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Single particle catalysis aims at determining factors that dictate nanoparticle activity and selectivity. Existing methods often use fluorescent model reactions at low reactant concentrations, operate at low pressures, or rely on plasmonic…

Self-organization of nanoparticles is a major issue to synthesize mesoscopic structures. Among the possible mechanisms leading to self-organization, the oriented attachment is efficient yet not completely understood. We investigate here the…

Mesoscale and Nanoscale Physics · Physics 2013-07-11 Dimitri Hapiuk , Bruno Masenelli , Karine Masenelli-Varlot , Dimitri Tainoff , Olivier Boisron , Clement Albin , Patrice Melinon

Controlled breakdown has recently emerged as a highly accessible technique to fabricate solid-state nanopores. However, in its most common form, controlled breakdown creates a single nanopore at an arbitrary location in the membrane. Here,…

Thin films consisting of Ag and Au nanoparticles embedded in amorphous ZrO2 matrix were grown by pulsed laser deposition in a wide range of metal volume concentrations in the dielectric regime (0.08<x(Ag)<0.28 and 0.08<x(Au)<0.52). High…

The mechanical performance of Directed Energy Deposition Additive Manufactured (DED-AM) components can be highly material dependent. Through in situ and operando synchrotron X-ray imaging we capture the underlying phenomena controlling…

We present self-assembly routes of metamagnetic FeRh nanoisland arrays using sputter deposition processing. Controlling the growth parameters and epitaxy allows tuning the size and shape of the FeRh nanoislands. While the phase transition…

In the majority of cases nanostructures prepared by focused electron beam induced deposition (FEBID) employing an organometallic precursor contain predominantly carbon-based ligand dissociation products. This is unfortunate with regard to…

Mesoscale and Nanoscale Physics · Physics 2017-05-01 Evgeniya Begun , Oleksandr V. Dobrovolskiy , Maksym Kompaniiets , Roland Sachser , Christian Gspan , Harald Plank , Michael Huth

Silica nanoparticles have emerged as key building blocks for advanced applications in electronics, catalysis, energy storage, biomedicine, and environmental science. In this review, we focus on recent developments in both the synthesis and…

Materials Science · Physics 2025-03-31 Srabani Karmakar , Milind Deo , Imteaz Rahaman , Swomitra Kumar Mohanty

Thin TiO2 films on quartz substrates were prepared by spin coating of undoped and metal-ion-doped Sol Gel precursors. These films were characterised by Scanning Electron Microscopy, Laser Raman Microspectroscopy, Xray Diffraction and UV Vis…

Materials Science · Physics 2021-06-08 D. A. H. Hanaor , G. Triani , C. C. Sorrell

Eutectic NiTiO$_3$-TiO$_2$ samples and their H$_2$ reduced Ni-TiO$_2$ samples, where high aspect ratio TiO$_2$ nanostructures are axially decorated with nodular Ni globules, are thoroughly explored to understand their effect in…

We report on a large improvement in the wetting of Al2O3 thin films grown by un-seeded atomic layer deposition on monolayer graphene, without creating point defects. This enhanced wetting is achieved by greatly increasing the nucleation…

Materials Science · Physics 2014-11-14 Bruno Dlubak , Piran R. Kidambi , Robert S. Weatherup , Stephan Hofmann , John Robertson

Early results on the plasma deposition of dielectric thin films on acoustic wave (AW) activated substrates revealed a densification pattern arisen from the focusing of plasma ions and their impact on specific areas of the piezoelectric…

A promising approach of designing mesostructured materials with novel physical behavior is to combine unique optical and electronic properties of solid nanoparticles with long-range ordering and facile response of soft matter to weak…

Soft Condensed Matter · Physics 2017-01-18 Haridas Mundoor , Ivan I Smalyukh

Halloysite nanotubes (HNTs) are naturally occurring clay minerals found in Earth's crust that typically exist in the form of high aspect-ratio nanometers-long rods. Here, we investigate the evaporation-driven self-assembly process of HNTs…

Soft Condensed Matter · Physics 2024-01-10 Arun Dadwal , Meenu Prasher , Pranesh Sengupta , Nitin Kumar

Moving nanoparticles/atoms to study the nearfield interaction between them is one of the many approaches to explore the optical and electrical properties of these assemblies. Traditional approach included the self assembly by spinning or…

Mesoscale and Nanoscale Physics · Physics 2015-01-09 Farbod Shafiei

Bulk Au-Fe alloys separate into Au-based fcc and Fe-based bcc phases, but L1$_0$ and L1$_2$ orderings were reported in single-phase Au-Fe nanoparticles. Motivated by these observations, we study the structural and ordering energetics in…

Materials Science · Physics 2017-10-18 I. A. Zhuravlev , S. V. Barabash , J. M. An , K. D. Belashchenko

The production of hydrogen from water using only a catalyst and solar energy is one of the most challenging and promising outlets for the generation of clean and renewable energy. Semiconductor photocatalysts for solar hydrogen production…

We report the fabrication of artificial unidimensional crystals exhibiting an effective bulk second-order nonlinearity. The crystals are created by cycling atomic layer deposition of three dielectric materials such that the resulting…

The characterization of Pt/TiO2 (Degussa P25) catalyst system using atomic resolution Z-contrast images and electron energy loss spectroscopy in the scanning transmission electron microscope has recently revealed that Pt particles have a…

Materials Science · Physics 2009-11-11 Hakim Iddir , Vladimir Skavysh , Serdar Ogut , Nigel D. Browning

Transparent titania coatings have self-cleaning and anti-reflection properties (AR) that are of great importance to minimize soiling effect on photovoltaic modules. In this work, TiO2 nanocolloids prepared by polyol reduction method were…