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A main goal of single-molecule experiments is to evaluate equilibrium free energy differences by applying fluctuation relations to repeated work measurements along irreversible processes. We quantify the error that is made in a free energy…

Statistical Mechanics · Physics 2009-06-22 Alessandro Mossa , Sara de Lorenzo , Josep Maria Huguet , Felix Ritort

Developments in the thermodynamics of small quantum systems envisage non-classical thermal machines. In this scenario, energy fluctuations play a relevant role in the description of irreversibility. We experimentally implement a quantum…

The work content of non-equilibrium systems in relation to a heat bath is often analyzed in terms of expectation values of an underlying random work variable. However, we show that when optimizing the expectation value of the extracted…

Quantum Physics · Physics 2015-03-19 Johan Aberg

We consider a class of quantum heat engines consisting of two subsystems interacting via a unitary transformation and coupled to two separate baths at different temperatures $T_h > T_c$. The purpose of the engine is to extract work due to…

Statistical Mechanics · Physics 2009-11-13 Armen E. Allahverdyan , Ramandeep S. Johal , Guenter Mahler

The Jarzynski equality allows the calculation of free-energy differences using values of work measured from nonequilibrium trajectories. The number of trajectories required to accurately estimate free-energy differences in this way grows…

Statistical Mechanics · Physics 2025-05-13 Stephen Whitelam

Jarzynski equality and related fluctuation theorems can be formulated for various setups. Such an equality was recently derived for nonunitary quantum evolutions described by unital quantum operations, i.e., for completely positive,…

Quantum Physics · Physics 2014-01-24 Alexey E. Rastegin , Karol Życzkowski

Despite the increasing interest, the research field which studies the concepts of work and heat at quantum level has suffered from two main drawbacks: first, the difficulty to properly define and measure the work, heat and internal energy…

Quantum Physics · Physics 2021-07-07 Paolo Solinas , Mirko Amico , Nino Zanghì

The Jarzynski equality relates the free energy difference between two equilibrium states to the fluctuating irreversible work afforded to switch between them. The prescribed fixed temperature for the equilibrium states implicitly constrains…

Statistical Mechanics · Physics 2020-09-03 Tobias Thalheim , Marco Braun , Gianmaria Falasco , Klaus Kroy , Frank Cichos

Thermodynamics is the phenomenological theory of heat and work. Here we analyze to what extent quantum thermodynamic relations are immune to the underlying mathematical formulation of quantum mechanics. As a main result, we show that the…

Quantum Physics · Physics 2016-04-21 Bartłomiej Gardas , Sebastian Deffner , Avadh Saxena

From the perspective of quantum thermodynamics, realisable measurements cost work and result in measurement devices that are not perfectly correlated with the measured systems. We investigate the consequences for the estimation of work in…

Quantum Physics · Physics 2019-11-05 Tiago Debarba , Gonzalo Manzano , Yelena Guryanova , Marcus Huber , Nicolai Friis

The characteristic function of the work performed by an external time-dependent force on a Hamiltonian quantum system is identified with the time-ordered correlation function of the exponentiated system's Hamiltonian. A similar expression…

Statistical Mechanics · Physics 2009-11-13 Peter Talkner , Eric Lutz , Peter Hanggi

We extend the quantum jump method to nearly adiabatically driven open quantum systems in a way that allows for an accurate account of the external driving in the system-environment interaction. Using this framework, we construct the…

Quantum Physics · Physics 2015-03-30 S. Suomela , J. Salmilehto , I. G. Savenko , T. Ala-Nissila , M. Möttönen

A system--bath (SB) model is considered to examine the Jarzynski equality in the fully quantum regime. In our previous paper [J. Chem. Phys. 153 (2020) 234107], we carried out "exact" numerical experiments using hierarchical equations of…

Statistical Mechanics · Physics 2021-02-11 Souichi Sakamoto , Yoshitaka Tanimura

The efficiency of any heat engine, defined as the ratio of average work output to heat input, is bounded by Carnot's celebrated result. However, this measure is insufficient to characterize the properties of miniaturized heat engines…

In this paper we give a pedagogical introduction to the ideas of quantum thermodynamics and work fluctuations, using only basic concepts from quantum and statistical mechanics. After reviewing the concept of work, as usually taught in…

Quantum Physics · Physics 2018-05-03 Wellington L. Ribeiro , Gabriel T. Landi , Fernando Semião

Traditional quantum thermodynamic frameworks associate work to energy exchanges induced by unitary transformations generated by external controls, and heat to energy exchanges induced by bath interaction. Recently, a framework was…

Quantum Physics · Physics 2026-01-06 Tiago F. F. Santos , Camille Latune

We propose and analyze the theoretical model for a two-stroke quantum heat engine with one of the heat baths replaced by a non-selective quantum measurement. We show that the engine's invariant reference state depends on whether the cycle…

Quantum Physics · Physics 2022-01-21 M. Sahnawaz Alam , B. Prasanna Venkatesh

The transition between a regime in which thermodynamic relations apply only to ensembles of small systems coupled to a large environment and a regime in which they can be used to characterize individual macroscopic systems is analyzed in…

Statistical Mechanics · Physics 2015-05-30 Alberto Suárez , Robert Silbey , Irwin Oppenheim

To define the work performed on a driven quantum system in a physically sound way has turned out to be a truly non-trivial task, except in some special cases of limited applicability. This topic has been in a focus of intense research…

Statistical Mechanics · Physics 2012-12-27 Jukka P. Pekola , Paolo Solinas , Alexander Shnirman , Dmitri V. Averin

We design a heat engine with multi-heat-reservoir, ancillary system and quantum memory. We then derive an inequality related with the second law of thermodynamics, and give a new limitation about the work gain from the engine by analyzing…

Quantum Physics · Physics 2017-11-09 Li-Hang Ren , Heng Fan