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Transport measurements have revealed several exotic electronic properties of graphene. The possibility to influence the electronic structure and hence control the conductivity by adsorption or doping with adatoms is crucial in view of…

By bridging graphene and benzene through a well-defined sequence of polycyclic aromatic hydrocarbons and their inherent shell structure, J. Phys. Chem. C, 2018, 122, 17526, it is shown that graphene is actually a coherent arrangement of…

Chemical Physics · Physics 2020-07-01 Aristides D. Zdetsis

We investigate electron transport through azulene molecule with four distinct electrode contact geometries using the non-equilibrium Green's function formalism within the tight-binding Hamiltonian. Employing the Q-matrix approach, we…

Mesoscale and Nanoscale Physics · Physics 2024-12-30 Koushik R. Das , Sudipta Dutta

Electronic transport properties for single-molecule junctions have been widely measured by several techniques, including mechanically controllable break junctions, electromigration break junctions or by means of scanning tunneling…

Mesoscale and Nanoscale Physics · Physics 2020-07-22 Ferdinand Evers , Richard Korytár , Sumit Tewari , Jan M. van Ruitenbeek

We study electron transport through single-molecule junctions formed by an octanethiol molecule bonded with the thiol anchoring group to a gold electrode and the opposing methyl endgroup to a carbon tip. Using the scanning tunneling…

We investigated a suspended bilayer graphene where the bottom (top) layer is doped by boron (nitrogen) substitutional atoms by using Density Functional Theory (DFT) calculations. We found that at high dopant concentration (one B-N pair…

Materials Science · Physics 2016-05-25 Daniele Giofré , Davide Ceresoli , Mario I. Trioni

Molecular electronic devices are the upmost destiny of the miniaturization trend of electronic components. Although not yet reproducible on large scale, molecular devices are since recently subject of intense studies both experimentally and…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 G. Cuniberti , F. Grossmann , R. Gutierrez

Along with the inherent remarkable properties of graphene, adatom-intercalated graphene-related systems are expected to exhibit tunable electronic properties. The metal-based atoms could provide multi-orbital hybridizations with the…

Computational Physics · Physics 2023-07-26 Thi My Duyen Huynh , Guo-Song Hung , Godfreys Gumbs , Ngoc Thanh Thuy Tran

A self-consistent method for calculating electron transport through a molecular device is proposed. It is based on density functional theory electronic structure calculations under periodic boundary conditions and implemented in the…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 San-Huang Ke , Harold U. Baranger , Weitao Yang

The shortcomings of mono-component systems, e.g., the gapless nature of graphene, the lack of air-stability in phosphorene, etc. have drawn great attention toward stacked materials expected to show interesting electronic and optical…

Mesoscale and Nanoscale Physics · Physics 2020-12-24 Maryam Mahdavifar , Sima Shekarforoush , Farhad Khoeini

We study inelastic electron tunneling through a molecular junction using the non-equilibrium Green function (NEGF) formalism. The effect of the mutual influence between the phonon and the electron subsystems on the electron tunneling…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Michael Galperin , Mark A. Ratner , Abraham Nitzan

We investigate the electronic transport properties of copper-graphene composites using a density-functional framework. Conduction in composites by varying the interface distance of a copper/graphene/copper (Cu/G/Cu) interface models was…

Materials Science · Physics 2023-02-01 K. N. Subedi , K. Nepal , C. Ugwumadu , K. Kappagantula , D. A. Drabold

Different stoichiometric configurations of graphane and graphene fluoride are investigated within density functional theory. Their structural and electronic properties are compared, and we indicate the similarities and differences among the…

Materials Science · Physics 2011-11-23 O. Leenaerts , H. Peelaers , A. D. Hernandez-Nieves , B. Partoens , F. M. Peeters

Ambipolar charge carrier transport in Copper phthalocyanine (CuPc) is studied experimentally in field-effect transistors and metal-insulator-semiconductor diodes at various temperatures. The electronic structure and the transport properties…

Mesoscale and Nanoscale Physics · Physics 2015-03-13 C. Schuster , M. Kraus , A. Opitz , W. Brütting , U. Eckern

We report on a first-principles study of the conductance through graphene suspended between Al contacts as a function of junction length, width, and orientation. The charge transfer at the leads and into the freestanding section gives rise…

Materials Science · Physics 2010-02-19 Salvador Barraza-Lopez , Mihajlo Vanevic , Markus Kindermann , Mei-Yin Chou

We analyze and compare the structural, dynamical, and electronic properties of liquid water next to prototypical metals including Pt, graphite, and graphene. Our results are built on Born-Oppenheimer molecular dynamics (BOMD) generated…

Materials Science · Physics 2017-08-09 Kevin Ryczko , Isaac Tamblyn

The interaction of metals with carbon materials, specifically with graphene, is of importance for various technological applications. In particular, intercalation of alkali metals is believed to provide a means for tuning the electronic…

Mesoscale and Nanoscale Physics · Physics 2023-01-26 Marianna Lorenzo , Conrad Escher , Tatiana Latychevskaia , Hans-Werner Fink

Density functional theory (DFT) and thermal DFT (thDFT) calculations were used to evaluate the energy band structure, bandgap, and the total energy of various graphene quantum dots (GQDs). The DFT calculations were performed using local…

Materials Science · Physics 2021-12-20 Majid Ghandchi , Ghafar Darvish , Mohammad Kazem Moravvej-Farshi

Graphene functionalized with catalytic transition metals offers high-performance gas sensing by coupling graphene's exceptional electronic transport properties with the metal's catalytic activity, yet the atomistic relationships connecting…

Materials Science · Physics 2025-05-29 Akram Ibrahim , Ahmed M. Hafez , Mahmooda Sultana , Can Ataca

We develop a new general formulation to explore light-driven electron transport through a single-molecule device with multiple pathways. Three individual systems are proposed including (i) a two-terminal molecular junction based on…

Mesoscale and Nanoscale Physics · Physics 2014-01-20 Liang-Yan Hsu , Herschel Rabitz