in a capillary is modified when its charged surfaces are coated by charged polymers. The theoretical treatment is based on a…

Mesoscale and Nanoscale Physics · Physics 2015-07-17 Umberto Marini Bettolo Marconi , Michele Monteferrante , Simone Melchionna

A new lattice method is presented in order to efficiently solve the electrokinetic equations, which describe the structure and dynamics of the charge cloud and the flow field surrounding a single charged colloidal sphere, or a fixed array…

Soft Condensed Matter · Physics 2015-06-05 R. Schmitz , B. Duenweg

We introduce a theoretical and numerical method to investigate the properties of electro-osmotic flows under conditions of extreme confinement. The present approach, aiming to provide a simple modeling of electrolyte solutions described as…

Mesoscale and Nanoscale Physics · Physics 2015-05-28 Simone Melchionna , Umberto Marini Bettolo Marconi

We describe electrophoresis of spherical dielectric particles in a uniformly aligned nematic medium with a negative dielectric anisotropy. A spherical particle that orients the liquid crystal (LC) perpendicularly to its surface moves under…

Soft Condensed Matter · Physics 2013-04-10 Israel Lazo , Oleg D. Lavrentovich

We investigate the flow of an electrolyte through a rigid nanochannel decorated with a surface charge pattern. Employing lattice Boltzmann and dissipative particle dynamics methods, as well as analytical theory, we show that the…

Soft Condensed Matter · Physics 2024-01-12 Tine Curk , Sergi G. Leyva , Ignacio Pagonabarraga

Anisotropic fluids appear in a diverse array of systems, from liquid-crystal displays to bacterial swarms, and are characterized by orientational order. Large colloidal particles immersed in such environments disturb the medium's…

Soft Condensed Matter · Physics 2025-01-03 Thomas G. J. Chandler , Saverio E. Spagnolie

A gap in understanding the link between continuum theories of ion transport in ionic liquids and the underlying microscopic dynamics has hindered the development of frameworks for transport phenomena in these concentrated electrolytes.…

Soft Condensed Matter · Physics 2015-09-11 Alpha A. Lee , Svyatoslav Kondrat , Dominic Vella , Alain Goriely

The confinement of an ionic liquid between charged solid surfaces is treated using an exactly solvable 1D Coulomb gas model. The theory highlights the importance of two dimensionless parameters: the fugacity of the ionic liquid, and the…

Soft Condensed Matter · Physics 2014-09-08 Alpha A Lee , Dominic Vella , Susan Perkin , Alain Goriely

Charge profiles in liquid electrolytes are of crucial importance for applications, such as supercapacitors, fuel cells, batteries, or the self-assembly of particles in colloidal or biological settings. However, creating localised (screened)…

Soft Condensed Matter · Physics 2021-03-17 Jeffrey C. Everts , Miha Ravnik

We study the time evolution and driven motion of thin liquid films lying on top of chemical patterns on a substrate. Lattice-Boltzmann and molecular dynamics methods are used for simulations of the flow of microscopic and nanoscopic films,…

Soft Condensed Matter · Physics 2012-04-04 Fabian Dörfler , Markus Rauscher , Joel Koplik , Jens Harting , S. Dietrich

We consider the gravity-driven flow of a perfect dielectric, viscous, thin liquid film, wetting a flat substrate inclined at a non-zero angle to the horizontal. The dynamics of the thin film is influenced by an electric field which is set…

Fluid Dynamics · Physics 2019-08-30 Ruben J Tomlin , Radu Cimpeanu , Demetrios T Papageorgiou

While fluids near a solid surface are at the core of applications in energy storage/conversion, electrochemistry/electrowetting and adsorption/catalysis, their nanoscale behavior remains only partially deciphered. Beyond conventional…

Soft Condensed Matter · Physics 2026-01-07 Cecilia Herrero , Lyderic Bocquet , Benoit Coasne

Electrohydrodynamic instabilities of fluid-fluid interfaces can be exploited in various microfluidic applications in order to enhance mixing, replicate well-controlled patterns or generate drops of a particular size. In this work, we study…

Fluid Dynamics · Physics 2021-06-29 Mohammadhossein Firouznia , David Saintillan

Molecular orientation fluctuations in ferroelectric smectic liquid crystals produce space charges, due to the divergence of the spontaneous polarization. These space charges interact with mobile ions, so that one must consider the coupled…

Soft Condensed Matter · Physics 2007-08-16 Robert A. Pelcovits , J. -B. Lee , R. B. Meyer

Electrically-controlled dynamics of fluids and particles at microscales is a fascinating area of research with applications ranging from microfluidics and sensing to sorting of biomolecules. The driving mechanisms are electric forces acting…

Soft Condensed Matter · Physics 2015-06-22 Israel Lazo , Chenhui Peng , Jie Xiang , Sergij V. Shiyanovskii , Oleg D. Lavrentovich

In 3D nematic liquid crystals, disclination lines have a range of geometric structures. Locally, they may resemble $+1/2$ or $-1/2$ defects in 2D nematic phases, or they may have 3D twist. Here, we analyze the structure in terms of the…

Soft Condensed Matter · Physics 2021-03-08 Cheng Long , Xingzhou Tang , Robin L. B. Selinger , Jonathan V. Selinger

Dynamics at low Reynolds numbers experiences recent revival in the fields of biophysics and active matter. While in bulk isotropic fluids it is exhaustively studied, this is less so in anisotropic fluids and in confined situations. Here, we…

Soft Condensed Matter · Physics 2026-01-21 Abdallah Daddi-Moussa-Ider , Elsen Tjhung , Marc Pradas , Thomas Richter , Andreas M. Menzel

The electro-osmotic flow through a channel between two undulated surfaces induced by an external electric field is investigated. The gap of the channel is very small and comparable to the thickness of the electrical double layers. A lattice…

Soft Condensed Matter · Physics 2016-05-24 Hiroaki Yoshida , Tomoyuki Kinjo , Hitoshi Washizu

Motivated by recent experimental observations [U. Delabre et al, Langmuir 24, 3998, 2008] we reconsider an instability of ultrathin nematic films, spread on liquid substrates. Within a continuum elastic theory of liquid crystals, in the…

Soft Condensed Matter · Physics 2011-02-18 O. V. Manyuhina , A. -M. Cazabat , M. Ben Amar

Dynamic processes in dispersions of charged spherical particles are of importance both in fundamental science, and in technical and bio-medical applications. There exists a large variety of charged-particles systems, ranging from…

Soft Condensed Matter · Physics 2013-11-25 G. Nägele , M. Heinen , A. J. Banchio , C. Contreras-Aburto